journal article·2024-03-25Open access

Controlled Synthesis of Mg-MOF-74 and Its CO2 Adsorption in Flue Gas

Chunling Xin, Shufen Hou, Lei Yu, Xiaojing Zhou, Yunkai Fu, Xiaoteng Yang, Weiwei Sun, Fan Yang, Xia Wang, Lili Liu

Coatings· Volume 14· Issue 4

Abstract

Yellow nanorod Mg-MOF-74 was obtained through a solvothermal synthesis method. The XRD, N2 adsorption–desorption isotherms, SEM, and TGA results suggest that the particle size of Mg-MOF-74 reaches 400 nm after the introduction of sodium acetate in the precursor of Mg-MOF-74. Furthermore, the morphology of Mg-MOF-74 changed from cauliflower- to rod-shaped particles. At the same time, the BET specific surface area and pore volume of Mg-MOF-74 also increased a lot. Then, the CO2 dynamic adsorption capacity of Mg-MOF-74 was measured with a self-made fixed bed at 30 °C and a 0.1 bar CO2 partial pressure. The results show that the CO2 adsorption capacity of Mg-MOF-74-N2 reaches 3.67 mmol/g, and its CO2 adsorption capacity remains unchanged after 10 CO2 adsorption–desorption cycles.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Carbon Dioxide Capture Technologies · Membrane Separation and Gas Transport

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry and Chemical & Environmental Engineering, Weifang University, Weifang 261061, China

Funding

National Natural Science Foundation of China

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