journal article·2024-12-21Open access

The Influence of Induction Hardening, Nitriding and Boronising on the Mechanical Properties of Conventional and Sintered Steels

František Nový, Jakub Harvanec, Miloš Mičian

Coatings· Volume 14· Issue 12

Abstract

Heat treatment technology changes all the mechanical properties of metallic materials. The influence of induction hardening, nitriding and boronising on the change in the microhardness, impact toughness, microstructure and coefficient of friction of conventional steels 42CrMo4 and 32CrMo12 has been examined and compared with results obtained in the sintered steels with an increased content of Cu, which were prepared using powder metallurgy technology. Widely used treatments for the examined materials include induction hardening and gas nitriding. This study focuses on comparing those technologies with alternative technologies of boronising. It was found that for powder metallurgy materials, boronising is a much more suitable process than nitriding because after the application of nitriding, the impact toughness dropped to one third of the impact toughness of the base material, while after boronising, the impact toughness remained unchanged. Through boronising, it was possible to achieve the unique possibility of improving the mechanical properties of sintered PM Fe-Cu-C steels and fully replacing the currently used nitriding process. Furthermore, compared to nitriding, it also increases the hardness of the surface layer many times to improve the friction properties and significantly increases the impact toughness.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Metal and Thin Film Mechanics · Powder Metallurgy Techniques and Materials · Metal Alloys Wear and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Mechanical Engineering, University of Žilina, Univerzitná 8215/1, 010 26 Žilina, Slovakia

Funding

APVV · KEGA · VEGA

References (30)

Show source-provided references
1. Totten, G.E., and Howes, M.A.H. (1997). Steel Heat Treatment Handbook, CRC Press.
2. Modifying a Stainless Steel via Electrochemical Nitridation10.1039/c0jm03585h ↗
3. Effect of Ion Nitriding on Properties of High Carbon Chromium Bearing Steel Containing Rare Earth Elements10.1007/s11665-023-08446-8 ↗
4. Study on Pressurized Gas Nitriding Characteristics for Steel 38CrMoAlA10.1016/j.surfcoat.2015.08.035 ↗
5. A Kinetic Model for Estimating the Boron Activation Energies in the FeB and Fe2B Layers during the Gas-Boriding of Armco Iron: Effect of Boride Incubation Times10.1016/j.apsusc.2014.01.151 ↗
6. The Effect of Temperature and Time on Microstructure and Friction Performance of RE-Borosulphurizing Composite Coatings10.1016/j.surfcoat.2018.03.022 ↗
7. Effect of Powder-Pack Boronizing on the Microhardness, Wear, and Corrosion Behaviors of AISI 304L Steel
8. Effect of boriding on tribocorrosion behavior of HSLA offshore mooring chain steel10.1016/j.surfcoat.2023.130276 ↗
9. Boriding Kinetics of H13 Steel10.1016/j.vacuum.2005.07.013 ↗
10. Role of RE Element Nd on Boronizing Kinetics of Steels10.1007/s11665-011-0053-7 ↗
11. Eyre, T.S. (1975). Brunel University Effect of Boronising on Friction and Wear of Ferrous Metals, Elsevier Sequoia S.A.10.1016/0043-1648(75)90105-2 ↗
12. Mei, S., Zhang, Y., Zheng, Q., Fan, Y., Lygdenov, B., and Guryev, A. (2022). Compound Boronizing and Its Kinetics Analysis for H13 Steel with Rare Earth CeO2 and Cr2O3. Appl. Sci., 12.10.3390/app12073636 ↗
13. Wear Behavior of Iron Boride Coating on AISI 414010.1134/S2070205116010299 ↗
14. Orihel, P., Drienovský, M., Gabalcová, Z., Jurči, P., and Keddam, M. (2023). Characterization and Boron Diffusion Kinetics on the Surface-Hardened Layers of Royalloy Steel. Coatings, 13.10.3390/coatings13010113 ↗
15. Mechanism of Thermochemical Growth of Iron Borides on Iron10.1023/B:JMSC.0000012924.74578.87 ↗
16. Orihel, P., Jurči, P., and Keddam, M. (2023). Characterizations and Kinetic Modelling of Boride Layers on Bohler K190 Steel. Coatings, 13.10.20944/preprints202305.0776.v1 ↗
17. Nanomechanical Characterization and Fracture Toughness of FeB and Fe2B Iron Borides Produced by Gas Boriding of Armco Iron10.1016/j.surfcoat.2017.07.020 ↗
18. Anode Plasma Electrolytic Boronitrocarburising of Low-Carbon Steel10.3103/S1068375515050099 ↗
19. Sliding and Abrasive Wear Behaviour of Boride Coatings10.1016/j.wear.2003.10.003 ↗
20. Surface Modification of Steel and Cast Iron to Improve Corrosion Resistance in Molten Aluminium10.1016/j.surfcoat.2005.06.026 ↗
21. Evaluating the Mechanical Behavior of Electrochemically Borided Low-Carbon Steel10.1016/j.surfcoat.2019.125177 ↗
22. Development of Ultra-Low Friction Coefficient Films and Their Effect on the Biocompatibility of Biomedical Steel10.2320/matertrans.M2019035 ↗
23. Tribocorrosion behavior of surface-modified AISI D2 steel10.1016/j.surfcoat.2020.125884 ↗
24. Tribological behavior of low-alloyed steel after nitriding10.30657/pea.2020.26.16 ↗
25. State of the North American P/M Industry—2005
26. (2024, October 14). European Steel and Alloy Grades, steelnumber.com. Available online: https://www.steelnumber.com/en/steel_composition_eu.php?name_id=335.
27. (2024, October 14). European Steel and Alloy Grades, steelnumber.com. Available online: https://www.steelnumber.com/en/steel_composition_eu.php?name_id=859.
28. (2024, October 14). MFIP Standard 35—Materials Standards for PM Structural Parts, Standard by Metal Powder Industries Federation, 105 College Road East Princeton, New Jersey 08540-6692, USA, Published: 2024, Number of Pages: 112, ISBN 978-1-943694-41-9. Available online: https://store.accuristech.com/mpif/standards/mpif-standard-35-structural-parts?product_id=2576471#jumps.
29. Bulger, M., and Stebick, B. (2010). Effect of Copper Alloy Addition Method on the Dimensional Response of Sintered Fe-Cu-C Steels. Advances in Powder Metallurgy and Particulate Materials—2010, Metal Powders Industry Federation. Part 7.
30. DOE Investigation of Anisotropic Dimensional Change During Sintering of Iron-Copper-Carbon