journal article·2023-02-28Open access

Enhanced Energy Storage Performance of AgNbO3:xCeO2 by Synergistic Strategies of Tolerance Factor and Density Regulations

Ke An, Gang Li, Tingting Fan, Feng Huang, Wenlin Wang, Jing Wang

Coatings· Volume 13· Issue 3

Abstract

AgNbO3-based ceramics have been widely studied as ideal lead-free materials. Herein, AgNbO3:xCeO2 (x = 0, 1, 2 mol%) ceramics were successfully prepared by the conventional solid-state reaction method. The optimization of energy storage properties is ascribed to the enhanced antiferroelectric (AFE) stability and the increased breakdown strength (Eb). The reduction of the tolerance factor leads to the enhancement of AFE stability. In addition, the enhancement of Eb is due to the increase of actual density, which is achieved through the regulation of CeO2 amount and grinding procedure in the experimental process. A high recoverable energy density (Wrec) of 5.04 J/cm3 and an energy efficiency (η) of 46.2% were achieved in AgNbO3:0.01CeO2 ceramics under an applied electric field up to 390 kV/cm. A higher η of 55.4% was obtained in AgNbO3:0.02CeO2 components. This research provides guidance for finding ceramic materials with comprehensive energy storage properties.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Multiferroics and related materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Analytical Science and Technology of Hebei Province, College of Chemistry and Materials Science, Hebei University, Baoding 071002, China

Department, Baoding Green Yijia Environmental Protection Technology Ltd., Baoding 071002, China

Funding

National Natural Science Foundation of China · Natural Science Foundation of Hebei province · Research Innovation Team of the College of Chemistry and Environmental Science of Hebei University

References (38)

Show source-provided references
1. Homogeneous/Inhomogeneous-Structured Dielectrics and their Energy-Storage Performances10.1002/adma.201601727 ↗
2. Decarbonising ceramic manufacturing: A techno-economic analysis of energy efficient sintering technologies in the functional materials sector10.1016/j.jeurceramsoc.2019.08.011 ↗
3. Nonlinear Dielectric Thin Films for High-Power Electric Storage With Energy Density Comparable With Electrochemical Supercapacitors10.1109/TUFFC.2011.2039 ↗
4. Ultra-high energy storage performance in lead-free multilayer ceramic capacitors via a multiscale optimization strategy10.1039/D0EE03094E ↗
5. Perovskite lead-free dielectrics for energy storage applications10.1016/j.pmatsci.2018.12.005 ↗
6. High-performance lead-free bulk ceramics for electrical energy storage applications: Design strategies and challenges10.1039/D1TA04504K ↗
7. Polymer composites with high energy density and charge-discharge efficiency at high temperature using aluminum oxide particles10.1016/j.jmrt.2022.04.117 ↗
8. Lead-Free Antiferroelectric Silver Niobate Tantalate with High Energy Storage Performance10.1002/adma.201701824 ↗
9. Constructing phase boundary in AgNbO3 antiferroelectrics: Pathway simultaneously achieving high energy density and efficiency10.1038/s41467-020-18665-5 ↗
10. Antiferroelectrics for Energy Storage Applications: A Review10.1002/admt.201800111 ↗
11. Energy storage characteristics of (Pb,La)(Zr,Sn,Ti)O3 antiferroelectric ceramics with high Sn content10.1063/1.5044712 ↗
12. High energy-storage performance of PLZS antiferroelectric multilayer ceramic capacitors10.1039/C9QI01416K ↗
13. Structural and dielectric properties of (1 − x)(Sr0.7Pb0.15Bi0.1)TiO3-x(Bi0.5Na0.5)TiO3 energy storage ceramic capacitors10.1016/j.jallcom.2020.158535 ↗
14. Displacive Ordering Transitions in Perovskite-Like AgNb1/2Ta1/2O310.1021/cm101263p ↗
15. Phase transitions in tantalum-modified silver niobate ceramics for high power energy storage10.1039/C8TA10075F ↗
16. Crystal structure and electrical properties of AgNbO3-based lead-free ceramics10.1016/j.ceramint.2016.09.021 ↗
17. High energy density in silver niobate ceramics10.1039/C6TA06353E ↗
18. Energy storage performance in BiMnO3-modified AgNbO(3)anti-ferroelectric ceramics10.1016/j.matlet.2018.11.105 ↗
19. Realizing high low-electric-field energy storage performance in AgNbO3 ceramics by introducing relaxor behaviour
20. Significantly enhanced energy storage performance of rare-earth-modified silver niobate lead-free antiferroelectric ceramics via local chemical pressure tailoring10.1039/C8TC05458D ↗
21. Aliovalent A-site engineered AgNbO3 lead-free antiferroelectric ceramics toward superior energy storage density10.1039/C9TA90145K ↗
22. Silver Niobate Lead-Free Antiferroelectric Ceramics: Enhancing Energy Storage Density by B-Site Doping10.1021/acsami.7b17382 ↗
23. Enhanced energy storage performances under moderate electric field in aliovalent A/B-site co-doped AgNbO310.1016/j.materresbull.2022.112008 ↗
24. Ultrahigh energy-storage density in A-/B-site co-doped AgNbO3 lead-free antiferroelectric ceramics: Insight into the origin of antiferroelectricity10.1039/C9TA06457E ↗
25. Improvement of dielectric and energy storage properties in Sr0.85Bi0.1ZrO3 modified (Bi0.5Na0.5)(0.7)Sr0.3TiO3 lead-free ceramics10.1016/j.jallcom.2022.164577 ↗
26. Design for high energy storage density and temperature-insensitive lead-free antiferroelectric ceramics10.1039/C8TC06549G ↗
27. Lead-free Ag1-3xLaxNbO3 antiferroelectric ceramics with high-energy storage density and efficiency10.1111/jace.16309 ↗
28. Effect of grain size on the energy storage properties of (Ba0.4Sr0.6)TiO3 paraelectric ceramics10.1016/j.jeurceramsoc.2013.11.039 ↗
29. Microstructural origin of the dielectric breakdown strength in alumina: A study by positron lifetime spectroscopy10.1016/j.jeurceramsoc.2005.03.146 ↗
30. Relationships between dielectric breakdown resistance and charge transport in alumina materials—Effects of the microstructure10.1016/j.jeurceramsoc.2006.05.047 ↗
31. Enhanced energy-storage performance in silver niobate-based dielectric ceramics sintered at low temperature
32. Effects of phase constitution and microstructure on energy storage properties of barium strontium titanate ceramics10.1016/j.jeurceramsoc.2016.12.052 ↗
33. Enhanced dielectric breakdown strength in TiO2-SiO2-Al2O3 based ceramics prepared through hot-press assisted liquid phase sintering10.1016/j.jeurceramsoc.2019.07.023 ↗
34. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta crystallographica section A: Crystal physics, diffraction, theoretical and general crystallography10.1107/S0567739476001551 ↗
35. Realizing high comprehensive energy storage performance in lead-free bulk ceramics via designing an unmatched temperature range10.1039/C9TA11314B ↗
36. The microstructure, dielectric abnormalities, polar order and microwave dielectric properties of Ag(Nb1-xTax)O3 (x = 0–0.8) ceramics10.1016/j.jeurceramsoc.2016.05.017 ↗
37. Local Structural Heterogeneity and Electromechanical Responses of Ferroelectrics: Learning from Relaxor Ferroelectrics10.1002/adfm.201801504 ↗
38. Phase transitions in bismuth-modified silver niobate ceramics for high power energy storage10.1039/C7TA03821F ↗