journal article·2025-01-03Open access

The Influence of an Alternating Current Field on Pack Boriding for Medium Carbon Steel at Moderate Temperature

Xiaoxiao Li, Wei Liu, Jianguang Yuan, Jiaye Yuan, Xiaobao Zhou, Taijun Pan, Yanjie Ren

Coatings· Volume 15· Issue 1

Abstract

The influence of alternating current (AC) field on the pack boriding process for medium carbon steel was investigated through characterization of microstructure, phase composition, microhardness, and corrosion resistance of the boride layer and its mechanism was revealed. Results showed that the boride layer obtained by AC field boriding was composed of the outer FeB and the inner Fe2B phase, which was similar to that of conventional boriding. Meanwhile, the effective thickness of the boride layer and proportion of Fe2B increased gradually with increasing current during AC field boriding. The introduction of an AC field during the boriding process served dual purposes. First, it facilitated the decomposition of the boriding medium, leading to an elevation in the concentration of active boron atoms. Second, it reduced the activation energy required for atomic diffusion, thereby accelerating the diffusion of both boron and iron atoms. These combined effects significantly enhanced the hardness distribution and corrosion resistance of the steel. Further insights into the process were gained by fitting the parabolic kinetics curves, which confirmed that the boriding process in an AC field was exclusively controlled by diffusion. This study also clarified the growth mechanism of the boride layer within an AC field.
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Research context

OpenAlex topics: Metal Alloys Wear and Properties · Advanced materials and composites · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Mechanical and Energy Engineering, Zhejiang University of Science and Technology, Hangzhou 310014, China

School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210097, China

Key Laboratory of Research on Hydraulic and Hydro-Power Equipment Surface Engineering Technology of Zhejiang Province, Hangzhou 310024, China

Jiangsu JITRI Advanced Energy and Materials Research Institute Co., Ltd., Changzhou 213032, China

School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China

Funding

National Natural Science Foundation of China · China Postdoctoral Science Foundation · Changzhou City In-ternational Cooperation Project · Zhejiang University of Science and Technology · Key Laboratory of Research on Hydraulic and Hydro-Power Equipment Surface Engineering Technology of Zhejiang Province

References (41)

Show source-provided references
1. Surface modification of titanium, titanium alloys, and related materials for biomedical applications10.1016/j.mser.2004.11.001 ↗
2. TiB Whisker Coating on Titanium Surfaces by Solid-State Diffusion: Synthesis, Microstructure, and Mechanical Properties10.1007/s11661-002-0336-6 ↗
3. Production and characterization of boride layers on AISI D2 tool steel10.1016/j.vacuum.2009.10.038 ↗
4. QPQ technology and resistance to hydrogen sulfide corrosion
5. Growth kinetics and some mechanical properties of two-phase boride layers produced on commercially pure titanium during plasma paste boriding10.1016/j.tsf.2017.02.033 ↗
6. Kinetics of growth of superhard boride layers during solid state diffusion of boron into titanium10.1016/j.ceramint.2012.05.077 ↗
7. Processing of titanium-titanium boride dual matrix composites10.1016/j.jmatprotec.2007.05.047 ↗
8. A comparative study of borided pure niobium, tungsten and chromium10.1016/j.vacuum.2006.01.036 ↗
9. Super and hyper duplex stainless steels: Structures, properties and application10.1016/j.prostr.2016.06.221 ↗
10. Investigation of the effect of boronizing on cast irons10.1016/S0025-5408(02)00697-9 ↗
11. Fracture toughness of borides formed on boronized ductile iron10.1016/j.matdes.2004.05.015 ↗
12. The fracture toughness of borides formed on boronized cold work tool steels10.1016/S1044-5803(03)00104-9 ↗
13. Effects of rare earths addition on the microstructure, wear and corrosion resistances of plasma nitrided 30CrMnSiA steel10.1016/j.surfcoat.2011.10.031 ↗
14. Characterization of boronized layers on a XC38 steel10.1016/j.surfcoat.2006.07.238 ↗
15. FeB/Fe2B phase transformation during SPS pack-boriding: Boride layer growth kinetics10.1016/j.actamat.2005.01.043 ↗
16. Investigation of Boronizing Kinetics of AISI 51100 Steel10.1007/s11665-012-0192-5 ↗
17. Effect on decreasing the eigen-brittleness of boride layer on its friction and wear behavior
18. Effect of rare earth on structure and properties of boronzing layer
19. Effect of rare elements on powder boro-carbo-nitnding at low temperature
20. Boride coatings on non-ferrous materials in a fluidized bed reactor and their properties10.1016/S1468-6996(02)00038-4 ↗
21. Study temperature property of bonding medium under microwave field
22. Enhanced boromzing kinetics of alloy steel assisted by surface mechanical attrition treatments10.1016/j.jallcom.2013.12.151 ↗
23. Superplastic boronizing of duplex stainless steel under dual compression method10.1016/j.msea.2011.07.054 ↗
24. Influences of current field frequency on alternating current field enhanced pack boriding on 45 steel
25. A kinetic investigation on alternating current field enhanced powder-pack boriding of Q215 steel10.1360/092013-1042 ↗
26. Alternating current field assisted pack boriding to Fe2B coating10.1179/1743294412Y.0000000104 ↗
27. Pulsed-DC powder-pack boriding: Growth kinetics of boride layers on an AISI 316L stainless steel and Inconel 718 superalloy10.1016/j.surfcoat.2021.127404 ↗
28. Alcantar-Martínez, L.M., Ruiz-Trabolsi, P.A., Tadeo-Rosas, R., Miranda-Hernández, J.G., Cabrera-Sierra, R., Velázquez, J.C., and Hernández-Sánchez, E. (2023). Improving the Surface Properties of an API 5L Grade B Pipeline Steel by Applying the Boriding Process-Part II: On the Changes in the Mechanical Properties. Coating, 13.10.3390/coatings13020470 ↗
29. Single-phase Fe2B layer prepared by variable electric field assisted pack-boriding at low temperature
30. Effect of Powder-Pack Boronizing on the Microhardness, Wear, and Corrosion Behaviors of AISI 304L Steel10.1007/s11665-023-07966-7 ↗
31. Characterization of alternating current field enhanced pack boriding for 45 carbon steel at low and medium temperatures
32. Phase structure and property of boriding case of 45 steel by direct current field enhanced pack boronizing
33. Effect of boronizing temperature and time on microstructure and abrasion wear resistance of Cr12Mn2V2 high chromium cast iron10.1016/j.surfcoat.2008.06.170 ↗
34. The kinetics and mechanism of multi-component diffusion on AISI 1045 steel10.1016/S0257-8972(99)00179-6 ↗
35. Effect of boron paste thickness on the growth kinetics of Fe2B boride layers during the boriding process10.1016/j.apsusc.2004.09.099 ↗
36. On the controlling factors in growth of boronizing layer and its kinetic analysis
37. Effects of Alternating Current Field on Growth of Boride Layer on Q215 Steel by Pack-boriding at 800 °C
38. Effect of pulsed DC current on atomic diffusion of Nb-C diffusion couple10.1007/s10853-008-2758-z ↗
39. Enhanced boronizing kinetics and high temperature wear resistance of H13 steel with boriding treatment assisted by air blast shot peening10.1016/j.surfcoat.2016.09.029 ↗
40. Boriding kinetics of H13 steel10.1016/j.vacuum.2005.07.013 ↗
41. Mechanism of thermochemical growth of iron borides on iron10.1023/B:JMSC.0000012924.74578.87 ↗