journal article·2025-10-08Open access

Application of Rejuvenators in Asphalt Binders: Classification and Micro- and Macro-Properties

Chengwei Xing, Weichao Zhou, Bohan Zhu, Haozongyang Li, Shixian Tang

Coatings· Volume 15· Issue 10

Abstract

Rejuvenating aged asphalt is critical for sustainable road construction and resource utilization. This paper systematically reviews the current research on rejuvenators, focusing on their classification and the micro-, and macro-properties of rejuvenated asphalt. Rejuvenators are categorized into mineral oil-based, bio-based, and compound types. Each type offers distinct advantages in recovering the performance of aged asphalt. Mineral oil-based rejuvenators primarily enhance low-temperature cracking resistance through physical dilution, while bio-based rejuvenators demonstrate superior environmental sustainability and stability. Compound rejuvenators, particularly those incorporating reactive compounds, show the best results in repairing degraded polymer modifiers and improving both low- and high-temperature properties of aged, modified asphalt. Atomic Force Microscopy (AFM), Fluorescence Microscopy (FM), and Scanning Electron Microscopy (SEM) have been applied to analyze the micro-properties of rejuvenated asphalt. These techniques have revealed that rejuvenators can restore the microstructure of aged asphalt by dispersing agglomerated asphaltenes and promoting molecular mobility. Functional groups and molecular weight changes, characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Gel Permeation Chromatography (GPC), indicate that rejuvenators effectively reduce oxidation products and molecular weight of aged asphalt, restoring its physicochemical properties. Macro-property evaluations show that rejuvenators significantly improve penetration, ductility, and fatigue resistance. Finally, this review identifies the key characteristics and challenges associated with rejuvenator applications and provides an outlook on future research directions.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Asphalt Pavement Performance Evaluation · Infrastructure Maintenance and Monitoring · Concrete and Cement Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Special Area Highway Engineering of Ministry of Education, Chang’an University, South 2nd Ring Road Middle Section, Xi’an 710064, China

School of Highway, Chang’an University, South 2nd Ring Road Middle Section, Xi’an 710064, China

Funding

Key Research and Development Program of Shaanxi, China · Spring Sunshine Program of the Ministry of Education of China · Key Laboratory of Road and Traffic Engineering of the Ministry of Education, Tongji University · Fundamental Research Funds for the Central Universities, CHD · Scientific Innovation Practice Project of Postgraduates of Chang’an University

References (100+)

Show source-provided references
1. Experimental study of the performance of porous ultra-thin asphalt overlay10.1080/10298436.2020.1837826 ↗
2. Comparative analysis of four styrene-butadiene-styrene (SBS) structure repair agents in the rejuvenation of aged SBS-modified bitumen10.1016/j.conbuildmat.2025.141232 ↗
3. Effects of utilization of rejuvenator in asphalt mixtures containing recycled asphalt pavement at high ratios
4. Ling, Q. (2006). Design and construction of flexible base mixture ratio of recycled asphalt mixture. J. Sichuan Univ. Sci. Eng., 107–110. Available online: https://link.cnki.net/doi/CNKI:SUN.
5. Sustainable asphalt rejuvenation using waste cooking oil: A comprehensive review10.1016/j.jclepro.2020.123304 ↗
6. A comprehensive review on the plant-mixed cold recycling technology of emulsified asphalt: Raw materials and factors affecting performances10.1016/j.conbuildmat.2024.137344 ↗
7. Mechanisms and research progress on biological rejuvenators for regenerating aged asphalt: Review and discussion10.1016/j.jclepro.2023.138622 ↗
8. Research progress on resource utilization of waste cooking oil in asphalt materials: A state-of-the-art review10.1016/j.jclepro.2022.135427 ↗
9. Waste cooking oil as an asphalt rejuvenator: A state-of-the-art review10.1016/j.conbuildmat.2019.116985 ↗
10. Aging mechanism and effective recycling ratio of SBS modified asphalt10.1016/j.conbuildmat.2014.07.064 ↗
11. Investigating bio-rejuvenation mechanisms in asphalt binder via laboratory experiments and molecular dynamics simulation10.1016/j.conbuildmat.2018.09.137 ↗
12. Hot central-plant recycling technology: A systematic review on raw materials and performance-influencing factors
13. Use of recycling agents in asphalt mixtures with high recycled materials contents in the United States: A literature review10.1016/j.conbuildmat.2019.03.286 ↗
14. Rheological properties and microscopic characteristics of rejuvenated asphalt using different components from waste cooking oil10.1016/j.jclepro.2022.133556 ↗
15. Interfacial damage mechanisms in hot-recycled asphalt mixtures: A molecular dynamics study considering the blending level between virgin and aged asphalt10.1016/j.fuel.2025.136345 ↗
16. Minireview on the rejuvenation of aged Styrene–Butadiene–Styrene (SBS) modified bitumen: State-of-the-art and outlook10.1021/acs.energyfuels.3c00860 ↗
17. Effects of rejuvenator on performance-based properties of rejuvenated asphalt binder and mixtures10.1016/j.conbuildmat.2006.03.006 ↗
18. Evaluation on Performance of Asphalt Rejuvenator Agent
19. Investigation on physical properties of waste cooking oil-rejuvenated bitumen binder10.1016/j.conbuildmat.2012.07.042 ↗
20. Investigation on performance of mineral-oil-based rejuvenating agent for aged high viscosity modified asphalt of porous asphalt pavement10.1016/j.jclepro.2023.136285 ↗
21. The aging behavior of reclaimed asphalt mixture with vegetable oil rejuvenators10.1016/j.conbuildmat.2021.123811 ↗
22. Compound rejuvenation of polymer modified asphalt binder10.1007/s11595-010-0152-6 ↗
23. Investigation of rejuvenation and modification of aged asphalt binders by using aromatic oil-SBS polymer blend10.1016/j.conbuildmat.2019.117154 ↗
24. Application of reactive rejuvenator in aged SBS modified asphalt regeneration: A review10.1016/j.conbuildmat.2024.135696 ↗
25. Workability and Rheological Property Evolution of Active Rejuvenated Styrene–Butadiene–Styrene-Modified Bitumen in the Early Stage10.1021/acssuschemeng.0c07699 ↗
26. Applications of vegetable oils and their derivatives as bio-additives for use in asphalt binders: A review10.1016/j.conbuildmat.2023.131312 ↗
27. Study on effect of various rejuvenators on virgin asphalt binders suffering various aging conditions and the unified evaluation index10.1016/j.conbuildmat.2023.132331 ↗
28. Viability of recycled asphalt mixtures with soybean oil sludge fatty acid10.1016/j.conbuildmat.2022.128728 ↗
29. Properties of reclaimed asphalt pavement mixture with organic rejuvenator10.1016/j.conbuildmat.2020.121514 ↗
30. Recycling asphalt using waste bio-oil: A review of the production processes, properties and future perspectives10.1016/j.psep.2021.01.032 ↗
31. A review on the effect of RAP recycling on bituminous mixtures properties and the viability of multi-recycling10.1016/j.conbuildmat.2019.03.258 ↗
32. Performance improvement and aging property of oil/SBS modified asphalt10.1016/j.conbuildmat.2021.123735 ↗
33. A novel characterization of furfural-extract oil from vacuum gas oil and its application in solvent extraction process10.1016/j.fuproc.2016.06.035 ↗
34. Evaluation and classification of recycling agents for asphalt binders10.1016/j.conbuildmat.2020.119864 ↗
35. Use of linear amplitude sweep test as a damage tolerance or fracture test to determine the optimum content of asphalt rejuvenator10.1016/j.conbuildmat.2021.123983 ↗
36. High temperature property and modification mechanism of asphalt containing waste engine oil bottom10.1016/j.conbuildmat.2020.119977 ↗
37. Waste engine oil influences on chemical and rheological properties of different asphalt binders10.1016/j.conbuildmat.2018.10.126 ↗
38. Al-Saffar, Z.H., Yaacob, H., Satar, M., Kamarudin, S.N.N., Mahmud, M.Z.H., Ismail, C.R., Hassan, S.A., and Mashros, N. (2020, January 28–30). A review on the usage of waste engine oil with aged asphalt as a rejuvenating agent. Proceedings of the 3rd International Conference on Materials Engineering and Science (IConMEAS), Kuala Lumpur, Malaysia.
39. Tian, R.Y., Luo, H.Y., Huang, X.M., Zheng, Y.Z.Z., Zhu, L.Y., and Liu, F.Y. (2022). Correlation analysis between mechanical properties and fractions composition of oil-rejuvenated asphalt. Materials, 15.10.3390/ma15051889 ↗
40. Analysis of relationship between component changes and performance degradation of waste-oil-rejuvenated asphalt10.1016/j.conbuildmat.2021.123777 ↗
41. Damage characteristics of waste engine oil bottom rejuvenated asphalt binder in the non-linear range and its microstructure10.1016/j.conbuildmat.2018.04.056 ↗
42. Evaluation of bio-based and petroleum-based rejuvenator based on cracking susceptibility of hot mix asphalt with high RAP content10.1016/j.conbuildmat.2023.130725 ↗
43. Preparation process of bio-oil and bio-asphalt, their performance, and the application of bio-asphalt: A comprehensive review
44. Productions and applications of bio-asphalts—A review10.1016/j.conbuildmat.2018.06.118 ↗
45. Use of tung oil as a rejuvenating agent in aged asphalt: Laboratory evaluations10.1016/j.conbuildmat.2019.117783 ↗
46. Investigation into possibility of rejuvenating aged asphalt binder using mustard oil10.1080/10298436.2020.1823388 ↗
47. High temperature properties of rejuvenating recovered binder with rejuvenator, waste cooking and cotton seed oils10.1016/j.conbuildmat.2014.02.032 ↗
48. Performance of aged asphalt binder treated with various types of rejuvenators10.28991/cej-2021-03091669 ↗
49. Use of mahua oil for rejuvenation of the aged binder through laboratory investigations10.1016/j.ijtst.2020.11.002 ↗
50. Preliminary examination of soybean oil derived material as a potential rejuvenator through superpave criteria and asphalt bitumen rheology10.1016/j.conbuildmat.2017.05.195 ↗
51. Comparison for the compositions of fast and slow pyrolysis oils by NMR characterization10.1016/j.biortech.2013.07.151 ↗
52. Bio-oil production from rice husk fast pyrolysis in a conical spouted bed reactor10.1016/j.fuel.2014.02.074 ↗
53. Utilization possibilities of palm shell as a source of biomass energy in Malaysia by producing bio-oil in pyrolysis process10.1016/j.biombioe.2011.01.033 ↗
54. Using bio-based rejuvenator derived from waste wood to recycle old asphalt10.1016/j.conbuildmat.2018.08.201 ↗
55. Upcycle olive pomace as antioxidant and recycling agent in asphalt paving materials10.1016/j.conbuildmat.2022.127217 ↗
56. Study on the optimum rice husk ash content added in asphalt binder and its modification with bio-oil10.1016/j.conbuildmat.2017.05.004 ↗
57. Physical-chemical properties of aged asphalt rejuvenated by bio-oil derived from biodiesel residue10.1016/j.conbuildmat.2015.12.025 ↗
58. Chemical characterization and oxidative aging of bio-asphalt and its compatibility with petroleum asphalt10.1016/j.jclepro.2016.11.100 ↗
59. Fast pyrolysis of pitch pine biomass in a bubbling fluidized-bed reactor for bio-oil production10.1016/j.jiec.2021.04.005 ↗
60. Advances in bio-oil regenerated aged asphalt materials
61. Aging influence on rheology properties of petroleum-based asphalt modified with biobinder10.1061/(ASCE)MT.1943-5533.0000712 ↗
62. Chemical characterization of biobinder from swine manure: Sustainable modifier for asphalt binder10.1061/(ASCE)MT.1943-5533.0000237 ↗
63. Investigating bitumen rejuvenation mechanisms using a coupled rheometry-morphology characterization approach10.1016/j.conbuildmat.2017.10.113 ↗
64. Sustainable recovery of waste vegetable cooking oil and aged bitumen: Optimized modification for short and long term aging cases10.1016/j.wasman.2020.05.012 ↗
65. Biofuels from waste fish oil pyrolysis: Continuous production in a pilot plant10.1016/j.fuel.2009.02.006 ↗
66. Sang, Y., Chen, M.Z., Wen, J., Leng, B.B., and Wu, S.P. (December, January 28). Effect of waste edible animal oil on physical properties of aged asphalt. Proceedings of the Annual Meetings of Chinese-Society’s-Building-Materials, Professional Committees of Stone and Aggregate and Utilization of Solid Waste, Wuhan, China.
67. Rejuvenation of aged asphalt binder extracted from reclaimed asphalt pavement using waste vegetable and engine oils
68. Utilization of palm oil and its by-products in bio-asphalt and bio-concrete mixtures: A review10.1016/j.conbuildmat.2022.127552 ↗
69. Investigation of rheological and chemical properties asphalt binder rejuvenated with waste vegetable oil10.1016/j.conbuildmat.2018.06.001 ↗
70. Investigation on the mechanism and performance of asphalt and its mixture regenerated by waste engine oil10.1016/j.conbuildmat.2021.125411 ↗
71. Evaluation of the effect of bio-oil on the high-temperature performance of rubber modified asphalt10.1016/j.conbuildmat.2018.10.064 ↗
72. Characteristics of bioepoxy based on waste cooking oil and lignin and its effects on asphalt binder10.1016/j.conbuildmat.2020.118926 ↗
73. Development of a novel binder rejuvenator composed by waste cooking oil and crumb tire rubber10.1016/j.conbuildmat.2019.117621 ↗
74. Investigating aging properties of bitumen modified with polyethylene-terephthalate waste plastic10.1016/j.resconrec.2021.105687 ↗
75. Chemical and rheological properties evaluation of a novel synchronous rejuvenated aged SBS modified asphalt10.1016/j.jclepro.2022.135213 ↗
76. Physical and chemical evaluation of adhesion recovery property of aged high-viscosity asphalt based on specialized composite rejuvenators10.1016/j.jclepro.2023.137758 ↗
77. Study on components selection and performance of bio-oil based asphalt rejuvenator based on softening and asphaltene deagglomeration effect10.1016/j.jclepro.2023.138238 ↗
78. Investigation of balanced feedstocks of lipids and proteins to synthesize highly effective rejuvenators for oxidized asphalt10.1021/acssuschemeng.0c01100 ↗
79. Rejuvenation of aged asphalt binders by waste engine oil and SBS blend: Physical, chemical, and rheological properties of binders and mechanical evaluations of mixtures10.1016/j.conbuildmat.2022.128441 ↗
80. Synergistic effect of SBS copolymers and aromatic oil on the characteristics of asphalt binders and mixtures containing reclaimed asphalt pavement10.1016/j.conbuildmat.2022.127026 ↗
81. Effect of phenolic resin on the performance of the styrene-butadiene rubber modified asphalt10.1016/j.conbuildmat.2018.06.076 ↗
82. Multi-scale studies on interfacial system compatibility between asphalt and SBS modifier using molecular dynamics simulations and experimental methods10.1016/j.conbuildmat.2022.128502 ↗
83. A comparison of rejuvenator and sryrene–butadiene rubber latex used in hot in-place recycling10.1080/14680629.2016.1142465 ↗
84. Performance restoration of aged SBS-modified asphalt in RAP via dry-process SBS modifier diffusion at the interface of aggregate-aged asphalt-virgin asphalt10.1016/j.conbuildmat.2024.139022 ↗
85. Preparation and characterization of active rejuvenated SBS modified bitumen for the sustainable development of high-grade asphalt pavement10.1016/j.jclepro.2020.123012 ↗
86. Thermal properties of 1-hexadecanol/high density polyethylene/graphene nanoplates composites as form-stable heat storage materials10.1016/j.solmat.2022.111580 ↗
87. Development of sustainable compound bio-oil rejuvenator and its rejuvenation mechanism on long-term aged asphalt10.1016/j.jclepro.2023.139440 ↗
88. Novel rejuvenators for sustainable recycling of aged SBS modified bitumen: Performance evaluation and reactive mechanism analysis10.1016/j.jclepro.2023.140147 ↗
89. Infrared spectra and rheological properties of asphalt cement containing waste engine oil residues10.1016/j.conbuildmat.2013.10.012 ↗
90. Effect of catalytic-reactive rejuvenator on structure and properties of aged SBS modified asphalt binders10.1016/j.conbuildmat.2020.118531 ↗
91. Structure and performance evaluation on aged SBS modified bitumen with bi- or tri-epoxy reactive rejuvenating system10.1016/j.conbuildmat.2017.06.102 ↗
92. Chiang, K.C.K., Zhu, B., Liu, L., Li, H., Chen, C., Tang, S., and Xing, C. (2025). Differences in rejuvenation mechanisms and physical properties of aged Styrene–Butadiene–Styrene (SBS)-modified bitumen by mono-epoxy and di-epoxy compounds. Polymers, 17.10.3390/polym17010086 ↗
93. A novel WCO-MDI reactive rejuvenation method for aged SBS modified asphalt toward sustainable asphalt pavements10.1016/j.jclepro.2023.140199 ↗
94. Preparation of reactive chain extension rejuvenators and its application in the aged SBS modified bitumen sustainable recycling10.1016/j.jclepro.2021.127954 ↗
95. Shedding light on the rejuvenation mechanism of reactive compounds in aged SBS-modified asphalt through molecular dynamics and quantum chemical simulations10.1061/JMCEE7.MTENG-18213 ↗
96. Development on the rheological properties and micromorphology of active reagent-rejuvenated SBS-modified asphalt10.1021/acssuschemeng.2c05008 ↗
97. Dual self-repairing enhancement mechanisms of blocked dynamic isocyanate prepolymer on aging degradation and fatigue damages of high-content SBS-modified asphalt10.1016/j.conbuildmat.2025.140855 ↗
98. Effect of reactive rejuvenating system on physical properties and rheological characteristics of aged SBS modified bitumen10.1016/j.conbuildmat.2018.04.217 ↗
99. Rheological properties and microscopic mechanism of composite regenerated asphalt10.1016/j.fuel.2024.134159 ↗
100. Synergistic effects of epoxy polymer and rejuvenator in asphalt rejuvenation: A comprehensive performance analysis10.1016/j.conbuildmat.2024.137056 ↗