journal article·2017-08-09Open access

Microstructure, Mechanical, Oxidation and Corrosion Properties of the Cr-Al-Si-N Coatings Deposited by a Hybrid Sputtering System

Jicheng Ding, Tengfei Zhang, Je Yun, Myung Kang, Qimin Wang, Kwang Kim

Coatings· Volume 7· Issue 8

Abstract

CrN and Cr-Al-Si-N coatings were deposited on SUS304 and Si-wafers by a hybrid coating system. The Cr and Al-Si target were connected to the cathode arc ion plating (AIP) and high power impulse magnetron sputtering (HiPIMS), respectively. Various Al and Si contents in the coatings were obtained by changing the power of Al-Si target from 0 to 1 kW. The results demonstrated a face-centered cubic structure in all of the coatings. With increasing Al-Si target power, both the density and mean diameter of the macroparticles on the coating surface declined. As Al and Si contents increased, the microstructure of the Cr-Al-Si-N coatings evolved from a dense column structure, to a finer grain column structure, and then to a compact granular-like structure. The hardness of the coatings increased from 21.5 GPa for the pure CrN coating, to a maximum value of ~27 GPa for the Cr-Al-Si-N coating deposited at 0.4 kW, which was mainly attributed to the solid solution strengthening and increased residual stress. The addition of Al and Si contents led to enhanced wear resistance against alumina balls at both room and elevated temperatures. Meanwhile, the Cr-Al-Si-N coatings also exhibited an excellent resistance to high-temperature oxidation at 800 and 1000 °C, and improved corrosion resistance, as compared with CrN coatings.
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Research context

OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Convergence Science, Pusan National University, Busan 609-735, Korea

Global Frontier R&D Center for Hybrid Interface Materials, Pusan National University, Busan 609-735, Korea

National Core Research Center for Hybrid Materials Solution, Pusan National University, Busan 609-735, Korea

School of Electromechanical Engineering, Guangdong University of Technology, Guangzhou 510006, China

References (54)

Show source-provided references
1. Fretting wear properties of CrN and Cr2N coatings10.1016/S0257-8972(03)00597-8 ↗
2. Interfacial structure, mechanical properties and thermal stability of CrAlSiN/CrAlN multilayer coatings10.1016/j.matchar.2017.01.010 ↗
3. Thermal and thermomechanical properties of Ti-Al-N and Cr-Al-N coatings10.1016/j.ijrmhm.2012.06.007 ↗
4. High-temperature tribological properties of CrAlN, CrAlSiN and AlCrSiN coatings10.1016/j.surfcoat.2011.08.037 ↗
5. Effect of nitrogen flow on the properties of quaternary CrAlSiN coatings at elevated temperatures10.1016/j.surfcoat.2007.06.042 ↗
6. Oxidation resistance of nanocomposite CrAlSiN under long-time heat treatment10.1016/j.surfcoat.2011.06.009 ↗
7. Electrochemical characterization of multilayer Cr/CrN-based coatings10.3390/coatings4030508 ↗
8. A comparative study of reactive direct current magnetron sputtered CrAlN and CrN coatings10.1016/j.surfcoat.2006.03.037 ↗
9. Effect of bias voltage on microstructure and phase evolution of Cr–Mo–N coatings by an arc bonded sputter system10.1016/j.ceramint.2015.12.048 ↗
10. Structure and mechanical properties of Cr-Zr-N films synthesized by closed field unbalanced magnetron sputtering with vertical magnetron sources10.1016/j.surfcoat.2005.08.101 ↗
11. Microstructural evolution and tribological behavior of Mo-Cu-N coatings as a function of Cu content10.1016/j.matchemphys.2011.08.002 ↗
12. Effect of substrate bias voltage on the properties of CrCN and CrN coatings deposited by cathodic arc evaporation10.1016/j.vacuum.2012.04.039 ↗
13. Tribological properties of duplex Cr-Si-N coatings on SS410 steel10.1016/j.surfcoat.2008.07.036 ↗
14. Design of AlCrSiN multilayers and nanocomposite coating for HSS cutting tools10.1016/j.apsusc.2015.05.191 ↗
15. Yadav, P., Lee, D.B., Lin, Y., Zhang, S.H., and Kwon, S.C. (2017). High-temperature corrosion of AlCrSiN film in Ar-1% SO2 gas. Coatings, 7.10.3390/coatings7030044 ↗
16. Influence of Al and Si content on structure and mechanical properties of arc evaporated Al-Cr-Si-N thin films10.1016/j.tsf.2013.03.017 ↗
17. Influence of bias potential and layer arrangement on structure and mechanical properties of arc evaporated Al-Cr-N coatings10.1016/j.vacuum.2014.03.006 ↗
18. Oxidation of arc-evaporated Al1−xCrxN coatings10.1116/1.2738492 ↗
19. Impact of bias potential and layer arrangement on thermal stability of arc evaporated Al-Cr-N coatings10.1016/j.tsf.2016.05.011 ↗
20. Friction and wear properties of TiN, TiAlN, AlTiN and CrAlN PVD nitride coatings10.1016/j.ijrmhm.2011.09.010 ↗
21. Corrosion resistance of CrAlN and TiAlN coatings deposited by lateral rotating cathode arc10.1016/j.tsf.2007.07.069 ↗
22. Influence of Si contents on the microstructure, mechanical and tribological properties of Cr-Si-N coatings10.1016/j.ceramint.2015.12.019 ↗
23. Oxidation behavior of Si-doped nanocomposite CrAlSiN coatings10.1016/j.surfcoat.2014.02.015 ↗
24. Influence of Si contents on tribological characteristics of CrAlSiN nanocomposite coatings10.1016/j.surfcoat.2010.08.156 ↗
25. Development of Si-modified CrAlSiN nanocomposite coating for anti-wear application in extreme environment10.1016/j.surfcoat.2015.06.090 ↗
26. Effects of nitrogen pressure and pulse bias voltage on the properties of Cr-N coatings deposited by arc ion plating10.1016/j.surfcoat.2009.11.021 ↗
27. Microstructural control of Cr-Si-N films by a hybrid arc ion plating and magnetron sputtering process10.1016/j.actamat.2009.07.001 ↗
28. Influence of Al on the microstructure and mechanical properties of Cr-Zr-(Al-)N coatings with low and high Zr content10.1016/j.surfcoat.2012.03.035 ↗
29. Effect of negative bias voltage on CrN films deposited by arc ion plating. I. Macroparticles filtration and film-growth characteristics10.1116/1.2966432 ↗
30. A superhard CrAlSiN superlattice coating deposited by multi-arc ion plating: I. Microstructure and mechanical properties10.1016/j.surfcoat.2012.05.144 ↗
31. Influence of negative bias voltage and deposition temperature on microstructure and properties of superhard TiB2 coatings deposited by high power impulse magnetron sputtering10.1016/j.surfcoat.2014.05.023 ↗
32. Effects of nitrogen partial pressure and pulse bias voltage on (Ti,Al)N coatings by arc ion plating10.1016/S0257-8972(02)00895-2 ↗
33. Microstructure and mechanical properties of Cr-Si-N nanocomposite coatings deposited by combined cathodic arc middle frequency magnetron sputtering10.1016/j.jallcom.2009.06.055 ↗
34. Determination of the local environment of silicon and the microstructure of quaternary CrAl(Si)N films10.1016/j.actamat.2006.11.014 ↗
35. Cutting performance using high reliable device of Ti-Si-N coated cutting tool for high-speed interrupted machining10.1016/j.surfcoat.2005.08.119 ↗
36. High temperature oxidation resistance of CrAlSiN coatings synthesized by a cathodic arc deposition process10.1016/j.jallcom.2007.06.084 ↗
37. Synthesis and properties of Cr-Al-Si-N films deposited by hybrid coating system with high power impulse magnetron sputtering (HiPIMS) and DC pulse sputtering10.1016/S1003-6326(12)61795-6 ↗
38. Effect of Si content on microstructural evolution and superhardness effect of TiN/CrAlSiN nanomultilayered films10.1016/j.jallcom.2015.08.012 ↗
39. Reactive-sputter-deposited TiN films on glass substrates10.1016/0040-6090(91)90225-M ↗
40. Effect of negative bias voltage on CrN films deposited by arc ion plating. II. Film composition, structure, and properties10.1116/1.2966434 ↗
41. Structure, hardness, and tribological properties of reactive magnetron sputtered chromium nitride films10.1116/1.582154 ↗
42. Microstructures, mechanical properties, and tribological behaviors of Cr-Al-N, Cr-Si-N, and Cr-Al-Si-N coatings by a hybrid coating system10.1016/j.surfcoat.2006.07.118 ↗
43. Effect of bias voltage on the microstructure and hardness of Ti-Si-N films deposited by using high-power impulse magnetron sputtering10.3938/jkps.68.351 ↗
44. Superhard nanocomposite Ti-Al-Si-N films deposited by reactive unbalanced magnetron sputtering10.1016/j.mseb.2006.06.043 ↗
45. Phase transition and properties of Ti-Al-N thin films prepared by r.f.-plasma assisted magnetron sputtering10.1016/S0040-6090(98)01364-9 ↗
46. Study on nanocrystalline Cr2O3 films deposited by arc ion plating: II. Mechanical and tribological properties10.1016/j.surfcoat.2011.10.026 ↗
47. Callister, W.D. (2004). Fundamentals of Materials Science and Engineering: An Integrated Approach, John Wiley & Sons. [2nd ed.].
48. Estimation of residual stress and its effects on the mechanical properties of detonation gun sprayed WC-Co coatings10.1016/j.msea.2009.10.009 ↗
49. Structure-performance relations in nanocomposite coatings10.1016/S0257-8972(01)01389-5 ↗
50. A study of the oxidation behavior of CrN and CrAlN thin films in air using DSC and TGA analyses10.1016/j.surfcoat.2007.11.037 ↗
51. High temperature properties of CrAlN, CrAlSiN and AlCrSiN coatings–Structure and oxidation10.1016/j.matchemphys.2011.03.078 ↗
52. Electrochemical impedance spectroscopy (EIS) study on corrosion performance of CrAlSiN coated steels in 3.5 wt % NaCl solution10.1016/j.surfcoat.2009.09.059 ↗
53. Ultra low nanowear in novel chromium/amorphous chromium carbide nanocomposite films10.1016/j.apsusc.2017.05.203 ↗
54. Combined reactive/non-reactive DC magnetron sputtering of high temperature composite AlN-TiB2-TiSi210.1016/j.matdes.2015.12.174 ↗