journal article·2020-03-23Open access

Effect of Addition of Mo or V on the Structure and Cutting Performance of AlCrN-Based Coatings

Sidra Iram, Fei Cai, Jianming Wang, Jiamin Zhang, Jiagang Liang, Farooq Ahmad, Shihong Zhang

Coatings· Volume 10· Issue 3

Abstract

This study focuses on a comparative analysis of AlCrXN (X = Mo or V) coatings with the reference AlCrN coating via arc ion plating technique (AIP). The XRD and XPS results showed that the AlCrXN coatings were mainly composed of fcc-(Cr,Al)N solid solution phases. Both the AlCrMoN and AlCrVN coatings exhibited much higher hardness and adhesive strength than the AlCrN coating. The addition of Mo or V decreased the coefficient of friction (COF) and wear rate, which was due to the formation of lubricant oxides containing Mo or V on the coating surfaces. The cutting results showed that abrasive wear, adhesive wear, and oxidation wear were the main wear mechanisms for the coated tools at the cutting speeds of 60 m/min and 94 m/min. The addition of Mo or V dramatically improved the cutting performance of AlCrXN-coated tools by increasing the anti-wear ability due to the high hardness and the formed lubricant VOx or MoOx films.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, Anhui University of Technology, Ma’anshan 243000, China

Research Center of Modern Surface and Interface Engineering, Anhui University of Technology, Ma’anshan 243002, China

School of Materials Science and Engineering, Anhui University of Technology, Ma’anshan 243002, China

Anhui Province Key Laboratory of Heavy Duty Special Vehicle Engine, Ma’anshan 243000, China

Funding

Science Foundation of Anhui Province

References (34)

Show source-provided references
1. Performance of PVD TiN, TiCN, and TiAlN coated cemented carbide tools in turning10.1016/S0263-4368(99)00008-6 ↗
2. The correlation between structure, multifunctional properties and application of PVD MAX phase coatings. Part. III. Multifunctional applications10.1080/02670844.2019.1656861 ↗
3. Thermal stability and age hardening of supersaturated AlCrN hard coatings10.1179/174951507X193657 ↗
4. A study of oxidation behavior of AlTiN-and AlCrN-based multilayer coatings10.1016/j.surfcoat.2017.10.078 ↗
5. Preparation and characterization of CrAlN/TiAlSiN nano-multilayers by cathodic vacuum arc10.1016/j.surfcoat.2015.01.023 ↗
6. Self-lubricating CrAlN/VN multilayer coatings at room temperature10.1016/j.apsusc.2013.04.068 ↗
7. Interfaces in arc evaporated Al-Cr-N/Al-Cr-O multilayers and their impact on hardness10.1016/j.surfcoat.2017.05.039 ↗
8. Structures and properties of hard and superhard nanocomposite coatings10.3367/UFNr.0179.200901b.0035 ↗
9. Toughness enhancement in hard ceramic thin films by alloy design10.1063/1.4822440 ↗
10. Influence of substrate rotation speed on the structure and mechanical properties of nanocrystalline AlTiN/MoN coatings synthesized by cathodic arc ion-plating10.1016/j.surfcoat.2015.01.049 ↗
11. Lisovenko, M., Bondar, O., Opielak, M., Beresnev, V., Konarski, P., Sakenova, R., Konstantinov, S., and Komarov, F.F. (2017, January 10–15). Structure and properties of nanoscale MoN/CrN multilayered coatings. Proceedings of the 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP), Odesa, Ukraine.10.1109/NAP.2017.8190210 ↗
12. RBS Depth Profiling Analysis of (Ti, Al)N/MoN and CrN/MoN Multilayers10.1186/s11671-017-1921-3 ↗
13. Ju, H. (2019). High-Temperature Self-Lubricating Metal Nitride-Based Nanostructure Composite Films. Friction, Lubrication and Wear, IntechOpen.10.5772/intechopen.86124 ↗
14. Deposition of CrN coatings by PVD methods for mechanical application10.1016/j.surfcoat.2005.02.038 ↗
15. Improvement of copper alloy properties in electro-explosive spraying of ZnO-Ag coatings resistant to electrical erosion10.1016/j.jmrt.2019.09.019 ↗
16. Structural-phase state of the system “CdO-Ag coating/copper substrate” formed by electroexplosive method
17. Structure of electro-explosion resistant coatings consisting of immiscible components10.1016/j.matlet.2016.10.076 ↗
18. Comparison of the wear and corrosion behavior between CrN and AlCrN coatings deposited by Arc-PVD method10.1088/2053-1591/ab4645 ↗
19. Structural optimisation and synthesis of multilayers and nanocomposite AlCrTiSiN coatings for excellent machinability10.1016/j.surfcoat.2015.07.033 ↗
20. Syntheses and Properties of Cr-Al-Mo-N Coatings Fabricated by Using a Hybrid Coating System10.3938/jkps.54.1237 ↗
21. Mechanical strengthening in self-lubricating CrAlN/VN multilayer coatings for improved high-temperature tribological characteristics10.1016/j.surfcoat.2016.02.003 ↗
22. Enhancing electrocatalytic activity for hydrogen evolution by strongly coupled molybdenum Nitride@Nitrogen-Doped carbon porous nano-octahedrons10.1021/acscatal.7b00120 ↗
23. Achour, A., Islam, M., Ahmad, I., Saeed, K., and Solaymani, S. (2019). Electrochemical stability enhancement in reactive magnetron sputtered VN films upon annealing treatment. Coatings, 9.10.3390/coatings9020072 ↗
24. Comparison in mechanical and tribological properties of CrTiAlMoN and CrTiAlN nano-multilayer coatings deposited by magnetron sputtering10.1016/j.apsusc.2015.12.005 ↗
25. The influence of alloying elements on the phase stability and mechanical properties of AlCrN coatings10.1016/j.surfcoat.2005.02.196 ↗
26. Strong and ductile non-equiatomic high-entropy alloys: Design, processing, microstructure, and mechanical properties10.1007/s11837-017-2540-2 ↗
27. The beneficial effect of high-temperature oxidation on the tribological behaviour of V and VN coatings10.1007/s11249-007-9241-x ↗
28. Effect of nitrogen partial pressure on microstructure and mechanical properties of Mo-Cu-V-N composite coatings deposited by HIPIMS10.1016/j.surfcoat.2017.08.041 ↗
29. Chen, R. (1992). Principle of Metal Cutting, China Machine.
30. Preparation and high-temperature tribological properties of CrAlVYN-Ag nanocomposite coatings10.1080/10426914.2016.1176189 ↗
31. The effect of grain size and hardness of wrought Alloy 718 on the wear of cemented carbide tools10.1016/j.wear.2010.01.017 ↗
32. Effect of cutting speed on chip formation and wear mechanisms of coated carbide tools when ultra-high-speed face milling titanium alloy Ti-6Al-4V
33. Research on friction characteristics of AlCrN and TiAlSiN coatings and properties of coated tools10.1007/s12541-019-00168-z ↗
34. Layered atomic structures of double oxides for low shear strength at high temperatures10.1016/j.scriptamat.2010.02.004 ↗