Recent Advances in Metal–Organic Frameworks for the Surface Modification of the Zinc Metal Anode: A Review
Source abstract
Abstract
Aqueous zinc ion batteries (AZIBs) are considered as one of the most promising energy storage technologies due to their advantages of being low in cost, high in safety, and their environmental friendliness. However, dendrite growth and parasitic side reactions on the zinc metal anode during cycling lead to a low coulombic efficiency and an unsatisfactory lifespan, which seriously hinders the further development of AZIBs. In this regard, metal–organic frameworks (MOFs) are deemed as suitable surface modification materials for the Zn anode to deal with the abovementioned problems because of their characteristics of a large specific surface area, high porosity, and excellent tunability. Considering the rapidly growing research enthusiasm for this topic in recent years, herein, we summarize the recent advances in the design, fabrication, and application of MOFs and their derivatives in the surface modification of the zinc metal anode. The relationships between nano/microstructures, synthetic methods of MOF-based materials, and the enhanced electrochemical performance of the zinc metal anode via MOF surface modification are systematically summarized and discussed. Finally, the existing problems and future development of this area are proposed.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advanced battery technologies research · Advancements in Battery Materials · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Henan Key Laboratory of Non-Ferrous Materials Science & Processing Technology, School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China
Longmen Laboratory, Luoyang 471023, China
Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Henan University of Science and Technology, Luoyang 471023, China
Funding
National Key Research and Development Program of China · Open Fund of State Key Laboratory of Advanced Refractories · Student Research Training Plan of Henan University of Science and Technology · Undergraduate Innovation and Entrepreneurship Training Program of Henan Province
References (91)
Show source-provided references
1. Recent advances in MOFs/MOF derived nanomaterials toward high-efficiency aqueous zinc ion batteries10.1016/j.ccr.2022.214642 ↗
2. Opportunities and challenges for a sustainable energy future10.1038/nature11475 ↗
3. The matter of a clean energy future10.1126/science.add5094 ↗
4. Emerging bismuth-based materials: From fundamentals to electrochemical energy storage applications10.1016/j.ensm.2023.03.023 ↗
5. Metal-Organic Frameworks for Energy Applications10.1016/j.chempr.2016.12.002 ↗
6. Electrical energy storage for transportation-approaching the limits of, and going beyond, lithium-ion batteries10.1039/c2ee21892e ↗
7. From anode to cell: Synergistic protection strategies and perspectives for stabilized Zn metal in mild aqueous electrolytes10.1016/j.ensm.2022.11.006 ↗
8. Recent progress in Co-based metal-organic framework derivatives for advanced batteries10.1016/j.jmst.2021.04.033 ↗
9. Review of electrical energy storage technologies, materials and systems: Challenges and prospects for large-scale grid storage10.1039/C8EE01419A ↗
10. Application of Ag-based materials in high-performance lithium metal anode: A review10.1016/j.jmst.2022.06.015 ↗
11. Synthesis and application of single-atom catalysts in sulfur cathode for high-performance lithium-sulfur batteries10.1016/j.cclet.2022.01.014 ↗
12. Electrochemical energy storage for green grid10.1021/cr100290v ↗
13. Shining light on transition metal tungstate-based nanomaterials for electrochemical applications: Structures, progress, and perspectives10.1007/s12274-022-4581-2 ↗
14. Si-based materials derived from biomass: Synthesis and applications in electrochemical energy storage10.1039/C9TA06934H ↗
15. Recent advances and perspective in metal coordination materials-based electrode materials for potassium-ion batteries10.1007/s12598-020-01649-1 ↗
16. Challenges in the development of advanced Li-ion batteries: A review10.1039/c1ee01598b ↗
17. Challenges for Rechargeable Li Batteries10.1021/cm901452z ↗
18. Nanomaterials for rechargeable lithium batteries10.1002/anie.200702505 ↗
19. Review—Meta-Review of Fire Safety of Lithium-Ion Batteries: Industry Challenges and Research Contributions10.1149/1945-7111/aba8b9 ↗
20. An amorphous ZnO and oxygen vacancy modified nitrogen-doped carbon skeleton with lithiophilicity and ionic conductivity for stable lithium metal anodes10.1039/D2TA03706H ↗
21. Materials chemistry for rechargeable zinc-ion batteries10.1039/C9CS00349E ↗
22. Pathways towards high energy aqueous rechargeable batteries10.1016/j.ccr.2020.213521 ↗
23. Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte10.1038/nchem.763 ↗
24. Graphene-based interlayer for high-performance lithium–sulfur batteries: A review10.1016/j.matdes.2021.110171 ↗
25. From room temperature to harsh temperature applications: Fundamentals and perspectives on electrolytes in zinc metal batteries10.1126/sciadv.abn5097 ↗
26. Energetic zinc ion chemistry: The rechargeable zinc ion battery10.1002/anie.201106307 ↗
27. Achieving both high reversible and stable Zn anode by a practical glucose electrolyte additive toward high-performance Zn-ion batteries10.1007/s12598-021-01858-2 ↗
28. Recent advances in zinc anodes for high-performance aqueous Zn-ion batteries10.1016/j.nanoen.2020.104523 ↗
29. High ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries10.1016/j.cclet.2022.07.046 ↗
30. A review on recent developments of vanadium-based cathode for rechargeable zinc-ion batteries10.1007/s42864-021-00091-9 ↗
31. Dendrites in Zn-Based Batteries10.1002/adma.202001854 ↗
32. Toward Hydrogen-Free and Dendrite-Free Aqueous Zinc Batteries: Formation of Zincophilic Protective Layer on Zn Anodes10.1002/advs.202104866 ↗
33. Issues and opportunities facing aqueous zinc-ion batteries10.1039/C9EE02526J ↗
34. Immunizing Aqueous Zn Batteries against Dendrite Formation and Side Reactions at Various Temperatures via Electrolyte Additives10.1002/smll.202103195 ↗
35. Functional Separators Regulating Ion Transport Enabled by Metal-Organic Frameworks for Dendrite-Free Lithium Metal Anodes10.1002/adfm.202102938 ↗
36. In situ growth of S-doped ZnO thin film enabling dendrite-free zinc anode for high-performance aqueous zinc-ion batteries10.1016/j.jallcom.2022.165486 ↗
37. Inhibiting corrosion and side reactions of zinc metal anode by nano-CaSiO3 coating towards high-performance aqueous zinc-ion batteries10.1088/1361-6528/aca1cd ↗
38. 3D Porous Copper Skeleton Supported Zinc Anode toward High Capacity and Long Cycle Life Zinc Ion Batteries10.1021/acssuschemeng.8b05568 ↗
39. Liu, Y., Tao, F., Xing, Y., Pei, Y., and Ren, F. (2023). Melamine Foam-Derived Carbon Scaffold for Dendrite-Free and Stable Zinc Metal Anode. Molecules, 28.10.3390/molecules28041742 ↗
40. Different surface modification methods and coating materials of zinc metal anode10.1016/j.jechem.2021.08.022 ↗
41. Suppressing interfacial side reactions of zinc metal anode via isolation effect toward high-performance aqueous zinc-ion batteries10.1007/s12274-022-5270-x ↗
42. Intrinsically zincophobic protective layer for dendrite-free zinc metal anode10.1016/j.cclet.2021.09.083 ↗
43. Metal–organic frameworks for energy storage: Batteries and supercapacitors10.1016/j.ccr.2015.09.002 ↗
44. Hybrid porous solids: Past, present, future10.1039/B618320B ↗
45. Metal-organic frameworks for direct electrochemical applications10.1016/j.ccr.2018.08.010 ↗
46. Recent Progress in Metal-Organic Frameworks and Their Derived Nanostructures for Energy and Environmental Applications10.1002/cssc.201601855 ↗
47. Cobalt-based metal organic framework with superior lithium anodic performance10.1016/j.jssc.2016.07.021 ↗
48. A novel spitball-like Co3(NO3)2(OH)4@Zr-MOF@RGO anode material for sodium-ion storage10.1016/j.jallcom.2019.153624 ↗
49. Layered nickel metal–organic framework for high performance alkaline battery-supercapacitor hybrid devices10.1039/C6TA05384J ↗
50. Constructing a Super-Saturated Electrolyte Front Surface for Stable Rechargeable Aqueous Zinc Batteries10.1002/anie.202001844 ↗
51. In Situ Growth of a Metal–Organic Framework-Based Solid Electrolyte Interphase for Highly Reversible Zn Anodes10.1021/acsenergylett.2c01958 ↗
52. Anion-functionalized interfacial layer for stable Zn metal anodes10.1016/j.nanoen.2022.107751 ↗
53. Amorphous MOF as smart artificial solid/electrolyte interphase for highly-stable Zn-ion batteries10.1016/j.cej.2023.142270 ↗
54. Metal-Organic Framework-Based Materials for Aqueous Zinc-Ion Batteries: Energy Storage Mechanism and Function10.1002/tcr.202200079 ↗
55. Metal-organic framework (MOF) composites as promising materials for energy storage applications10.1016/j.cis.2022.102732 ↗
56. Metal organic framework (MOF) in aqueous devices10.1016/j.mattod.2021.03.011 ↗
57. Stable Metal-Organic Frameworks with Group 4 Metals: Current Status and Trends10.1021/acscentsci.8b00073 ↗
58. Metal-organic frameworks for food contaminant adsorption and detection10.3389/fchem.2023.1116524 ↗
59. Electrospray ionization mass spectrometric solvate cluster and multiply charged ions: A stochastic dynamic approach to 3D structural analysis10.1007/s42452-020-2555-0 ↗
60. In situ observations of liquid–liquid phase separation in aqueous ZnSO4 solutions at temperatures up to 400 °C: Implications for Zn2+–SO42− association and evolution of submarine hydrothermal fluids10.1016/j.gca.2016.03.001 ↗
61. Zeolitic Imidazolate Frameworks as Zn2+ Modulation Layers to Enable Dendrite-Free Zn Anodes10.1002/advs.202002173 ↗
62. Building a seamless water-sieving MOF-based interphase for highly reversible Zn metal anodes10.1016/j.cej.2022.140510 ↗
63. A Seamless Metal–Organic Framework Interphase with Boosted Zn2+ Flux and Deposition Kinetics for Long-Living Rechargeable Zn Batteries10.1021/acs.nanolett.2c04410 ↗
64. MOF-based ionic sieve interphase for regulated Zn2+ flux toward dendrite-free aqueous zinc-ion batteries10.1039/D1TA10245A ↗
65. Uniform In Situ Grown ZIF-L Layer for Suppressing Hydrogen Evolution and Homogenizing Zn Deposition in Aqueous Zn-Ion Batteries10.1021/acsami.2c11313 ↗
66. Demonstrating U-shaped zinc deposition with 2D metal-organic framework nanoarrays for dendrite-free zinc batteries10.1016/j.ensm.2022.06.005 ↗
67. Design principles of MOF-related materials for highly stable metal anodes in secondary metal-based batteries10.1016/j.mtener.2020.100608 ↗
68. Advances of Electroactive Metal–Organic Frameworks10.1002/smll.202207547 ↗
69. Metal-Organic Framework Integrated Anodes for Aqueous Zinc-Ion Batteries10.1002/aenm.201904215 ↗
70. Two-dimensional CuO nanosheets-induced MOF composites and derivatives for dendrite-free zinc-ion batteries10.1007/s12274-023-5424-x ↗
71. A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability10.1021/ja8057953 ↗
72. Surface coatings of two-dimensional metal-organic framework nanosheets enable stable zinc anodes10.1007/s11426-022-1324-0 ↗
73. Artificial Solid-Electrolyte Interface Facilitating Dendrite-Free Zinc Metal Anodes via Nanowetting Effect10.1021/acsami.9b11243 ↗
74. Understanding the modifications and applications of highly stable porous frameworks via UiO-6610.1016/j.mtchem.2018.12.004 ↗
75. A comprehensive review on water remediation using UiO-66 MOFs and their derivatives10.1016/j.chemosphere.2022.134845 ↗
76. Metal–organic framework for dendrite-free anodes in aqueous rechargeable zinc batteries10.1016/j.electacta.2022.140648 ↗
77. Self-supported three-dimensional macroporous amorphous NiFe bimetallic-organic frameworks for enhanced water oxidation10.1016/j.apsusc.2021.149323 ↗
78. Amorphous Metal–Organic Frameworks10.1021/ar5000314 ↗
79. Quasi-Solid Electrolyte Interphase Boosting Charge and Mass Transfer for Dendrite-Free Zinc Battery10.1007/s40820-023-01031-7 ↗
80. Highly Stable Zn Anodes Modulated by Selenizing In Situ Grown Metal-Organic Frameworks10.1021/acs.jpcc.2c07850 ↗
81. Hydrophobic Organic-Electrolyte-Protected Zinc Anodes for Aqueous Zinc Batteries10.1002/anie.202008634 ↗
82. Angstrom-Level Ionic Sieve 2D-MOF Membrane for High Power Aqueous Zinc Anode10.1002/adfm.202300339 ↗
83. In Situ Construction of High-Density Solid Electrolyte Interphase from MOFs for Advanced Zn Metal Anodes10.1002/adfm.202301530 ↗
84. Missing-linker bifunctional MIL-125(Ti)-Zn interface modulation layer to simultaneously suppress hydrogen evolution reaction and dendrites for Zn metal anodes10.1016/j.ensm.2022.09.014 ↗
85. MOF-derived defect-rich CeO2 as ion-selective smart artificial SEI for dendrite-free Zn-ion battery10.1016/j.cej.2022.138769 ↗
86. Advances in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives for anode of lithium-ion batteries10.1016/j.ccr.2020.213221 ↗
87. Recent advances in titanium metal–organic frameworks and their derived materials: Features, fabrication, and photocatalytic applications10.1016/j.cej.2020.125080 ↗
88. Designing Atomic Active Centers for Hydrogen Evolution Electrocatalysts10.1002/anie.201914647 ↗
89. Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution10.1039/C3CS60468C ↗
90. Corrosion protective ability of electrodeposited ceria layers10.1007/s10008-012-1937-7 ↗
91. Chemical composition and corrosion protection of silane films modified with CeO2 nanoparticles10.1016/j.electacta.2009.01.053 ↗