journal article·2024-09-29Open access

Aluminide Coatings by Means of Slurry Application: A Low Cost, Versatile and Simple Technology

Alina Agüero, Pauline Audigié, Marcos Gutiérrez, Cristina Lorente, Julio Mora, Sergio Rodríguez

Coatings· Volume 14· Issue 10

Abstract

The present study focused on demonstrating the versatility of the slurry deposition technique to produce aluminide coatings to protect components from high-temperature corrosion in a broad temperature range, from 400 to 1400 °C. This is a simpler and low-cost coating technology used as an alternative to CVD and pack cementation, which also allows the coating of complex geometries and offers improved and simple repairability for a lot of industrial applications, along with avoiding the use of non-hazardous components. Slurry aluminide coatings from a proprietary water-based-Cr6+ free slurry were produced onto four different substrates: A516 carbon steel, 310H AC austenitic steel, Ti6246 Ti-based alloy and TZM, a Mo-based alloy. The resulting coatings were thoroughly characterised by FESEM and XRD, mainly so that the identification of microstructures and appropriate phases was reported for each coating. The importance of surface preparation and heat treatment as key parameters for the coating final microstructures was also evidenced, and how those parameters can be optimised to obtain stable intermetallic phases rich in Al to sustain the formation of a protective Al2O3 oxide scale. These coating systems have applications in diverse industrial environments in which high-temperature corrosion limits the lifetime of the components.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · High-Temperature Coating Behaviors · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

INTA-Instituto Nacional de Técnica Aeroespacial, Área de Materiales Metálicos, Ctra. Ajalvir Km 4, 28850 Torrejón de Ardoz, Spain

Funding

Spanish Ministry of Sciences and Innovation · European Commission

References (66)

Show source-provided references
1. Zhang, Y. (2003). Aluminide Coatings for Power-Generation Applications, Oak Ridge National Lab. (ORNL).10.2172/885900 ↗
2. Grilli, M.L., Valerini, D., Slobozeanu, A.E., Postolnyi, B.O., Balos, S., Rizzo, A., and Piticescu, R.R. (2021). Critical Raw Materials Saving by Protective Coatings under Extreme Conditions: A Review of Last Trends in Alloys and Coatings for Aerospace Engine Applications. Materialsed, 14.10.3390/ma14071656 ↗
3. Long-term performance of aluminide coatings on Fe-base alloys10.1016/j.surfcoat.2007.06.046 ↗
4. Overview of surface engineering technology to improve the energy efficiency in concentrated solar power (CSP) plants10.1016/j.solmat.2024.113090 ↗
5. Diffusion aluminide coatings for TiAl intermetallic turbine blades10.1016/j.intermet.2010.12.015 ↗
6. Zeng, S., and Li, F. (2023). Research Status of Aluminum Base Coating on Titanium Alloy. Coatings, 13.10.20944/preprints202308.0337.v1 ↗
7. Performance of Al-rich oxidation resistant coatings for Fe-base alloys10.1002/maco.201005884 ↗
8. Advanced intermetallic iron aluminide coatings for high temperature applications10.1016/j.pmatsci.2020.100769 ↗
9. Mechanisms of formation of diffusion aluminide coatings on nickel-base superalloys10.1007/BF00604047 ↗
10. Advances in coating design for high-performance gas turbines10.1557/mrs2003.194 ↗
11. Oxidation and microstructure evolution of cobalt aluminide coatings on directionally solidified superalloys during long term exposure at 1000 °C10.1179/1432891714Z.000000000816 ↗
12. Cyclic oxidation behavior of Al-Si coating on new γ′-strengthened cobalt-based superalloy: Experimental study and first-principles calculation10.1016/j.corsci.2021.109422 ↗
13. Growth Kinetics and Isothermal Oxidation Behavior of Aluminide Pack Coatings on a Multiphase Mo–Si–B Alloy10.1007/s11085-019-09930-0 ↗
14. Corrosion properties of aluminized 16Mo3 steel10.2298/JMMB220927008K ↗
15. Mechanical Characterization Potentials of Aluminide Diffusion Coatings on Molybdenum Substrates10.1002/adem.202302027 ↗
16. Coatings for gas turbine materials and long term stability issues10.1016/j.matdes.2004.02.005 ↗
17. High-temperature cyclic oxidation behaviour of Pt-rich γ-γ’ coatings. Part I: Oxidation kinetics of coated AM1 systems after very long-term exposure at 1100 °C10.1016/j.corsci.2018.08.050 ↗
18. Progress on high-temperature protective coatings for aero-engines10.1007/s44251-023-00005-6 ↗
19. Metal Dusting Protective Coatings. A Literature Review10.1007/s11085-011-9248-4 ↗
20. Analysis of an aluminide coating on austenitic steel 800HT exposed to metal dusting conditions: Lessons from an industrial hydrogen production plant10.1016/j.ijpvp.2020.104129 ↗
21. Microstructural evolution of germanium modified AlSi-slurry coatings on alloy 600 at 620°C in metal dusting environment10.1016/j.surfcoat.2017.02.061 ↗
22. Steam Oxidation Resistance of Slurry Aluminum and Aluminum/Silicon Coatings on Steel for Ultrasupercritical Steam Turbines10.1007/s11085-017-9726-4 ↗
23. Agüero, A., Baraibar, I., Gutierrez, M., Tuurna, S., Toivonen, A., Pennila, S., and Auerkari, P. (2020). Steam Oxidation of Aluminide-Coated and Uncoated TP347HFG Stainless Steel under Atmospheric and Ultra-Supercritical Steam Conditions at 700 °C. Coatings, 10.10.3390/coatings10090839 ↗
24. Protective coatings for high temperature molten salt heat storage systems in solar concentration power plants10.1063/1.5067095 ↗
25. High temperature corrosion beneath carbonate melts of aluminide coatings for CSP application10.1016/j.solmat.2020.110514 ↗
26. Improving the corrosion resistance of ferritic-martensitic steels at 600 °C in molten solar salt via diffusion coatings10.1016/j.solmat.2021.111105 ↗
27. Aluminide coatings on Inconel 617 obtained by slurry method with inorganic binder
28. Berry, D., Meelu, M.C., McMordie, B.G., and Kircher, T.A. (1995, January 5–8). Enhancing Performance of Silicon-Modified Slurry Aluminides on Turbine Components Operating in Marine Environments. Proceedings of the ASME 1995 International Gas Turbine and Aeroengine Congress and Exposition, Houston, TX, USA.10.1115/95-GT-359 ↗
29. Performance of a silicon-modified aluminide coating in high temperature hot corrosion test conditions10.1016/0257-8972(94)90134-1 ↗
30. Overview of steam oxidation behaviour of Al protective oxide precursor coatings on P9210.1080/02670844.2016.1155691 ↗
31. Aluminide Protective Coatings Obtained by Slurry Method10.4028/www.scientific.net/MSF.782.590 ↗
32. Thermal cyclic resistance and long term inter-diffusion properties of slurry aluminide coatings modified with Si10.1016/j.rsurfi.2022.100042 ↗
33. Microstructure of diffusion aluminide coatings on Ti-base alloy IMI-834 and their cyclic oxidation behaviour at 650 °C10.1016/j.msea.2003.10.196 ↗
34. Kochmańska, A.E., Jarlaczyńska, A., and Baranowska, J. (2021). Formation of Silicide and Silicide-Aluminide Coatings on Molybdenum Alloy during Slurry Cementation Process: Influence of Slurry Volume. Materials, 14.10.3390/ma14226940 ↗
35. 10,000 h molten salt corrosion testing on IN617, uncoated and aluminide ferritic steels at 580 °C10.1063/5.0028930 ↗
36. Superior corrosion resistance of a slurry FeAl coating on 316LN stainless steel in 550 °C liquid lead-bismuth eutectic10.1016/j.corsci.2023.111757 ↗
37. Behavior of Slurry Aluminized Austenitic Stainless Steels under Steam at 650 and 700 °C10.1007/s11085-017-9725-5 ↗
38. (2024, September 04). ArcelorMittal Asturias en Avilés | ArcelorMittal España. Available online: https://spain.arcelormittal.com/.
39. (2024, September 04). Alleima® 7RE10—Alleima. Available online: https://www.alleima.com/en/products/.
40. (2024, September 04). 6246—Aubert & Duval English. Available online: www.aubertduval.com.
41. (2024, September 04). Molybdenum Alloys | Goodfellow—TZM Molybdenum Alloy | Material: TZM Molybdenum Alloy. Available online: https://www.fonlinkmetal.com/products/molybdenum/tzm_alloy_and_piercing_plug.html?gad_source=1&gclid=EAIaIQobChMI1ezQy77fiAMVpqpmAh2PFTD9EAAYAyAAEgJqXvD_BwE.
42. Comparison between pilot and lab scale testing of aluminide coated and uncoated ferritic steels under oxy-fuel and coal/thistle co-firing conditions10.1016/j.surfcoat.2022.128982 ↗
43. High-temperature corrosion behaviour of metal alloys in commercial molten salts10.1016/j.solener.2020.03.010 ↗
44. (2022, August 03). Applicability & Allowable Stress of ASTM A516 Gr.70. Available online: www.metalspiping.com.
45. Molten Salts and Applications II: 565 °C Molten Salt Solar Energy Storage Design, Corrosion, and Insulation
46. Microstructural Evolution of Slurry Fe Aluminide Coatings during High Temperature Steam Oxidation
47. Du, H., Tan, N., Fan, L., Zhuang, J., Qiu, Z., and Lei, Y. (2019). Formation Mechanism of Aluminide Diffusion Coatings on Ti and Ti-6Al-4V Alloy at the Early Stages of Deposition by Pack Cementation. Materialsed, 12.10.3390/ma12193097 ↗
48. General mass balance for oxygen steelmaking10.1080/03019233.2020.1731252 ↗
49. (2024, September 01). Acero inoxidable 310/310S/310H, aleación 310 (UNS S31000/S31008/S31009) (allianzsteel.com). Available online: https://es.allianzsteel.com/serve/stainless-steel-310-310s-310h.html.
50. Audigié, P., Rodríguez, S., and Agüero, A. (2024). Improved Corrosion Resistance of Slurry Coated Austenitic Steel in Molten Carbonates Doped with Nanoparticles for Thermal Energy Storage Technologies. Poster Commun.
51. The Fe–Ni–Al phase diagram in the Al-rich (>50at.% Al) corner10.1016/j.intermet.2007.04.012 ↗
52. Microstructure of Al-Si Slurry Coatings on Austenitic High-Temperature Creep Resisting Cast Steel10.1155/2018/5473079 ↗
53. Titanium for aerospace: Rationale and applications10.1007/BF00705316 ↗
54. An overview on the use of titanium in the aerospace industry10.1016/0921-5093(96)10233-1 ↗
55. Titanium alloys for aerospace applications10.1002/adem.200310095 ↗
56. Classification and applications of titanium and its alloys: A review
57. Study of titanium alloy Ti6242S oxidation behaviour in air at 560 °C: Effect of oxygen dissolution on lattice parameters10.1016/j.corsci.2019.06.004 ↗
58. Školáková, A., Salvetr, P., Leitner, J., Lovaši, T., and Novák, P. (2020). Formation of Phases in Reactively Sintered TiAl3 Alloy. Molecules, 25.10.3390/molecules25081912 ↗
59. Interfacial microstructure evolution mechanism of high temperature oxidation-resistant Al-based coating on Ti alloy surface10.1088/2053-1591/ab2a66 ↗
60. Oxidation behaviour of TiAl3 coatings and alloys10.1016/0010-938X(93)90340-M ↗
61. Finite element analysis of thermal stresses in Ti-Al3Ti metal-intermetallic laminated composites10.1016/j.rinp.2019.102706 ↗
62. A novel TiAl3/Al2O3 composite coating on γ-TiAl alloy and evaluating the oxidation performance10.1016/j.apsusc.2015.11.155 ↗
63. Preparation of TZM alloy by aluminothermic smelting and its characterization10.1016/j.jallcom.2004.09.055 ↗
64. Oxidation and volatilization of TZM alloy in air10.1016/S0022-3115(00)00303-2 ↗
65. MoSi2 coating on Mo substrate for short-term oxidation protection in air10.1016/j.jallcom.2009.07.141 ↗
66. Long exposure steam oxidation testing and mechanical properties of slurry aluminide coatings for steam turbine components10.1016/j.surfcoat.2005.07.080 ↗