Preparation of Silicone Coating and Its Anti-Ice and Anti-Corrosion Properties
Source abstract
Abstract
To enhance protection against corrosion and ice on iron metal material in frigid zones, an organic silicone resin coating was prepared using four monomers. Its structure and performance was analyzed via infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), and thermal analysis (TG). Corrosion resistance of coating was tested by saltwater resistance and salt spray resistance and assessed using an electrochemical workstation, alongside anti-icing tests. The results showed that the organic silicone resin was successfully synthesized. The coatings could delay freezing onset by one-third compared to controls in low temperatures, with a detachment time also reduced by one-third, indicating excellent corrosion and ice resistance. The methylphenyl silicone resin had good anti-corrosion and anti-ice properties, with a low corrosion current density (icorr) of 0.8793 μA/cm2 and a high charge transfer resistance (Rct) of 24,930 Ω·cm2 in saline.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Surface Modification and Superhydrophobicity · Material Properties and Applications · Silicone and Siloxane Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
Funding
the Special Projects of the Ministry of Science and Technology
References (38)
Show source-provided references
1. How widespread is the usage of the Northern Sea Route as a commercially viable shipping route? A statistical analysis of ship transits from 2011 to 2018 based on empirical data10.1016/j.marpol.2020.104300 ↗
2. Investigating the trends in arctic research: The increasing role of social sciences and humanities10.1016/j.scitotenv.2020.139027 ↗
3. Holistic and sustainable design optimization of Arctic ships10.1016/j.oceaneng.2023.114095 ↗
4. Application of superhydrophobic coatings as a corrosion barrier: A review10.1016/j.surfcoat.2017.11.053 ↗
5. Epoxy/graphene film for lifecycle self-sensing and multifunctional applications10.1016/j.compscitech.2020.108312 ↗
6. Self-healing ability based on hydrogen bonds in organic coatings for corrosion protection of AA120010.1016/j.corsci.2020.108984 ↗
7. Anti-corrosion and self-healing behaviors of waterborne polyurethane composite coatings enhanced via chitosan-modified graphene oxide and phosphate intercalated hydrotalcite10.1016/j.porgcoat.2022.106881 ↗
8. 2-Mercaptobenzimidazole-inbuilt metal-organic-frameworks modified graphene oxide towards intelligent and excellent anti-corrosion coating10.1016/j.corsci.2021.109715 ↗
9. Polymer brush coatings for combating marine biofouling10.1016/j.progpolymsci.2014.02.002 ↗
10. Experimental Study on Corrosion Prevention of a Multilayer Coating System10.4028/www.scientific.net/AMR.881-883.1307 ↗
11. Influence of materials and fabrication strategies in tailoring the anticorrosive property of superhydrophobic coatings
12. Anticorrosive epoxy coatings containing ultrafine bamboo char and zinc particles10.1016/j.jece.2021.105707 ↗
13. Study on anti-corrosion performance and mechanism of epoxy coatings based on basalt flake loaded aniline trimer10.1016/j.colcom.2021.100505 ↗
14. Study of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings10.1016/j.jallcom.2018.03.160 ↗
15. Effects of morphology parameters on anti-icing performance in superhydrophobic surfaces10.1016/j.apsusc.2017.11.137 ↗
16. Robust Anti-Icing Performance of a Flexible Superhydrophobic Surface10.1002/adma.201602480 ↗
17. Hydrophobic Surfaces: Topography Effects on Wetting by Supercooled Water and Freezing Delay10.1021/jp404396m ↗
18. Non-fluorinated and durable photothermal superhydrophobic coatings based on attapulgite nanorods for efficient anti-icing and deicing10.1016/j.cej.2021.132585 ↗
19. Study on the synthesis and application of silicone resin containing phenyl group10.1007/s10971-015-3752-y ↗
20. Sol–gel coatings on metals for corrosion protection10.1016/j.porgcoat.2008.08.010 ↗
21. Corrosion protection of stainless steel by polysiloxane hybrid coatings prepared using the sol–gel process10.1016/j.surfcoat.2010.02.022 ↗
22. Exactly alternating silarylene–siloxane polymers. II. The condensation polymerization of arylenedisilanols and bisureidosilanes10.1002/pol.1982.170200405 ↗
23. Synthesis of MQ silicone resins through hydrolytic condensation of ethyl polysilicate and hexamethyldisiloxane10.1002/(SICI)1097-4628(19981128)70:9<1753::AID-APP13>3.0.CO;2-V ↗
24. Synthesis of fluorinated hybrid material for UV embossing of a large core optical waveguide structure10.1039/b412419g ↗
25. Improved hydrophobicity of inorganic–organic hybrid mesoporous silica with cage-like pores10.1016/j.colsurfa.2012.11.066 ↗
26. Viscoelastic and adhesive properties of PMMA-b-PtBA with tackifier10.1016/j.ijadhadh.2012.05.005 ↗
27. High dispersion and fluorescence of anthracene doped in polyphenylsiloxane films10.1007/s10971-006-7650-1 ↗
28. Improvement of Corrosion Resistance of Metals by an Environmentally Friendly Silica Coating Method10.1023/B:JSST.0000023849.33761.86 ↗
29. Thermal and flammability properties of a silica–poly(methylmethacrylate) nanocomposite10.1002/app.12307 ↗
30. Organic–inorganic hybrid materials. V. Dynamics and degradation of poly(methyl methacrylate) silica hybrids10.1002/(SICI)1099-0518(20000601)38:11<1972::AID-POLA60>3.0.CO;2-5 ↗
31. Silicone resin synthesized by tetraethoxysilane and chlorotrimethylsilane through hydrolysis–condensation reaction10.1002/app.40317 ↗
32. Effects of reduced surface grain structure and improved particle distribution on pitting corrosion of AA6063 aluminum alloy10.1016/j.jallcom.2020.155464 ↗
33. The Effect of High-Pressure Torsion on Microstructure, Hardness and Corrosion Behavior for Pure Magnesium and Different Magnesium Alloys10.1002/adem.201801081 ↗
34. Inorganic-organic sol gel hybrid coatings for corrosion protection of metals10.1007/s10971-010-2173-1 ↗
35. Brinker, C.J., and Scherer, C.W. (1990). Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, Academic press.
36. Electrochemical behaviour of SiO2 sol-gel coatings on stainless steel10.1007/BF00488379 ↗
37. Microstructure Effects in Multidipped Tin Oxide Films10.1111/j.1151-2916.1995.tb08038.x ↗
38. Preparation and properties of polyphenylsiloxane-based hybrid glass films obtained from a non-aqueous coating sol via a single-step dip-coating10.1016/j.optmat.2005.12.009 ↗