journal article·2024-11-27Open access

Efficient Photocatalytic Reduction of Hexavalent Chromium by NiCo2S4/BiOBr Heterogeneous Photocatalysts

Shumeng Qin, Ruofan Xu, Qiu Jin, Sen Wang, Yi Ren, Yulin Huang, Ziye Zheng, Lihui Xiao, Dong Zhai, Shuguang Wang, Zuoli He

Coatings· Volume 14· Issue 12

Abstract

For typical Cr(VI)-containing industrial wastewater, more efficient water treatment technologies need to be used to ensure that Cr(VI) concentrations are reduced to safe levels before discharge. Photocatalytic technology is highly efficient, environmentally friendly, and has been extensively used to address this demand. Herein, heterogeneous NiCo2S4/BiOBr photocatalysts with different ratios were prepared using a solvothermal method. When compared with pure NiCo2S4 and BiOBr, the NiCo2S4/BiOBr-30 had significantly increased adsorption capacity and visible-light-driven photocatalytic reduction activity for Cr(VI) removal. The improved adsorption performance of the NiCo2S4/BiOBr-30 was mainly due to its increased specific surface area, and the enhanced photocatalytic performance of the NiCo2S4/BiOBr-30 could be attributed to the improved separation and transfer of photogenerated carriers at the interface. Lastly, a possible enhanced photocatalytic Cr(VI) reduction mechanism of the NiCo2S4/BiOBr heterostructure was developed.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Pigment Synthesis and Properties · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shandong Key Laboratory of Water Pollution Control and Resource Reuse, Shandong Key Laboratory of Environmental Processes and Health, School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China

State Key Laboratory of Microbial Technology, Microbial Technology Institute, Shandong University, Qingdao 266237, China

Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao 266237, China

Weihai Research Institute of Industrial Technology of Shandong University, Shandong University, Weihai 264209, China

Sino-French Research Institute for Ecology and Environment (ISFREE), School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China

Funding

National Natural Science Foundation of China · Future Young Scholars Program of Shandong University · Taishan Scholars Project of Shandong Province · Key Laboratory of Organic Compound Pollution Control Engineering (MOE) Foundation

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