Development of Multicomponent Nanostructured Nitride Coatings to Protect against Corrosion Products from Titanium Alloy
Source abstract
Abstract
Phase-structural characteristics and the corrosion resistance of coatings ZrN, (Zr,Ti)N, (Zr,Hf)N, (Zr,Nb)N, (Ti,Zr,Hf)N and (Ti,Zr,Nb)N, which were deposited on a Ti6Al-4V titanium alloy substrate, were investigated. It was found that the titanium substrate has a crystalline structure, including grains with high (up to 24 at.%) and low (less than 2 at.%) vanadium content. Thus, during the deposition process, the coating can form adhesive bonds with local areas of the substrate that have quite different compositions. The diffusion of the coating elements into the substrate takes place up to a depth of 200 nm. The diffusion of titanium alloy elements (primarily titanium and vanadium) into the adhesive sublayer of the coating to a depth of 100 nm is also observed. Corrosion studies were carried out in 1M solutions with acidic (H2SO4), alkaline (NaOH) and neutral (NaCl) media at a constant temperature of 50 °C. The actual change in the mass of the samples during corrosion tests is extremely small. The protective coatings under study have very high anti-corrosion characteristics and practically do not react with solutions that imitate the liquid environments of the human body.
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Research context
OpenAlex topics: Metal and Thin Film Mechanics · Advanced materials and composites · Titanium Alloys Microstructure and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Design and Technological Informatics of the Russian Academy of Sciences (IDTI RAS), Vadkovsky Lane 18a, 127055 Moscow, Russia
Department of Solid State Physics and Nanotechnology, Belarusian State University, Nezavisimosti Ave. 4, 220030 Minsk, Belarus
Department of High-Efficiency Machining Technologies, Moscow State University of Technology “STANKIN”, Vadkovsky Lane 3a, 127055 Moscow, Russia
Department of Chemical, Biological, Radiation and Nuclear Protection, The State Educational Institution “University of Civil Protection” of the Ministry of Emergency Situations of the Republic of Belarus, Mashinostroiteley Street, 25, 220118 Minsk, Belarus
Physical Technical Institute, National Academy of Sciences of Belarus, Kuprevicha Str. 10, 220141 Minsk, Belarus
Department of Digital and Additive Technologies, Federal State Budget Educational Institution of Higher Education, MIREA—Russian Technological University, Vernadsky Avenue, 78, 119454 Moscow, Russia
Funding
Russian Science Foundation · Belarusian Republican Foundation for Fundamental Research
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