Crosslinked Polymer Coatings of Poly (Acrylic Acid-co-acrylamide)/Polyethyleneimine (P(AA-co-AAm)/PEI) on Titanium Alloy with Excellent Lubrication Performance for Artificial Joints
Source abstract
Abstract
The development of coatings with efficient lubrication and load-bearing capacity is an urgent need for artificial joints. Here, we successfully fabricated poly (acrylic acid-co-acrylamide)/polyethyleneimine (P(AA-co-AAm)/PEI) coating on titanium alloy (Ti6Al4V) surface via UV irradiation and thermal treatment technique. The dual crosslinked network structures were composed of a P(AA-co-AAm) network via free radical polymerization and a PAA-co-PEI network via thermal crosslinking of amine and carboxyl groups. The thermally crosslinked P(AA-co-AAm)/PEI coatings exhibit a stable low friction coefficient (approximately 0.022) and exceptionally low wear volume, with a 93.8% and 92.6% reduction, respectively, in comparison to the pristine Ti6Al4V. These thermally crosslinked P(AA-co-AAm)/PEI hydrogel coatings exhibit excellent lubrication and anti-wear properties, providing a strategy for developing novel lubricating coatings in the biomedical field.
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Research context
OpenAlex topics: Tribology and Wear Analysis · Orthopaedic implants and arthroplasty · Polymer Surface Interaction Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Intelligent Science and Control Engineering, Jinling Institute of Technology, Nanjing 211169, China
State Key Laboratory of Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China
College of Life Sciences, Xinyang Normal University (XYNU), Xinyang 464000, China
Funding
Natural Science Foundation of Jiangsu Province · Nanhu Scholars Program for Young Scholars of XYNU · High-Level Talents Program of Jinling Institute of Technology · research fund of State Key Laboratory of Organic Electronics and Information Displays
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