journal article·2024-09-14Open access

The Evaluation and Analysis of the Anti-Corrosion Performance of the Sealing Material B72 for Metal Artifacts Based on Electrochemical Noise

Hao Xu, Minghao Jia, Pei Hu, Shengyu Liu, Gang Hu

Coatings· Volume 14· Issue 9

Abstract

Paraloid B-72 (B72), as a transparent, colorless polymer material, has good film-forming ability when dissolved in acetone and is widely used as a sealing material for metal artifacts. In order to analyze and evaluate the preservation performance of B72 as a sealing material on the substrate of metal artifacts, a variety of electrochemical methods, mainly electrochemical noise (EN), and scanning electron microscopy (SEM) were applied to evaluate the B72 coating. The results showed that the B72 coating had a good preservation effect at the initial stage, and its poor water resistance led to the loss of its effectiveness after a few days of immersion. Compared with conventional electrochemical methods, electrochemical noise is non-destructive, which cannot cause new corrosion on the metal substrate and can well characterize the corrosion rate of the test system, and the results of its time domain and frequency domain analyses can correspond well with the polarization resistance and impedance spectra. Electrochemical noise is an effective method for evaluating the anti-corrosion performance of material preservation coatings.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · Concrete Corrosion and Durability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Archaeology and Museology, Peking University, Beijing 100871, China

Institute of Archaeology, Chinese Academy of Social Sciences, Beijing 100710, China

Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Key Scientific Research Base of Scientific & Technological Evaluation (Beijing University of Chemical Technology), National Cultural Heritage Administration, Beijing 100029, China

Key Laboratory of Archaeomaterials and Conservation, Ministry of Education, Institute for Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China

Key Laboratory of Archaeological Science, Ministry of Education, School of Archaeology and Museology, Peking University, Beijing 100871, China

Funding

National Key Research and Development Program of China

References (64)

Show source-provided references
1. Sources of electrochemical noise in corroding systems10.1134/S1023193506050077 ↗
2. Liu, H. (2023). Corrosion Measurement Technology, Chemical Industry Press. (In Chinese).
3. Transient Voltage Changes Produced in Corroding Metals and Alloys10.1149/1.2411362 ↗
4. Experimental-study of Relationships between Electrochemical Noise and Structure of Electrodeposits of Metals10.1016/0013-4686(78)80071-1 ↗
5. A Statistical-Analysis of the Fluctuations of the Passive Current10.1149/1.2109018 ↗
6. Eden, D.A., John, D.G., and Dawson, J.L. (1987). Detecting Localised Corrosion of Metallic Surface—By Comparing Test Electrode Coupling Current with Electrochemical Current Noise. (Patent WO 8707022-A).
7. Eden, D.A., Hladky, K., John, D.G., and Dawson, J.L. (1987, January 5–7). Electrochemcial Noise—Simultaneous Monitoring of Potential and Current Noise Signals from Corroding Electrodes. Proceedings of the Tri-Service Conference on Corrosion, Colorado Springs, CO, USA.
8. The Measurement of Corrosion Using Electrochemical 1/f Noise10.1016/0010-938X(82)90107-X ↗
9. The Measurement of Localized Corrosion Using Electrochemical Noise10.1016/0010-938X(81)90006-8 ↗
10. Hladky, K. (1983). Monitoring Corrosion of Metal Part Using Voltage Measurements between Part and Electrode. (Patent EP 84404-A).
11. The Physical Meaning of Noise Resistance10.1016/0010-938X(95)00089-3 ↗
12. Electrochemical noise resistance as a tool for corrosion rate prediction10.5006/1.3290271 ↗
13. Electrochemical Noise-Analysis of Iron Exposed to NaCl Solutions of Different Corrosivity10.1149/1.2148757 ↗
14. Dawson, J.L., Eden, D.A., and Carr, R.N. (1992). Production of Electrochemical Impedance Spectra Uses Spontaneously Occurring Potential Noise between Array of Electrodes to Produce Electrochemical Impedance Spectra. (Patent WO 9216825-A1).
15. Noise resistance applied to corrosion measurements: I. Theoretical analysis10.1149/1.1837361 ↗
16. Noise resistance applied to corrosion measurements: II. Experimental tests10.1149/1.1837362 ↗
17. Noise resistance applied to corrosion measurements; III. Influence of the instrumental noise on the measurements10.1149/1.1837896 ↗
18. A Review on Electrochemical Noise Analysis
19. Advances of the Analysis Methodology for Electrochemical Noise
20. Measures for the detection of localized corrosion with electrochemical noise10.1016/S0013-4686(01)00645-4 ↗
21. A practical evaluation of electrochemical noise parameters as indicators of corrosion type10.1016/j.electacta.2004.01.040 ↗
22. Shot noise and statistical parameters for the estimation of corrosion mechanisms10.1016/j.corsci.2005.05.047 ↗
23. The Fundamentals of FFT-Based Signal Analysis and Measurement
24. Use of wavelets to study electrochemical noise transients10.1016/S0013-4686(01)00424-8 ↗
25. Using wavelets transform in the analysis of electrochemical noise data10.1016/S0013-4686(99)00222-4 ↗
26. Wavelet transform-based analysis for electrochemical noise10.1016/S1388-2481(99)00053-3 ↗
27. The empirical mode decomposition and the Hilbert spectrum for nonlinear and non-stationary time series analysis10.1098/rspa.1998.0193 ↗
28. Novel time-frequency characterization of electrochemical noise data in corrosion studies using Hilbert spectra10.1016/j.corsci.2012.09.007 ↗
29. Analysis of Electrochemical Noise by Hilbert-Huang Transform and Its Application
30. Determination of corrosion types for AISI type 304L stainless steel using electrochemical noise method10.1016/j.msea.2005.07.022 ↗
31. Li, Y., Cai, Z.X., Huang, L.J., and Liao, R.Q. (2024). A Comparative Study of the Corrosion Behavior of P110 Casing Steel in Simulated Concrete Liquid Containing Chloride and Annulus Fluid from an Oil Well. Coatings, 14.10.3390/coatings14030294 ↗
32. Jáquez-Muñoz, J.M., Gaona-Tiburcio, C., Chacón-Nava, J., Cabral-Miramontes, J., Nieves-Mendoza, D., Maldonado-Bandala, E., Delgado, A.D., Flores-De los Rios, J.P., Bocchetta, P., and Almeraya-Calderón, F. (2022). Electrochemical Corrosion of Titanium and Titanium Alloys Anodized in H2SO4 and H3PO4 Solutions. Coatings, 12.10.3390/coatings12030325 ↗
33. Measuring electrochemical noise of a single working electrode for assessing corrosion resistance of polymer coated metals10.1016/j.porgcoat.2013.12.014 ↗
34. In situ evaluation of corrosion damage using non-destructive electrochemical measurements-A case study10.1016/j.jiec.2016.07.045 ↗
35. Analysis of electrochemical noise measurement on an organically coated metal10.1016/j.porgcoat.2016.01.017 ↗
36. Identifying defect levels in organic coatings with electrochemical noise (EN) measured in Single Cell (SC) mode10.1016/j.porgcoat.2018.10.027 ↗
37. Barrera, P.R., Gómez, F.J.R., and Ochoa, E.G. (2019). Assessing of New Coatings for Iron Artifacts Conservation by Recurrence Plots Analysis. Coatings, 9.10.3390/coatings9010012 ↗
38. Wang, H. (2009). Cultural Relics Preservation, Cultral Relics Press. (In Chinese).
39. Stabilization and Protection of Catechins on Simulated Archaeological Iron
40. Research of Compound Volatile Corrosion Inhibitors for Cast Iron Relics
41. Study on preparation and anticorrosion of silane sealing film on carbon steel
42. The Application of Electrochemical Noise for the Study of Metal Corrosion and Organic Anticorrosion Coatings: A Review10.1002/celc.202001342 ↗
43. Investigation of defects in organic anti-corrosive coatings using electrochemical noise measurement10.1016/S0300-9440(00)00098-9 ↗
44. Developments of the electrochemical noise method (ENM) for more practical assessment of anti-corrosion coatings10.1016/j.porgcoat.2006.09.017 ↗
45. Study and Application of Sealing Materials for Copper Cultural Relics
46. Huang, K., and Ma, Q.-l. (2009). The Conservation and Restoration Technology of Chinese Cultural Relics, Science Press. (In Chinese).
47. Paraloid® B-72/B-48N 1:1 as an Adhesive for Use in Hot Climates: Literature Review, Laboratory Testing, and Observational Field Study10.1080/00393630.2021.1891810 ↗
48. The use of Paraloid B-72 as an adhesive: Its application for archaeological ceramics and other materials10.1179/sic.1986.31.1.7 ↗
49. Emergency preservation of ivory artifacts unearthed from Fuquan Hill
50. Evaluation of commonly used reinforcement materials for color paintings on ancient wooden architecture in China10.1186/s40494-024-01236-y ↗
51. Investigation of photo-stability of acrylic polymer Paraloid B72 used for conservation
52. A study on the anti-photoageing property of the modified B72 as a relic protection material
53. A critical review of electrochemical noise measurement as a tool for evaluation of organic coatings10.1016/j.porgcoat.2016.02.016 ↗
54. An assessment of intrinsic noise of pseudo-reference electrodes and instrumental noise to enable reliable electrochemical noise measurements in situ on organically coated metal10.1016/j.electacta.2021.139279 ↗
55. Methods of trend removal in electrochemical noise data—Overview10.1016/j.measurement.2018.08.023 ↗
56. Characterization of Coatings Performance Using Electrochemical Noise-Analysis10.1016/0033-0655(91)80019-F ↗
57. Corrosion propagation monitoring using electrochemical noise measurements on carbon steel in hydrogenocarbonated solution containing chloride ions10.1016/j.corsci.2021.109885 ↗
58. Guideline for an assessment of electrochemical noise measurement devices10.1002/maco.201005839 ↗
59. Electrochemical Noise-Guidance for Improving Measurements and Data Analysis
60. Review—Electrochemical Noise Applied in Corrosion Science: Theoretical and Mathematical Models towards Quantitative Analysis10.1149/1945-7111/ab8de3 ↗
61. Evaluation of Corrosion-Inhibitors by Electrochemical Noise-Analysis10.1149/1.2069288 ↗
62. Corrosion Monitoring-System based on Measurement and Analysis of Electrochemical Noise10.5006/1.3293594 ↗
63. Spectral analysis of electrochemical noise with different transient shapes10.1016/S0013-4686(99)00406-5 ↗
64. Electrochemical noise measurements on stainless steel using a gelled electrolyte10.1016/j.corsci.2018.12.004 ↗