Experimental Study on Anti-Icing of Robust TiO2/Polyurea Superhydrophobic Coating
Source abstract
Abstract
This study aims to solve the icing problem of wind turbine blades in low-temperature environments and to improve the power generation efficiency of wind turbines. In this study, modified TiO2 particles (500 nm), butyl acetate solvent, polyaspartic acid ester polyurea (PAE polyurea), and Crestron N75 curing agent were mixed and sprayed on the epoxy resin board surface. Static icing test, dynamic icing test, wear resistance test, and icing adhesion strength test studies were carried out to evaluate the anti-icing performance of the coating as well as its mechanical stability. The results showed that the mechanical stability and anti-icing performance of the coating were relatively optimal when the ratio of modified TiO2 particles to PAE polyurea was 1.5. Under this ratio, the static contact angle of the coating was 161.4°, and the rolling angle was 4.7°. The main reason for the superhydrophobic performance after 250 wear cycles was that the TiO2 particles were encapsulated by PAE polyurea. The static contact angle of the coating was still greater than 150° after eight icing–de-icing cycles. This paper provides a simple method to prepare a robust superhydrophobic coating and promotes the application of superhydrophobic coatings in the field of passive anti-icing of wind turbine blades.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Icing and De-icing Technologies · Surface Modification and Superhydrophobicity · Aerodynamics and Fluid Dynamics Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Faculty of Electrical Engineering, Xinjiang University, 777 Huarui Street, Urumqi 830017, China
Beijing Key Laboratory of Power Generation System Functional Material, CHN Energy New Energy Technology Research Institute Ltd., Beijing 102209, China
Funding
Science and Technology Department of Xinjiang Uygur Autonomous Region
References (49)
Show source-provided references
1. A holistic approach to the assessment of the groundwater destructive effects on stone decay in Edfu temple using AAS, SEM-EDX and XRD10.1007/s12665-015-4849-x ↗
2. Wind turbine blade ice accretion: A correlation with nacelle ice accretion10.1016/j.coldregions.2018.10.009 ↗
3. Volpe, A., Gaudiuso, C., and Ancona, A. (2020). Laser fabrication of anti-icing surfaces: A review. Materials, 13.10.3390/ma13245692 ↗
4. Applications of superhydrophobic coatings in anti-icing: Theory, mechanisms, impact factors, challenges and perspectives10.1016/j.porgcoat.2020.106117 ↗
5. Hot-air anti-icing heat transfer and surface temperature modeling10.2514/1.J059776 ↗
6. Slippery liquid-infused porous electric heating coating for anti-icing and de-icing applications10.1016/j.surfcoat.2019.06.077 ↗
7. Novel sandwich structural electric heating coating for anti-icing/de-icing on complex surfaces10.1016/j.surfcoat.2020.126489 ↗
8. Superhydrophobic anti-icing coatings with self-deicing property using melanin nanoparticles from cuttlefish juice10.1016/j.cej.2021.130553 ↗
9. Moth-eye-inspired texturing surfaces enabled self-cleaning aluminum to achieve photothermal anti-icing10.1016/j.optlastec.2021.107115 ↗
10. Facilely fabricated self-lubricated photothermal coating with long-term durability and external-replenishing property for anti-icing/deicing10.1021/acsami.1c21220 ↗
11. A survey of icephobic coatings and their potential use in a hybrid coating/active ice protection system for aerospace applications10.1016/j.paerosci.2019.01.002 ↗
12. Hydrothermally structured superhydrophobic surface with superior anti-corrosion, anti-bacterial and anti-icing behaviors10.1016/j.colsurfa.2021.126820 ↗
13. Multifunctional Ti3C2TX MXene-Based Composite Coatings with Superhydrophobic Anti-Icing and Photothermal Deicing Properties10.1021/acsami.2c07087 ↗
14. When superhydrophobic coatings are icephobic: Role of surface topology10.1016/j.surfcoat.2018.11.039 ↗
15. Three-dimensional capillary ratchet-induced liquid directional steering10.1126/science.abg7552 ↗
16. Anti-icing and de-icing techniques for wind turbines: Critical review10.1016/j.coldregions.2010.01.005 ↗
17. Super-hydrophobic cesium lead halide perovskite quantum dot-polymer composites with high stability and luminescent efficiency for wide color gamut white light-emitting diodes10.1021/acs.chemmater.8b04596 ↗
18. Thermal annealing as a new simple method for PTFE texturing10.1016/j.polymer.2013.08.011 ↗
19. Fabrication of PVDF nanofibrous hydrophobic composite membranes reinforced with fabric substrates via electrospinning for membrane distillation desalination10.1016/j.jes.2018.04.002 ↗
20. Preparation and anti-icing of hydrophobic polypyrrole coatings on wind turbine blade10.1155/2020/8626457 ↗
21. Karmouch, R., Coudé, S., Abel, G., and Ross, G.G. (2009, January 22–23). Icephobic PTFE coatings for wind turbines operating in cold climate conditions. Proceedings of the 2009 IEEE Electrical Power & Energy Conference (EPEC), Montreal, QC, Canada.10.1109/EPEC.2009.5420897 ↗
22. Polyurea—The New Generation of Lining and Coating10.4028/www.scientific.net/AMR.95.85 ↗
23. Effects of additives, pigment and filler on physico-mechanical properties and weather resistance of polyurea coatings10.15625/2525-2518/55/5B/12221 ↗
24. Experimental study on anti-icing and deicing performance of polyurethane concrete as road surface layer10.1016/j.conbuildmat.2017.11.170 ↗
25. Fabrication of superhydrophobic coatings based on nanoparticles and fluoropolyurethane10.1002/app.38418 ↗
26. Self-healing superhydrophobic polyvinylidene fluoride/Fe3O4@ polypyrrole fiber with core–sheath structures for superior microwave absorption10.1007/s12274-016-1094-x ↗
27. Superhydrophobicity on aluminum through reactive-etching and TEOS/GPTMS/nano-Al2O3 silane-based nanocomposite coating10.1016/j.surfcoat.2019.06.074 ↗
28. Superhydrophobic TiO2/fluorinated polysiloxane hybrid coatings with controlled morphology for solar photocatalysis10.1016/j.colsurfa.2021.127633 ↗
29. Robust hydrophobic surfaces from suspension HVOF thermal sprayed rare-earth oxide ceramics coatings10.1038/s41598-018-25375-y ↗
30. All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance10.1038/s41563-018-0044-2 ↗
31. Durable and flexible superhydrophobic materials: Abrasion/scratching/slicing/droplet impacting/bending/twisting-tolerant composite with porcupinefish-like structure10.1021/acsami.9b09524 ↗
32. Design of robust superhydrophobic surfaces10.1038/s41586-020-2331-8 ↗
33. Fabrication of robust superhydrophobic surfaces via aerosol-assisted CVD and thermo-triggered healing of superhydrophobicity by recovery of roughness structures10.1039/C9TA03264A ↗
34. Fast self-healing superhydrophobic surfaces enabled by biomimetic wax regeneration10.1016/j.cej.2020.124311 ↗
35. Sprayable superhydrophobic coating with high processibility and rapid damage-healing nature10.1016/j.cej.2020.124834 ↗
36. Organogel as durable anti-icing coatings10.1007/s40843-015-0069-7 ↗
37. Icephobic/anti-icing properties of micro/nanostructured surfaces10.1002/adma.201104412 ↗
38. Turning a surface superrepellent even to completely wetting liquids10.1126/science.1254787 ↗
39. Two-component aliphatic polyurea coatings for high productivity applications
40. Controlled growth of monodisperse silica spheres in the micron size range10.1016/0021-9797(68)90272-5 ↗
41. Numerical investigations of drop solidification on a cold plate in the presence of volume change10.1016/j.ijmultiphaseflow.2015.07.005 ↗
42. Freezing of sessile water droplet for various contact angles10.1016/j.ijthermalsci.2015.10.027 ↗
43. Ultrafast laser enabling hierarchical structures for versatile superhydrophobicity with enhanced Cassie–Baxter stability and durability10.1021/acs.langmuir.9b02986 ↗
44. Extremely high Cassie–Baxter state stability of superhydrophobic surfaces via precisely tunable dual-scale and triple-scale micro–nano structures10.1039/C9TA04484A ↗
45. Flexible and mechanically robust superhydrophobic silicone surfaces with stable Cassie–Baxter state10.1039/C6TA06493K ↗
46. Control of ice nucleation: Freezing and antifreeze strategies10.1039/C8CS00626A ↗
47. Temperature regulation of the contact angle of water droplets on the solid surfaces10.1063/1.5090529 ↗
48. Effect of contact angle on water droplet freezing process on a cold flat surface10.1016/j.expthermflusci.2012.02.002 ↗
49. Effect of Cassie-Baxter versus Wenzel states on ice adhesion: A fracture toughness approach10.1016/j.coldregions.2021.103440 ↗