journal article·2016-01-14Open access

On Modulating Interfacial Structure towards Improved Anti-Icing Performance

Kshitij Jha, Emmanuel Anim-Danso, Selemon Bekele, George Eason, Mesfin Tsige

Coatings· Volume 6· Issue 1

Abstract

The design of anti-icing surfaces presents an interface with high causal density that has been challenging to quantify in terms of individual contributions of various interactions and environmental factors. In this commentary, we highlight the role of interfacial water structure as uniquely expressing the physico-chemical aspects of ice accretion. Recent work on the topic that focuses on control of interfacial structure is discussed along with results by our research group on wettability of chemically modified surfaces and the role of ions in modulating interfacial structure. Suggestions for systematic studies to understand the fundamental interactions at play in ice adhesion at interfaces are made especially in the under-explored areas of cooperative hydrogen bonding and the role of solvated counterions. Insights expected from such studies would contribute to design of robust anti-icing hierarchies.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Icing and De-icing Technologies · nanoparticles nucleation surface interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Polymer Science, The University of Akron, Akron, OH 44325, USA

Funding

ACS Petroleum Research Fund · National Science Foundation

References (100+)

Show source-provided references
1. Harry, L.W., and Alexander, R.O. (1945). Compositions for the Prevention of the Formation or Accretion of Ice on Exposed Surfaces. (2,373,727), U.S. Patent.
2. Sayward, J.M. (1979). Seeking Low Ice Adhesion, The Laboratory. Special report (Cold Regions Research and Engineering Laboratory (U.S.).10.21236/ADA071040 ↗
3. Nimerick, K.H., and Copeland, C.T. (1983). Composition and Method for Melting Frozen Aqueous Solutions. (4,388,203), U.S. Patent.
4. Forty years of helicopter ice protection experience at sikorsky aircraft10.4050/JAHS.26.3.5 ↗
5. Kanury, A., McComas, S., Lloyd, J., Slepicka, K., Miller, A., Kosel, T., Strieder, W., and Wolf, E. (1981). Cold Weather Transit Technology Program. Volume 2: Physics of Ice and Snow at the Interface with Transitway Surfaces, Technical Report.
6. A new look at homogeneous ice nucleation in supercooled water drops10.1175/1520-0469(1995)052<1924:ANLAHI>2.0.CO;2 ↗
7. Hansman, R.J., and Dershowitz, A. (1991). Optically Indicating Surface De-Icing Fluids. (5,039,439), U.S. Patent.
9. Worsnop, D.R., Miake-Lye, R., and Hed, Z.E. (1992). Icing Prevention by Ultrasonic Nucleation of Supercooled Water Droplets in Front of Subsonic Aircraft.
10. Cheng, K., and Yen, Y.C. (1991). Freezing and Melting Heat Transfer in Engineering: Selected Topics on Ice-Water Systems and Welding and Casting Processes, CRC Press.
11. Snow-band formation and evolution during the 15 November 1987 aircraft accident at Denver airport10.1175/1520-0434(1993)008<0453:SBFAED>2.0.CO;2 ↗
12. Reduction of ice adhesion to metal by using self-assembling monolayers (SAMs)10.1139/p03-014 ↗
13. Wowk, B. (2002). Polyvinyl Alcohol Compounds for Inhibition of Ice Growth. (6,391,224), U.S. Patent.
14. Cober, S.G., and Isaac, G.A. (2002, January 14–17). Aircraft icing environments observed in mixed-phase clouds. Proceedings of the AIAA 40th Aerospace Sciences Meeting & Exhibit, Reno, NV, USA.10.2514/6.2002-675 ↗
15. Slowly accreting ice due to supercooled water impacting on a cold surface10.1063/1.1416186 ↗
16. An analysis of freezing rain, freezing drizzle, and ice pellets across the United States and Canada: 1976–9010.1175/1520-0434(2004)019<0377:AAOFRF>2.0.CO;2 ↗
17. Georgiadis, J.G., and Hoke, J. (December, January 30). Quantitative Visualization of Early Frost Growth with Scanning Confocal Microscopy. Proceedings of the Brazilian Congress of Thermal Engineering & Science, Rio de Janeiro, Brazil.
18. New techniques in macromolecular cryocrystallography: Macromolecular crystal annealing and cryogenic helium10.1016/S1047-8477(03)00040-6 ↗
19. Anti-icing superhydrophobic coatings10.1021/la902882b ↗
20. Design of ice-free nanostructured surfaces based on repulsion of impacting water droplets10.1021/nn102557p ↗
21. Varanasi, K.K., Deng, T., Smith, J.D., Hsu, M., and Bhate, N. (2010). Frost formation and ice adhesion on superhydrophobic surfaces. Appl. Phys. Lett., 97.10.1063/1.3524513 ↗
22. In situ investigation of ice formation on surfaces with representative wettability10.1016/j.apsusc.2010.04.086 ↗
23. Exploiting topographical texture to impart icephobicity10.1021/nn103214q ↗
24. Characterization of titanium alkoxide sol–gel systems designed for anti-icing coatings: II. Mass loss kinetics10.1007/s11998-007-9055-7 ↗
25. Relationships between water wettability and ice adhesion10.1021/am1006035 ↗
26. Mimicking biopolymers on a molecular scale: Nano (bio) technology based on engineered proteins
27. Alizadeh, A., Bahadur, V., Zhong, S., Shang, W., Li, R., Ruud, J., Yamada, M., Ge, L., Dhinojwala, A., and Sohal, M. (2012). Temperature dependent droplet impact dynamics on flat and textured surfaces. Appl. Phys. Lett., 100.10.1063/1.3692598 ↗
28. Anti-icing potential of superhydrophobic Ti6Al4V surfaces: Ice nucleation and growth10.1021/acs.langmuir.5b02946 ↗
29. Robust prototypical anti-icing coatings with a self-lubricating liquid water layer between ice and substrate10.1021/am401004t ↗
30. Liquid-infused nanostructured surfaces with extreme anti-ice and anti-frost performance10.1021/nn302310q ↗
31. Verification of icephobic/anti-icing properties of a superhydrophobic surface10.1021/am400429q ↗
32. Investigating the effects of solid surfaces on ice nucleation10.1021/la3014915 ↗
33. Development of anti-icing materials by chemical tailoring of hydrophobic textured metallic surfaces10.1016/j.jcis.2012.11.021 ↗
34. Preparation and anti-icing behavior of superhydrophobic surfaces on aluminum alloy substrates10.1021/la400979d ↗
35. Charpentier, T.V. (2012). The Heterogeneous Ice Nucleation Properties of Structured and Chemically Tailored Surfaces for the Development of Novel Anti-Icing Materials. [Ph.D. Thesis, University of Leeds].
36. Inhibition of ice nucleation by slippery liquid-infused porous surfaces (SLIPS)10.1039/C2CP43586A ↗
37. Bio-inspired strategies for anti-icing10.1021/nn406522n ↗
38. Hydrophobic and ice-retarding properties of doped silicone rubber coatings10.1016/j.apsusc.2012.11.042 ↗
39. A novel superhydrophobic hybrid nanocomposite material prepared by surface-initiated AGET ATRP and its anti-icing properties10.1039/C4TA00634H ↗
40. Anti-icing Coating with an Aqueous Lubricating Layer10.1021/am501252u ↗
41. Nowak, A.P., Gross, A.F., and Bartl, M.H. (2012). Structural Coatings with Dewetting and Anti-Icing Properties, and Coating Precursors for Fabricating Same. (App. 13/708,642), U.S. Pat.
42. Understanding the anti-icing behavior of superhydrophobic surfaces10.1680/si.13.00046 ↗
43. Design and fabrication of a large-area superhydrophobic metal surface with anti-icing properties engineered using a top-down approach10.1016/j.apsusc.2015.06.024 ↗
44. Design of anti-icing coatings using supercooled droplets as nano-to-microscale probes10.1021/la2034565 ↗
45. An investigation of freezing of supercooled water on anti-freeze protein modified surfaces10.1016/S1672-6529(13)60208-5 ↗
46. Ice nucleation behaviour on sol–gel coatings with different surface energy and roughness10.1039/C5CP03243A ↗
47. Why superhydrophobic surfaces are not always icephobic10.1021/nn302138r ↗
48. Lee, M., Yim, C., and Jeon, S. (2015). Communication: Anti-icing characteristics of superhydrophobic surfaces investigated by quartz crystal microresonators. J. Chem. Phys., 142.10.1063/1.4906510 ↗
49. Ice adhesion on lubricant-impregnated textured surfaces10.1021/la402456c ↗
50. New insight into icing and de-icing properties of hydrophobic and hydrophilic structured surfaces based on core–shell particles10.1039/C5SM02143J ↗
51. Guadarrama-Cetina, J., Mongruel, A., González-Viñas, W., and Beysens, D. (2015). Frost formation with salt. EPL (Europhys. Lett.), 110.10.1209/0295-5075/110/56002 ↗
52. Carpenter, K., and Bahadur, V. (2015). Saltwater icephobicity: Influence of surface chemistry on saltwater icing. Sci. Rep., 5.10.1038/srep17563 ↗
53. A facile method for preparations of micro-nanotextured Co3O4 films with the excellent superhydrophobic and anti-icing behavior10.1016/j.matlet.2014.02.015 ↗
54. Ice-phobic surfaces that are wet10.1021/nn303372q ↗
55. Gross, A.F., Nowak, A.P., and Carter, W. (2013). Structural Coatings with Dewetting and Anti-Icing Properties, and Processes for Fabricating These Coatings. (App. 13/836,208), U.S. Pat.
56. Ice repellency behaviour of superhydrophobic surfaces: Effects of atmospheric icing conditions and surface roughness10.1016/j.apsusc.2015.04.180 ↗
57. Condensation mode determines the freezing of condensed water on solid surfaces10.1039/c2sm26206a ↗
58. Organogel as durable anti-icing coatings10.1007/s40843-015-0069-7 ↗
59. Jung, S., Tiwari, M.K., Doan, N.V., and Poulikakos, D. (2012). Mechanism of supercooled droplet freezing on surfaces. Nat. Commun., 3.10.1038/ncomms1630 ↗
60. Zhang, X.X., Chen, M., and Fu, M. (2014). Impact of surface nanostructure on ice nucleation. J. Chem. Phys., 141.10.1063/1.4896149 ↗
61. Hydrophobic surfaces for control and enhancement of water phase transitions10.1557/mrs.2013.104 ↗
62. Sun, X., Damle, V.G., Liu, S., and Rykaczewski, K. (2015). Bioinspired Stimuli-Responsive and Antifreeze-Secreting Anti-Icing Coatings. Adv. Mater. Interfaces, 2.10.1002/admi.201400479 ↗
63. Investigation of ice shedding properties of superhydrophobic coatings on helicopter blades10.1016/j.coldregions.2013.12.009 ↗
64. Reducing ice accumulation and adhesion by using a flexible micro-rod film10.1016/j.coldregions.2015.06.001 ↗
65. Predictive model for ice formation on superhydrophobic surfaces10.1021/la200816f ↗
66. Fabrication and anti-icing property of coral-like superhydrophobic aluminum surface10.1016/j.apsusc.2015.01.066 ↗
67. Ice-phobic coatings based on silicon-oil-infused polydimethylsiloxane10.1021/am400704z ↗
68. Wang, Z., Cong, Y., and Zhang, B. (2015). Liquid crystal compound anti-ice surface. Liq. Cryst., 1–8.
69. The Many Faces of Heterogeneous Ice Nucleation: Interplay Between Surface Morphology and Hydrophobicity10.1021/jacs.5b08748 ↗
70. Singh, J.K., and Müller-Plathe, F. (2014). On the characterization of crystallization and ice adhesion on smooth and rough surfaces using molecular dynamics. Appl. Phys. Lett., 104.10.1063/1.4862257 ↗
71. Influence of substrate elasticity on droplet impact dynamics10.1021/la304767t ↗
72. Reducing ice adhesion by hierarchical micro-nano-pillars10.1016/j.apsusc.2014.03.139 ↗
73. Hao, P., Lv, C., and Zhang, X. (2014). Freezing of sessile water droplets on surfaces with various roughness and wettability. Appl. Phys. Lett., 104.10.1063/1.4873345 ↗
74. On Hydrophobic and Icephobic Properties of TiO2-Doped Silicon Rubber Coatings
75. The freezing process of continuously sprayed water droplets on the superhydrophobic silicone acrylate resin coating surface10.1016/j.apsusc.2014.08.145 ↗
76. A review of icing prevention in photovoltaic devices by surface engineering10.1016/j.rser.2014.01.015 ↗
77. The icephobic performance of alkyl-grafted aluminum surfaces10.1039/C4SM02204A ↗
78. Mechanism of frost formation on lubricant-impregnated surfaces10.1021/la400801s ↗
79. Condensation and freezing of droplets on superhydrophobic surfaces10.1016/j.cis.2013.10.018 ↗
80. Energy-Effective Frost-Free Coatings Based on Superhydrophobic Aligned Nanocones10.1021/am502607e ↗
81. Fabrication of superhydrophobic surface on aluminum by continuous chemical etching and its anti-icing property10.1016/j.apsusc.2014.08.187 ↗
82. Delayed frost growth on jumping-drop superhydrophobic surfaces10.1021/nn3055048 ↗
83. Chen, X., Ma, R., Zhou, H., Zhou, X., Che, L., Yao, S., and Wang, Z. (2013). Activating the microscale edge effect in a hierarchical surface for frosting suppression and defrosting promotion. Sci. Rep., 3.10.1038/srep02515 ↗
84. Mechanism of Delayed Frost Growth on Superhydrophobic Surfaces with Jumping Condensates: More Than Interdrop Freezing10.1021/la504166x ↗
85. Water droplet behavior on superhydrophobic SiO2 nanocomposite films during icing/deicing cycles10.1016/j.matchar.2013.04.017 ↗
86. Anti-frost coatings containing carbon nanotube composite with reliable thermal cyclic property10.1039/C4TA01398K ↗
87. Direct Calculation of Ice Homogeneous Nucleation Rate for a Molecular Model of Water10.1073/pnas.1509267112 ↗
88. Yeong, Y.H., Mudafort, R., Steele, A., Bayer, I., and Loth, E. (2012, January 25–28). Water droplet impact dynamics at icing conditions with and without superhydrophobicity. Proceedings of the 4th American Institute of Aeronautics & Astronautics, Atmospheric and Space Environments Conference, New Orleans, LA, USA.10.2514/6.2012-3134 ↗
89. Hejazi, V., Sobolev, K., and Nosonovsky, M. (2013). From superhydrophobicity to icephobicity: Forces and interaction analysis. Sci. Rep., 3.10.1038/srep02194 ↗
90. Ice-phobic behavior of superhydrophobic Al surface undervarious etching conditions10.1007/s10832-014-9924-2 ↗
91. Switching fluid slippage on pH-responsive superhydrophobic surfaces10.1021/la500999k ↗
92. Dynamics of Droplet Impact on Hydrophobic/Icephobic Concrete with the Potential for Superhydrophobicity10.1021/la504626f ↗
93. Influence of solidification on the impact of supercooled water drops onto cold surfaces10.1007/s00348-015-1999-2 ↗
94. Morgan, C., Bossanyi, E., and Seifert, H. (1997, January 6–9). Assessment of safety risks arising from wind turbine icing. Proceedings of the EWEC-Conference, Dublin, Germany.
95. A review of surface engineering issues critical to wind turbine performance10.1016/j.rser.2007.11.009 ↗
96. Breaking the ice [transmission line icing]10.1109/MIA.2003.1227872 ↗
97. Petrenko, V.F. (2000). Systems and Methods for Modifying Ice Adhesion Strength. (6,027,075), U.S. Patent.
98. Aircraft anti-icing and de-icing techniques and modeling10.2514/3.47027 ↗
99. Stolarczyk, L.G., and Stolarczyk, G.L. (1995). Ice Detection Apparatus for Transportation Safety. (5,474,261), U.S. Patent.
100. Shotton, J.A. (1962). Mixtures of Acyclic Polyhydroxy Alcohols and Glycol Ethers as Anti-Icing Additives for Hydrocarbon Fuels. (3,032,971), U.S. Patent.