Effect of W Content on Microstructure and Properties of Laser Cladding CoCrFeNi HEA Coating
Source abstract
Abstract
The 316L SS surfaces were prepared with CoCrFeNi HEA/W-composite coatings using the laser cladding technique with various mass fractions of W. The mass fractions of W were 10, 20, 30, and 40%. The microstructure of the HEA/W-composite coatings was investigated using a variety of characterization methods. According to the results, the samples were in the BBC phase. In the SEM images, a solid–liquid bonding layer was observed, which indicates the samples had good metallurgical bonding. The W particles prevented the orderly growth of the HEA grains, and a significant refinement of the grains around the W particles occurred. The lattice constants measured by XRD mapping indicate that adding W particles to CoCrFeNi HEA leads to lattice distortion. The hardness of the HEA/W coatings was substantially higher than the substrate and the pure CoCrFeNi coating by hardness measurements and was greatest at a W content of 40%. The hardness of the HEA/W coatings was significantly increased compared to the substrate and the pure CoCrFeNi coating by hardness measurements and was greatest at a W content of 40%. The HEA/W coating was tested for electrochemical corrosion, and a 10% mass fraction of W achieved the highest level of corrosion resistance.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: High Entropy Alloys Studies · Additive Manufacturing Materials and Processes · High-Temperature Coating Behaviors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Electronics and Information Engineering, Guangdong Ocean University, Zhanjiang 524088, China
Funding
national natural science foundation projects · Laser processing team project of Guangdong Ocean University
References (43)
Show source-provided references
1. Wear mechanisms and micro-evaluation on WC particles investigation of WC-Fe composite coatings fabricated by laser cladding10.1016/j.surfcoat.2021.127341 ↗
2. A Analytical modeling of insitude formation of part and substrate in laser cladding additive manufacturing of Inconel 62510.1016/j.jmapro.2019.11.013 ↗
3. Laser cladding and interface evolutions of inconel 625 alloy on low alloy steel substrate upon heat and chemical treatments10.1016/j.surfcoat.2020.126607 ↗
4. Recent research and development status of laser cladding: A review10.1016/j.optlastec.2021.106915 ↗
5. Microstructure mechanical and biological properties of laser cladding derived CaO-SiO2-MgO system ceramic coatings on titanium alloys10.1016/j.apsusc.2021.149296 ↗
6. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes10.1002/adem.200300567 ↗
7. Anomalous decrease in X-ray diffraction intensities of Cu-Ni-Al-Co-Cr-Fe-Si alloy systems with multi-principal elements10.1016/j.matchemphys.2007.01.003 ↗
8. High-entropy alloy: Challenges and prospects10.1016/j.mattod.2015.11.026 ↗
9. Design of high entropy alloys: A single parameter thermodynamic rule10.1016/j.scriptamat.2015.03.023 ↗
10. Microstructures and properties of high-entropy alloys10.1016/j.pmatsci.2013.10.001 ↗
11. A fracture-resistant high-entropy alloy for cryogenic applications10.1126/science.1254581 ↗
12. The effect of boron on the corrosion resistance of the high entropy alloys Al0.5CoCrCuFeNiBx10.1149/1.2744133 ↗
13. Effect of aluminum on the microstructure and properties of two refractory high entropy alloys10.1016/j.actamat.2014.01.029 ↗
14. CoCrFeNi(W1 x Mox) high-entropy alloy coatings with excellent mechanical properties and corrosion resistance prepared by mechanical alloying and hot pressing sintering10.1016/j.matdes.2016.12.076 ↗
15. Effects of Fe-to-Co ratio on microstructure and mechanical properties of laser cladded FeCoCrBNiSi high-entropy alloy coatings10.1016/j.apsusc.2018.03.128 ↗
16. The effect of Co and Cr substitutions for Ni on mechanical properties and plastic deformation mechanism of FeMnCoCrNi high entropy alloys10.1016/j.jmst.2020.03.010 ↗
17. Laser cladding of CoCrFeNi high-entropy alloy coatings: Compositional homogeneity towards improved corrosion resistance10.1016/j.matlet.2022.132133 ↗
18. Comparison of CoCrFeNi coatings prepared via high-speed laser cladding and normal laser cladding on microstructure and properties10.1016/j.intermet.2022.107795 ↗
19. Superior corrosion resistance-dependent laser energy density in (CoCrFeNi)95Nb5 high entropy alloy coating fabricated by laser cladding10.1007/s12613-020-2238-2 ↗
20. Microstructure and properties of in-situ TiN reinforced laser cladding CoCr2FeNiTix high-entropy alloy composite coatings10.1016/j.surfcoat.2018.03.035 ↗
21. Direct laser deposition cladding of AlxCoCrFeNi high entropy alloys on a high-temperature stainless steel10.1016/j.surfcoat.2017.09.072 ↗
22. Synergistic strengthening of FeCrNiCo high entropy alloys via micro-TiC and nano-SiC particles10.1016/j.mtcomm.2020.101729 ↗
23. Huang, J., Zhu, Z.K., Wang, H., Li, K.Y., Shi, W.Q., and Jiao, T.W. (2023). Effect of WC Content on Microstructure and Properties of CoCrFeNi HEA Composite Coating on 316L Surface via Laser Cladding. Materials, 16.10.3390/ma16072706 ↗
24. A prismatic substructure formed during solidification of metals10.1139/p53-003 ↗
25. Microstructures and mechanical properties of FeCoCrNi high entropy alloy/WC reinforcing particles composite coatings prepared by laser cladding and plasma cladding10.1016/j.ijrmhm.2019.105044 ↗
26. Effect of microstructure on the corrosion resistance of coatings by extreme high speed laser cladding10.1016/j.apsusc.2020.146085 ↗
27. Effect of WC content on microstructures and mechanical properties of FeCoCrNi high entropy alloy/WC composite coatings by laser cladding and plasma cladding10.1016/j.surfcoat.2019.125326 ↗
28. Microstructure and phase transformation of WC/Ni60B laser cladding coatings during dry sliding wear10.1016/j.wear.2007.01.132 ↗
29. Laser cladding of stainless steel with Ni–Cr3C2 and Ni–WC for improving erosive–corrosive wear performance10.1016/j.surfcoat.2004.03.018 ↗
30. Mechanism and control of the nick-based alloy WC laser cladded layer microstructure
31. Mechanical and chemical properties of CoCrFeNiMo0.2 high entropy alloy coating fabricated on Ti6Al4V by laser cladding10.1016/j.intermet.2022.107504 ↗
32. On enhancing wear resistance of titanium alloys by laser cladded WC-Co composite coatings10.1016/j.ijrmhm.2022.105902 ↗
33. Microstructure and properties of laser cladding and CoCr2.5FeNi2Tix high-entropy alloy composite coatings10.1016/j.jallcom.2019.152986 ↗
34. Microstructure and wear resistance of AlCoCrFeNi-WC/TiC composite coating by laser cladding10.1016/j.matchar.2022.112479 ↗
35. Lattice distortion as an estimator of solid solution strengthening in high-entropy alloys10.1016/j.matchar.2021.110877 ↗
36. Microstructure and mechanical properties of grapheme reinforced Fe50Mn30Co10Cr10, high-entropy alloy composites synthesized by MA and SPS10.1007/s00339-017-1151-7 ↗
37. In-situ alloyed, oxide-dispersionstrengthened CoCrFeMnNi high entropy alloy fabricated via laser powder bed fusion10.1016/j.matdes.2020.108966 ↗
38. A perspective on precipitation-hardening high-entropy alloys fabricated by additive manufacturing10.1016/j.matdes.2021.110161 ↗
39. Corrosion monitoring for prestressed concrete cylinder pipe spigot with combined use of Tafel extrapolation and surface acoustic wave methods10.1016/j.conbuildmat.2022.127572 ↗
40. Effect of molybdenum on the corrosion behavior of high entropy alloys CoCrFeNi2 and CoCrFeNi2Mo0.25 under sodium chloride aqueous conditions10.1155/2018/3016304 ↗
41. High-temperature oxidation behavior and corrosion resistance of in-situ TiC and Mo reinforced AlCoCrFeNi-based high entropy alloy coatings by laser cladding10.1016/j.ceramint.2022.11.198 ↗
42. Laser cladding highly corrosion-resistant nano/submicron ultrafine-grained Fe-based composite layers10.1016/j.surfcoat.2021.127636 ↗
43. Microstructural evolution and corrosion behavior of CoCrFeNiAlxMn(1 − x) dual-phase high-entropy alloy coatings prepared by laser cladding10.1016/j.jallcom.2021.161251 ↗