Superhydrophilic Surface Creation and Its Temporal Transition to Hydrophobicity on Copper via Femtosecond Laser Texturing
Source abstract
Abstract
We analyzed a process to fabricate a superhydrophilic surface on copper by forming various laser-induced periodic surface structures (LIPSS) using a Ti/sapphire femtosecond laser. For these structured surfaces, the correlation between the surface structure and the wetting characteristics was analyzed by scanning electron microscopy, atomic force microscopy, and contact angle (CA) measurement. X-ray photoelectron spectroscopy (XPS) was also employed to analyze variation of the elemental composition of the surfaces. The laser treatment produced micro/nanostructures composed of ripples whose length and width are in microscale and nanoscale, respectively. At specific conditions, the CA of a water droplet was reduced to less than 1°. The superhydrophilcity is attributed to the effect of nanoholes and nanoclusters, which consist of copper (II) oxide and copper hydroxide, having a hydrophilic effect on LIPSS. However, the pristine superhydrophilic surface spontaneously became hydrophobic after being exposed to air at room temperature for about 10 days. According to XPS analysis, the surface’s transition to hydrophobic is attributed not only to the decomposition of Cu(OH)2 but also to the adsorption of oxygen molecules and/or airborne organic molecules containing carbon, which further influences the wettability.
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Research context
OpenAlex topics: Surface Modification and Superhydrophobicity · Laser Material Processing Techniques · Adhesion, Friction, and Surface Interactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Smart Forming Process Group, Korea Institute of Industrial Technology (KITECH), Ulsan 44776, Republic of Korea
Funding
Ministry of Science and ICT · Commercialization Promotion Agency for R&D Outcomes (COMPA) · Korea Institute of Industrial Technology
References (57)
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