Study of Wear and Corrosion Resistance of Cold Sprayed TC4 Coating on the Surface of Mg-Li Alloy
Source abstract
Abstract
Mg-Li alloys have achieved vital applications in aerospace, automotive, and 3C fields for their prominent properties. However, the Mg-Li alloy exhibits poor corrosion and wear resistance due to the high activity of Mg and Li elements and low hardness of Mg. Accordingly, TC4 alloy coating was prepared on the surface of Mg-Li alloy using the cold spray technique to enhance the surface properties. Moreover, the microstructure, microhardness, tribological properties, and corrosion resistance of the coating were systematically investigated. As indicated by the results, the interface between the coating and the Mg-Li alloy substrate was mechanical bonding without significant defects. Several pores exist in the cold sprayed TC4 coating for its high elasticity, toughness, and passivation, resulting in a porosity of 4.3%. The microhardness of the cold sprayed TC4 coating reached 296.3 HV, marking a notable increase in comparison with the substrate. The TC4 alloy coating has better wear resistance than the Mg-Li alloy substrate. The wear volume of the cold sprayed TC4 alloy only accounted for 38% of that of Mg-Li alloy. Abrasive wear was the major wear mechanism of the TC4 alloy coating. In electrochemical tests, the corrosion current density of the TC4 alloy coating (1.426 × 10−5 A/cm2) was two orders of magnitude lower than that of the magnesium-lithium alloy substrate (1.008 × 10−3 A/cm2), and the corrosion potential of the TC4 alloy coating was higher, which indicates that the coating has excellent corrosion resistance.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: High-Temperature Coating Behaviors · Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory for New Type of Functional Materials in Hebei Province, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China
Tianjin Institute of Aerospace Mechanical and Electrical Equipment, Tianjin 300301, China
Funding
National Natural Science Foundation of China · S&T Program of Tianjin under Grant
References (35)
Show source-provided references
1. A novel Ni2MnCuSnAl0.1 multi-principal element alloy coating to enhance the wear resistance and corrosion resistance of Mg-Li alloy10.1016/j.optlastec.2021.107243 ↗
2. Synthesis and microstructure, properties characterization of Ni-Ti-Cu/Cu-Al functionally graded coating on Mg-Li alloy by laser cladding10.1016/j.apsusc.2021.151645 ↗
3. Guo, J., Guo, S., Shen, Y., and Li, D. (2022). Hot Deformation Behavior and Microstructural Evolution Based on the Processing Map of Dual-Phase Mg-Li Based Alloy. Materials, 15.10.3390/ma15031022 ↗
4. Zou, Y., Liu, S.H., Wang, Q.L., and Li, Y. (2022). A Comparative Study on Mechanical and Corrosion Behaviours of α/(α + β) Mg-Li Al-loys Subjected to Ultrasonic Nanocrystal Surface Modification. Metals, 12.10.3390/met12040681 ↗
5. Co–P alloy matrix composite deposits reinforced by nano-MoS2 solid lubricant: An alternative tribological coating to hard chromium coatings10.1016/j.triboint.2021.106956 ↗
6. Feasible strategies for promoting the mechano-corrosion performance of Ni-Co based coatings: Which one is better?10.1016/j.surfcoat.2021.127337 ↗
7. Effect of Voltage on Mg-Li-Al Alloy Anodic Oxide Film10.4028/www.scientific.net/MSF.941.1194 ↗
8. Effects of copper additive on micro-arc oxidation coating of LZ91 magnesium-lithium alloy10.1016/j.surfcoat.2016.10.008 ↗
9. Ultrasonic-Assisted Electroless Ni-P Plating on Dual Phase Mg-Li Alloy10.1149/2.0841501jes ↗
10. A chrome-free conversion coating for magnesium–lithium alloy by a phosphate–permanganate solution10.1016/j.surfcoat.2007.07.094 ↗
11. Zhao, X., Dong, T., Fu, B., Li, G., Liu, Q., and Li, Y. (2021). Microstructure and Properties of Cold Sprayed NiCrAl Coating on AZ91D Magnesium Alloy. Coatings, 11.10.3390/coatings11020193 ↗
12. Cold spray coating: Review of material systems and future perspectives10.1179/1743294414Y.0000000270 ↗
13. Current Implementation Status of Cold Spray Technology: A Short Review10.1007/s11666-022-01382-4 ↗
14. Solid-state cold spraying of Ti and its alloys: A literature review10.1016/j.pmatsci.2019.100633 ↗
15. Modification of surface hardness, wear resistance and corrosion resistance of cold spray Al coated AZ31B Mg alloy using cold spray double layered Ta/ Ti coating in 3.5 wt % NaCl solution10.1016/j.corsci.2020.109029 ↗
16. Wear and Corrosion Resistance of Thick Ti-6Al-4V Coating Deposited on Ti-6Al-4V Substrate via High-Pressure Cold Spray10.1007/s11666-017-0588-8 ↗
17. Adhesion, tribological and corrosion properties of cold-sprayed CoCrMo and Ti6Al4V coatings on 6061-T651 Al alloy10.1016/j.surfcoat.2017.07.062 ↗
18. Singh, S., Raman, R.K.S., Berndt, C.C., and Singh, H. (2021). Influence of Cold Spray Parameters on Bonding Mechanisms: A Review. Metals, 11.10.3390/met11122016 ↗
19. Cold spray additive manufacturing and repair: Fundamentals and applications
20. Particle flattening during cold spray: Mechanistic regimes revealed by single particle impact tests10.1016/j.surfcoat.2020.126386 ↗
21. Microstructure and mechanical property of Ti and Ti6Al4V prepared by an in-situ shot peening assisted cold spraying10.1016/j.matdes.2015.07.015 ↗
22. Fan, J., Yun, H., Zhang, X., Chang, D., Chu, X., Xie, Y., and Huang, G. (2023). High-Performance Pure Aluminum Coatings on Stainless Steels by Cold Spray. Coatings, 13.10.3390/coatings13040738 ↗
23. Microstructure and Properties of Cold Sprayed IN718 Coating
24. Microstructure, hardness and cavitation erosion resistance of different cold spray coatings on stainless steel 316 for hydropower applications10.1016/j.mtcomm.2020.101305 ↗
25. Evaluation of residual stresses induced by cold spraying of Ti-6Al-4V on Ti-6Al-4V substrates10.1016/j.surfcoat.2019.06.028 ↗
26. Modification of Archard’s equation by taking account of elastic/pseudoelastic properties of materials10.1016/S0043-1648(01)00711-6 ↗
27. Effect of Different Substrate Angles on Wear Resistance of Laser Cladding Ni25/WC Coating
28. Dry sliding wear behaviour of AZ31 magnesium alloy strengthened by nanoscale SiCp10.1016/j.jmrt.2021.12.048 ↗
29. High temperature sliding wear behavior and mechanisms of cold-sprayed Ti and Ti–TiC composite coatings10.1016/j.wear.2021.203746 ↗
30. Corrosion Behaviour of AZ63 Magnesium Alloy in Natural Seawater and 3.5 wt. % NaCl Aqueous Solution10.20964/2018.08.32 ↗
31. Wang, Z., Fu, B.G., Wang, Y.F., Dong, T.S., Li, J.K., Li, G.L., Zhao, X.B., Liu, J.H., and Zhang, G.X. (2022). Effect of Cu Content on the Precipitation Behaviors, Mechanicaland Corrosion Properties of As-Cast Ti-Cu Alloys. Materials, 15.10.3390/ma15051696 ↗
32. Acquesta, A., Sinagra, C., and Monetta, T. (2023). Electrochemical and Economic Analysis of No-Rinse, “True-Cr-Free” Surface Conver-sion Coatings for a Green, Cost-Saving, Corrosion Protection of 8079 Aluminium Alloy. Appl. Sci., 13.10.3390/app13031560 ↗
33. Corrosion behavior of cold sprayed pure zinc coating on magnesium10.1016/j.surfcoat.2019.06.068 ↗
34. Li, R., Fu, B., Wang, Y., Li, J., Dong, T., Li, G., Zhang, G., and Liu, J. (2022). Effect of Cold-Rolling Reduction on Recrystallization Microstructure, Texture and Corrosion Properties of the X2CrNi12 Ferritic Stainless Steel. Materials, 15.10.3390/ma15196914 ↗
35. Corrosion behaviour of plasma sprayed Fe based metallic glass (Fe73Cr2Si11B11C3 (at%) coatings in 3.5% NaCl solution10.1016/j.jnoncrysol.2021.120913 ↗