journal article·2024-12-12Open access

Analysis of Lacquer from the Zeng Cemetery (1046–771 BCE) at Guojiamiao

Zifan Chen, Suya Wei, Yingchun Fu, Qin Fang

Coatings· Volume 14· Issue 12

Abstract

The wooden lacquerware unearthed from the Zhou Dynasty (1046–771 BCE) Zeng Cemetery of Guojiamiao in Hubei Province, China, holds significant cultural value. Although the artifacts retain intact lacquer films, the wooden bodies exhibit high moisture content and severe decay, necessitating immediate dehydration and reinforcement. The characterization of the samples was carried out using microscopy, SEM-EDS (Scanning Electron Microscopy—Energy Dispersive Spectrometry), XRD (X-Ray Diffraction), Raman spectroscopy, and THM-Py-GC/MS (Thermally Assisted Hydrolysis–Methylation Pyrolysis–Gas Chromatography/Mass Spectrometry) to analyze their physical and chemical properties, while moisture content was assessed through the loss-on-drying method. Findings reveal that the wooden structures of the dou and bow are made from Catalpa wood and Sawtooth oak, respectively, with a moisture content reaching 274%. The lacquer film comprises three layers: a mortar layer, a lacquer layer, and a cinnabar-containing red pigment layer. The purpose of this study is to investigate the material properties of lacquered wood artifacts, focusing on the application of advanced analytical techniques to assess their condition and composition, offering a foundation for effective conservation strategies for these cultural relics.
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Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Wood and Agarwood Research · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Hubei Provincial Institute of Cultural Relics and Archaeology, Wuhan 430077, China

Institute of Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China

Funding

Hubei Provincial Institute of Cultural Relics and Archaeology

References (38)

Show source-provided references
1. The Nature of Guojiamiao Zeng Guo Cemetery
2. Xiangfan City Archaeological Team, and Chen, Q. (2005). Zeng Guo Cemetery at Guojiamiao, Zaoyang, Science Press. (In Chinese).
3. Main Archaeological Achievements at the Caomenwan Section of Guojiamiao Cemetery in Zaoyang
4. Hubei Provincial Institute of Cultural Relics and Archaeology, Zhang, T., Fan, G., Fang, Q., and Hu, G. (2016). Excavation Bulletin of M10, M13 and M22 in the Caomenwan Section (2014) of Guojiamiao Cemetery, Zaoyang, Hubei. Jianghan Archaeol., 5, 78–89. (In Chinese).
5. Hubei Provincial Institute of Cultural Relics and Archaeology, Fang, Q., and Hu, G. (2016). Excavation Bulletin of M43 in the Caomenwan Section (2015) of Guojiamiao Cemetery in Zaoyang, Hubei. Jianghan Archaeol., 5, 90–105. (In Chinese).
6. Rowell, R. (1990). Structure and Degradation Process for Waterlogged Archaeological Wood, American Chemical Society.
7. Wu, S. (, January May). Research on the Cleaning, Dehydration, Restoration, and Protection of Ancient Water-Saturated Lacquered Woodware. Proceedings of the First Academic Annual Meeting of China Association for Preservation Technology of Cultural Relics, Lanzhou, China. (In Chinese).
8. Wang, J., Qian, G., and Yuan, C. (2007, January 6–8). Research Progress on the Protection of Unearthed Lacquered Woodware. Proceedings of the Fifth Academic Annual Meeting of China Association for Preservation Technology of Cultural Relics, Nanjing, China. (In Chinese).
9. An overview of dehydration and reinforcement materials and methods for waterlogged wooden cultural relics
10. The chemical analysis of Southeast Asian lacquers collected from forests and workshops in Vietnam, Cambodia, and Myanmar10.1016/j.culher.2019.05.015 ↗
11. Pitthard, V., Miklin-Kniefacz, S., Stanek, S., and Griesser, M. (2019). Analytical Examination and Conservation of East Asian Lacquer Works from European Collections. Heritage Wood, Springer. Cultural Heritage Science.10.1007/978-3-030-11054-3_4 ↗
12. Multi-analytical approach (SEM-EDS, FTIR, Py-GC/MS) to characterize the lacquer objects from Xiongnu burial complex (Noin-Ula, Mongolia)10.1016/j.microc.2016.10.013 ↗
13. Composition/structure and lacquering craft analysis of Wenzhou Song dynasty lacquerware10.1039/C6AY01694D ↗
14. Rate of occurrence of wood degradation in foundations and archaeological sites when groundwater levels are too low10.1016/j.culher.2023.07.005 ↗
15. Molecular Mechanism of Film Formation of Raw Lacquer
16. Research on the Films of Ancient Lacquerwares by Thermally Assisted Hydrolysis-Methylation (THM) Pyrolysis-Gas Chromatography/Mass Spectrometry (Py-GC/MS) Analysis
17. Xu, F. (2008). Wood Identification Atlas, Chemical Industry Press. (In Chinese).
18. Cheng, J. (1992). Timbers of China, China Forestry Publishing House. (In Chinese).
19. (2018). Measurement of Moisture Content of Unearthed Bamboo, Wood, and Lacquer Ware Artifacts—Gravimetric Method. Domestic Industry Standard—Industry Standard for Cultural Relic Protection—CN-WW (Standard No. WW/T 0086-2018).
20. InsideWood (2024, October 25). 2004-Onwards. Available online: http://insidewood.lib.ncsu.edu/search.
21. (2014). Technical Specification for Assessment of Diseases and Conditions of Movable Cultural Relics—Cultural Relics of Bamboo, Wood, and Lacquerware. Industry Standard for Cultural Relic Protection—CN-WW (Standard No. WW/T 0060-2014).
22. Study on the coating of wooden bowls unearthed from Hemudu
23. Oracle bone Color pigments
24. Characterization of early imperial lacquerware from the Luozhuang Han tomb, China10.1111/arcm.12226 ↗
25. Chen, X.L. (2014). Preliminary Study on the Protection of Lacquered Ware with Cloth and Lacquer Mixed together Unearthed from the Han Tomb at Dayun Mountain in Xuyi. Sci. Conserv. Archaeol., 7–12.
26. Infrared Spectral Analysis of Painted Pottery from the Western Han Dynasty Unearthed in Xuzhou
27. Infrared Spectra of Ancient Lacquer Ware
28. Determination of provenance and species of Japanese Jomon lacquer by pyrolysis-gas chromatography/mass spectrometry and 87Sr/86Sr isotope ratio10.1016/j.jaap.2014.11.003 ↗
29. Characterization and comparison of asian lacquer saps10.1016/j.porgcoat.2007.09.003 ↗
30. Scientific investigation of the lacquered wooden coffin of Xiang Fei excavated from eastern royal tombs of the qing dynasty10.1039/C7NJ02128C ↗
31. Beyond the basics: A systematic approach for comprehensive analysis of organic materials in Asian lacquers10.1080/00393630.2016.1230978 ↗
32. Wang, S.X. (2013). Explanation of Xiushi Lu, SDX Joint Publishing Company.
33. Yuan, J.Z. (1963). Taiyin Daduanji, Zhonghua Book Company. Published during the Zhengde and Jiajing periods of the Ming Dynasty.
34. Waterlogged archaeological wood A substrate for white rot fungi during drainage of wetlands10.1016/S0964-8305(01)00130-5 ↗
35. Evaluation of the state of preservation of waterlogged archaeological wood based on its physical properties: Basic density vs. wood substance density10.1016/j.jas.2014.03.038 ↗
36. Hoffmann, P., and Witkoepper, M. (1998, January 19–23). The Kauramin Method for Stabilizing Waterlogged Wood. Proceedings of the 7th ICOM-CC Working Group on Wet Organic Archaeological Materials Conference, Grenoble, France.
37. A methodological approach in the evaluation of the efficacy of treatments for the dimensional stabilization of waterlogged archaeological wood10.1016/j.culher.2009.04.003 ↗
38. Research on glyoxal used to reinforce water-saturated lacquered woodware