journal article·2024-12-23Open access

Microstructure and Corrosion Resistance of Laser-Cladded FeCo1.5CrNi1.5Ti0.5 High-Entropy Alloy Coatings

Sui Wang, Siqi Tian, Renjie Liu, Dengya Chen, Chao Wang, Jing Li, Sen Yang

Coatings· Volume 14· Issue 12

Abstract

Due to their excellent mechanical properties and corrosion resistance, high-entropy alloys (HEAs) have the potential to be used as new engineering structures and functional materials. In this study, an FeCo1.5CrNi1.5Ti0.5HEA coating was prepared on the surface of a 1Cr18Ni9Ti alloy by laser cladding technology. Phase structure and microstructure were characterized by XRD and using an SEM. The corrosion resistance was evaluated by an electrochemical workstation, and the polarization curves were obtained in simulated seawater and 3.5 wt.% NaCl and 5% HCl solutions. The corrosion morphology of the Fe-based HEA coating was further characterized using the SEM, super depth of field observation, and 3D topological images. The results showed that the Fe-based HEA coating had a single-phase FCC structure with a grain size of about 10.7 ± 0.25 μM. Electrochemical analysis results showed that the corrosion resistance of the current Fe-based HEA coating was poor in HCl solutions. However, it exhibited good corrosion properties in simulated seawater and 3.5 wt.% NaCl solutions. Further analysis of the corrosion morphology revealed that in simulated seawater and the 3.5 wt.% NaCl solution, the surface of the current Fe-based HEA coating exhibited a preferential corrosion tendency between dendrites, while in the 5% HCl solution, it exhibited more obvious pitting characteristics. The results indicate that the current Fe-based HEA coating exhibits good comprehensive performance, especially in an acidic Cl− corrosion environment. These findings provide a reference for the application of laser cladding prepared Fe HEA coatings.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, CNPC Tubular Goods Research Institute, Xi’an 710077, China

Research Institute of Engineering Technology, PetrChina Xinjiang Oilfield Company, Karamay 834000, China

Shaanxi Institute of Applied Physics and Chemistry, Xi’an 710061, China

Xi’an Beifang Qinghua Mechanical and Electrical Co., Ltd., Xi’an 710025, China

School of Materials Engineering, Xi’an Aeronautical University, Xi’an 710077, China

Funding

the CNPC Science and Technology Project

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