journal article·2024-09-15Open access

Polymer Capacitor Films with Nanoscale Coatings for Dielectric Energy Storage: A Review

Liang Cao, Rui Xi, Chen Zhou, Gaohui He, Feng Yang, Lingna Xu, He Li

Coatings· Volume 14· Issue 9

Abstract

Enhancing the energy storage properties of dielectric polymer capacitor films through composite materials has gained widespread recognition. Among the various strategies for improving dielectric materials, nanoscale coatings that create structurally controlled multiphase polymeric films have shown great promise. This approach has garnered considerable attention in recent years due to its effectiveness. This review examines surface-coated polymer composites used for dielectric energy storage, discussing their dielectric properties, behaviors, and the underlying physical mechanisms involved in energy storage. The review thoroughly examines the fabrication methods for nanoscale coatings and the selection of coating materials. It also explores the latest advancements in the rational design and control of interfaces in organic–inorganic, organic–organic, and heterogeneous multiphase structures. Additionally, the review delves into the structure–property relationships between different interfacial phases and various interface structures, analyzing how nanoscale coatings the impact dielectric constant, breakdown strength, conduction and charge transport mechanisms, energy density and efficiency, thermal stability, and electrothermal durability of polymeric capacitor films. Moreover, the review summarizes relevant simulation methods and offers computational insights. The potential practical applications and characteristics of such nanoscale coating techniques are discussed, along with the existing challenges and practical limitations. Finally, the review concludes with a summary and outlook, highlighting potential research directions in this rapidly evolving field.
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Research context

OpenAlex topics: Dielectric materials and actuators · Advanced Sensor and Energy Harvesting Materials · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Engineering and Technology, Southwest University, Chongqing 400715, China

Department of Electrical Engineering, The Pennsylvania State University, University Park, PA 16802, USA

The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

References (100+)

Show source-provided references
1. Deka, B., and Cho, K.-H. (2021). BiFeO3-Based Relaxor Ferroelectrics for Energy Storage: Progress and Prospects. Materials, 14.10.3390/ma14237188 ↗
2. Liu, X., Yao, Y., Wang, X., Zhao, L., and San, X. (2024). Energy Storage Performance of (Na0.5Bi0.5)TiO3 Relaxor Ferroelectric Film. Coatings, 14.10.3390/coatings14070801 ↗
3. Yang, Z., Yue, D., Yao, Y., Li, J., Chi, Q., Chen, Q., Min, D., and Feng, Y. (2022). Energy Storage Application of All-Organic Polymer Dielectrics: A Review. Polymers, 14.10.3390/polym14061160 ↗
4. Bonardd, S., Moreno-Serna, V., Kortaberria, G., Díaz Díaz, D., Leiva, A., and Saldías, C. (2019). Dipolar Glass Polymers Containing Polarizable Groups as Dielectric Materials for Energy Storage Applications. A Minireview. Polymers, 11.10.3390/polym11020317 ↗
5. Phillips, J. (2018). Toward an Improved Understanding of the Role of Dielectrics in Capacitors. Materials, 11.10.3390/ma11091519 ↗
6. Gnonhoue, O.G., Velazquez-Salazar, A., David, É., and Preda, I. (2021). Review of Technologies and Materials Used in High-Voltage Film Capacitors. Polymers, 13.10.3390/polym13050766 ↗
7. Polymer-grafted nanoparticles with variable grafting densities for high energy density polymeric nanocomposite dielectric capacitors
8. Meng, Z., Zhang, T., Zhang, C., Shang, Y., Lei, Q., and Chi, Q. (2024). Advances in polymer dielectrics with high energy storage performance by designing electric charge trap structures. Adv. Mater., 2310272.10.1002/adma.202310272 ↗
9. Polymer dielectrics for high-temperature energy storage: Constructing carrier traps10.1016/j.pmatsci.2023.101208 ↗
10. Chain-like semiconductive fillers for dielectric enhancement and loss reduction of polymer composites10.1002/adma.202401597 ↗
11. Interface design for high energy density polymer nanocomposites10.1039/C9CS00043G ↗
12. Pattipaka, S., Lim, Y., Son, Y.H., Bae, Y.M., Peddigari, M., and Hwang, G.-T. (2024). Ceramic-Based Dielectric Materials for Energy Storage Capacitor Applications. Materials, 17.10.3390/ma17102277 ↗
13. Ultrahigh energy storage in high-entropy ceramic capacitors with polymorphic relaxor phase10.1126/science.adl2931 ↗
14. Engineering relaxors by entropy for high energy storage performance10.1038/s41560-023-01300-0 ↗
15. High-entropy enhanced capacitive energy storage10.1038/s41563-022-01274-6 ↗
16. Ultrahigh energy storage in superparaelectric relaxor ferroelectrics10.1126/science.abi7687 ↗
17. Wang, J. (2022). High-Performance Dielectric Ceramic for Energy Storage Capacitors. Coatings, 12.10.3390/coatings12070889 ↗
18. Polymeric insulating materials characteristics for high-voltage applications10.1038/s44287-024-00070-5 ↗
19. Recent progress in polymer dielectric energy storage: From film fabrication and modification to capacitor performance and application10.1016/j.pmatsci.2023.101207 ↗
20. Chen, J., Pei, Z., Chai, B., Jiang, P., Ma, L., Zhu, L., and Huang, X. (2024). Engineering the dielectric constants of polymers: From molecular to mesoscopic scales. Adv. Mater., 2308670.10.1002/adma.202308670 ↗
21. High-temperature polymers with record-high breakdown strength enabled by rationally designed chain-packing behavior in blends10.1016/j.matt.2021.04.026 ↗
22. Review of polymer-based nanodielectric exploration and film scale-up for advanced capacitors10.1002/adfm.201808567 ↗
23. Polymer nanocomposite dielectrics for capacitive energy storage10.1038/s41565-023-01541-w ↗
24. Recent progress and future prospects on all-organic polymer dielectrics for energy storage capacitors10.1021/acs.chemrev.1c00793 ↗
25. Suppressing the loss of polymer-based dielectrics for high power energy storage10.1002/adma.202203623 ↗
26. Zhang, X., Zhang, L., Li, M., Chen, W., Chen, J., Liu, Y.J., and Wang, Y. (2022). Research Advances in Hierarchically Structured PVDF-Based All-Organic Composites for High-Energy Density Capacitors. Membranes, 12.10.3390/membranes12030274 ↗
27. Pan, Z., Mao, M., Zhang, B., Li, Z., Song, K., Li, H.-F., Mao, Z., and Wang, D. (2023). Excellent Energy Storage Performance in Epoxy Resin Dielectric Polymer Films by a Facile Hot−Pressing Method. Polymers, 15.10.3390/polym15102315 ↗
28. Xiao, M., Zhang, M., Liu, H., Du, B., and Qin, Y. (2022). Dielectric Property and Breakdown Strength Performance of Long-Chain Branched Polypropylene for Metallized Film Capacitors. Materials, 15.10.3390/ma15093071 ↗
29. Chen, C., Shen, L., Liu, G., Cui, Y., and Yan, S. (2024). Improved Energy Storage Performance of Composite Films Based on Linear/Ferroelectric Polarization Characteristics. Polymers, 16.10.3390/polym16081058 ↗
30. High-temperature polyimide dielectric materials for energy storage: Theory, design, preparation and properties10.1039/D1EE03186D ↗
31. Rational design of all-organic flexible high-temperature polymer dielectrics10.1016/j.matt.2022.06.064 ↗
32. High-temperature dielectric materials for electrical energy storage10.1146/annurev-matsci-070317-124435 ↗
33. High-Performing Polysulfate Dielectrics for Electrostatic Energy Storage under Harsh Conditions10.1016/j.joule.2022.12.010 ↗
34. Tailoring poly(styrene-co-maleic anhydride) networks for all-polymer dielectrics exhibiting ultrahigh energy density and charge–discharge efficiency at elevated temperatures10.1002/adma.202207580 ↗
35. Flexible cyclic-olefin with enhanced dipolar relaxation for harsh condition electrification10.1073/pnas.2115367118 ↗
36. Aromatic-free polymers based all-organic dielectrics with breakdown self-healing for high-temperature capacitive energy storage10.1002/adma.202306562 ↗
37. Ladderphane copolymers for high-temperature capacitive energy storage10.1038/s41586-022-05671-4 ↗
38. Designing tailored combinations of structural units in polymer dielectrics for high-temperature capacitive energy storage10.1038/s41467-023-38145-w ↗
39. Anisotropic semicrystalline homopolymer dielectrics for high-temperature capacitive energy storage10.1002/anie.202319766 ↗
40. Spiral-structured dielectric polymers exhibiting ultrahigh energy density and charge–discharge efficiency at high temperatures10.1002/adma.202303849 ↗
41. Pendant group functionalization of cyclic olefin for high temperature and high-density energy storage10.1002/adma.202402133 ↗
42. Flexible polyolefin dielectric by strategic design of organic modules for harsh condition electrification10.1039/D1EE02630E ↗
43. High-Temperature High-Energy-Density Dielectric Polymer Nanocomposites Utilizing Inorganic Core–Shell Nanostructured Nanofillers10.1002/aenm.202101297 ↗
44. Zhu, C., Yin, J., Feng, Y., Li, J., Li, Y., Zhao, H., Yue, D., and Liu, X. (2022). Enhanced Energy Storage Performance of PVDF-Based Composites Using BN@PDA Sheets and Titania Nanosheets. Materials, 15.10.3390/ma15134370 ↗
45. Li, Y., Zhou, Y., Cheng, S., Hu, J., He, J., and Li, Q. (2021). Polymer Nanocomposites with High Energy Density Utilizing Oriented Nanosheets and High-Dielectric-Constant Nanoparticles. Materials, 14.10.3390/ma14174780 ↗
46. Interfacial Engineering using Covalent Organic Frameworks in Polymer Composites for High-Temperature Electrostatic Energy Storage10.1002/adfm.202314910 ↗
47. Flexible All-Organic Nanocomposite Films Interlayered with In Situ Synthesized Covalent Organic Frameworks for Electrostatic Energy Storage10.1016/j.nanoen.2023.108544 ↗
48. Largely Enhanced Dielectric Properties of Polymer Composites with HfO2 Nanoparticles for High-Temperature Film Capacitors10.1016/j.compscitech.2020.108528 ↗
49. Tuning Interfacial Relaxations in P(VDF-HFP) with Al2O3@ZrO2 Core-Shell Nanofillers for Enhanced Dielectric and Energy Storage Performance10.1016/j.compscitech.2022.109379 ↗
50. Polymer Nanocomposites with Concurrently Enhanced Dielectric Constant and Breakdown Strength at High Temperature Enabled by Rationally Designed Core-Shell Structured Nanofillers10.1016/j.jmst.2024.05.046 ↗
51. High Temperature Polyimide Nanocomposites Containing Two-Dimensional Nanofillers for Improved Thermal Stability and Capacitive Energy Storage Performance10.1007/s12274-024-6765-4 ↗
52. Pu, Z., Zheng, X., Tian, Y., Hu, L., and Zhong, J. (2017). Flexible Ultrahigh-Temperature Polymer-Based Dielectrics with High Permittivity for Film Capacitor Applications. Polymers, 9.10.3390/polym9110596 ↗
53. Chen, J., Zhang, X., Yang, X., Li, C., Wang, Y., and Chen, W. (2021). High Breakdown Strength and Energy Storage Density in Aligned SrTiO3@ SiO2 Core–Shell Platelets Incorporated Polymer Composites. Membranes, 11.10.3390/membranes11100756 ↗
54. Wang, J., Xie, Y., Liu, J., Zhang, Z., Zhuang, Q., and Kong, J. (2018). Improved Energy Storage Performance of Linear Dielectric Polymer Nanodielectrics with Polydopamine coated BN Nanosheets. Polymers, 10.10.3390/polym10121349 ↗
55. Quantum size effect to induce colossal high-temperature energy storage density and efficiency in polymer/inorganic cluster composites10.1002/adma.202301936 ↗
56. Roll-to-roll fabricated polymer composites filled with subnanosheets exhibiting high energy density and cyclic stability at 200 °C10.1038/s41560-023-01416-3 ↗
57. Polymer/molecular semiconductor all-organic composites for high-temperature dielectric energy storage10.1038/s41467-020-17760-x ↗
58. Polyimides physically crosslinked by aromatic molecules exhibit ultrahigh energy density at 200 °C10.1002/adma.202302392 ↗
59. Scalable ultrathin all-organic polymer dielectric films for high-temperature capacitive energy storage10.1002/adma.202207421 ↗
60. Scalable polyimide-organosilicate hybrid films for high-temperature capacitive energy storage10.1002/adma.202211487 ↗
61. Atomic-level matching metal-ion organic hybrid interface to enhance energy storage of polymer-based composite dielectrics10.1002/adma.202402239 ↗
62. Multilaminate Energy Storage Films from Entropy-Driven Self-Assembled Supramolecular Nanocomposites10.1002/adma.202401954 ↗
63. Zhang, C., Tong, X., Liu, Z., Zhang, Y., Zhang, T., Tang, C., Liu, X., and Chi, Q. (2023). Enhancement of Energy Storage Performance of PMMA/PVDF Composites by Changing the Crystalline Phase through Heat Treatment. Polymers, 15.10.3390/polym15112486 ↗
64. Meng, X.-S., Zhou, Y., Li, J., Ye, H., Chen, F., Zhao, Y., Pan, Q., and Xu, J. (2023). All-Organic PTFE Coated PVDF Composite Film Exhibiting Low Conduction Loss and High Breakdown Strength for Energy Storage Applications. Polymers, 15.10.3390/polym15051305 ↗
65. Wang, C., Shen, Y., Cao, X., Zheng, X., and Ren, K. (2024). High Energy Density in All-Organic Polyimide-Based Composite Film by Doping of Polyvinylidene Fluoride-Based Relaxor Ferroelectrics. Polymers, 16.10.3390/polym16081138 ↗
66. Improving Charge Storage of Biaxially-Oriented Polypropylene under Extreme Electric Fields by Excimer UV Irradiation10.1002/adma.202311713 ↗
67. Flexible High-Temperature Dielectric Materials from Polymer Nanocomposites10.1038/nature14647 ↗
68. Charge Interaction Behaviors at Interfacial Domains in DC GIL Insulators10.1063/5.0203206 ↗
69. Min, D., Yan, C., Mi, R., Ma, C., Huang, Y., Li, S., Wu, Q., and Xing, Z. (2018). Carrier Transport and Molecular Displacement Modulated DC Electrical Breakdown of Polypropylene Nanocomposites. Polymers, 10.10.3390/polym10111207 ↗
70. Space Charge Dynamics of Epoxy/Micro-Al2O3 Composites under Multi-Physical Fields10.1088/1361-6463/acd3fd ↗
71. Space Charge Behavior in Epoxy-Based Dielectrics: Progress and Perspective10.1002/aelm.202200259 ↗
72. Atomic Layer Deposition for Polypropylene Film Engineering—A Review10.1002/mame.202000127 ↗
73. A Scalable, High-Throughput, and Environmentally Benign Approach to Polymer Dielectrics Exhibiting Significantly Improved Capacitive Performance at High Temperatures10.1002/adma.201805672 ↗
74. High-Temperature Capacitive Energy Storage in Polymer Nanocomposites through Nanoconfinement10.1038/s41467-024-51052-y ↗
75. Atom Permeable Gradient-Structured Hybrid Dielectric Films for Highly Improved Capacitive Energy Storage10.1016/j.jpowsour.2024.235196 ↗
76. Polymer Dielectrics Sandwiched by Medium-Dielectric-Constant Nanoscale Deposition Layers for High-Temperature Capacitive Energy Storage10.1016/j.ensm.2021.07.018 ↗
77. High-Performance Polymers Sandwiched with Chemical Vapor Deposited Hexagonal Boron Nitrides as Scalable High-Temperature Dielectric Materials10.1002/adma.201701864 ↗
78. High-Temperature Energy Storage Dielectric with Inhibition of Carrier Injection/Migration Based on Band Structure Regulation10.1002/inf2.12368 ↗
79. Multilayer Polyetherimide Films Incorporating Alumina Nanolayers for Dielectric Capacitors10.1016/j.cej.2022.137940 ↗
80. Significantly Improved High-Temperature Energy Storage Performance of BOPP Films by Coating Nanoscale Inorganic Layer10.1002/eem2.12549 ↗
81. Qadir, M., Li, Y., and Wen, C. (2019). Ion-Substituted Calcium Phosphate Coatings by Physical Vapor Deposition Magnetron Sputtering for Biomedical Applications: A review. Acta Biomater., 89.10.1016/j.actbio.2019.03.006 ↗
82. Sandwich-Structured Polymers with Electrospun Boron Nitrides Layers as High-Temperature Energy Storage Dielectrics10.1016/j.cej.2020.124443 ↗
83. Improved Working Temperature and Capacitive Energy Density of Biaxially Oriented Polypropylene Films with Alumina Coating Layers10.1021/acsaem.1c03735 ↗
84. Polyphenylene Oxide Film Sandwiched between SiO2 Layers for High-Temperature Dielectric Energy Storage10.1021/acsami.3c18237 ↗
85. 2D Nanosheet Spray Coating for Scalable Processing of High-Energy-Density Dielectric Polymer Films10.1002/aelm.202300187 ↗
86. Improved High-Temperature Energy Storage Performance of PEI Dielectric Films by Introducing an SiO2 Insulating Layer10.1002/mame.202100514 ↗
87. Polyimide Films Coated by Magnetron Sputtered Boron Nitride for High-Temperature Capacitor Dielectrics10.1109/TDEI.2020.008592 ↗
88. Multi-Layered Boron Nitride/Polyimide High-Temperature Capacitor Dielectric Film10.1016/j.mtener.2022.101093 ↗
89. Interfacial 2D Montmorillonite Nanocoatings Enable Sandwiched Polymer Nanocomposites to Exhibit Ultrahigh Capacitive Energy Storage Performance at Elevated Temperatures10.1002/advs.202204760 ↗
90. Sandwiched Polymer Nanocomposites Reinforced by Two-Dimensional Interface Nanocoating for Ultrahigh Energy Storage Performance at Elevated Temperatures10.1002/smll.202208105 ↗
91. Enhancing High Field Dielectric Properties of Polymer Films by Wrapping a Thin Layer of Self-Assembled Boron Nitride Film10.1016/j.apsusc.2020.147737 ↗
92. Improved Energy Storage Performance of P(VDF-TrFE-CFE) Multilayer Films by Utilizing Inorganic Functional Layers10.1021/acsaem.1c02471 ↗
93. Greatly Enhanced Energy Density in Polymer Nanocomposites Coated with High-k Perovskite Nanosheets10.1016/j.mtener.2022.101213 ↗
94. High-Temperature Performance of Dielectric Breakdown in BOPP Capacitor Film Based on Surface Grafting10.1109/TDEI.2021.009585 ↗
95. Improved Energy Density and Charge Discharge Efficiency of Polypropylene Capacitor Film Based on Surface Grafting10.1109/TDEI.2021.009577 ↗
96. γ-Ray Irradiation Significantly Enhances Capacitive Energy Storage Performance of Polymer Dielectric Films10.1002/adma.202308597 ↗
97. Yang, M., Wang, Z., Zhao, Y., Liu, Z., Pang, H., and Dang, Z.-M. (2024). Unifying and Suppressing Conduction Losses of Polymer Dielectrics for Superior High-Temperature Capacitive Energy Storage. Adv. Mater., 2309640.10.1002/adma.202309640 ↗
98. Enhanced Energy Density at Elevated Temperature in Polyetherimide Based All-Organic Dielectrics via UV Irradiation10.1063/5.0144547 ↗
99. Pei, J.-Y., Zhu, J., Yin, L.-J., Zhao, Y., Yang, M., Zhong, S.-L., Feng, Q.-K., and Dang, Z.-M. (2024). Flexible High-Temperature Polymer Dielectrics Induced by Ultraviolet Radiation for High Efficient Energy Storage. Adv. Funct. Mater., 2316869.10.1002/adfm.202316869 ↗
100. Multilayered Hierarchical Polymer Composites for High Energy Density Capacitors10.1039/C8TA11392K ↗