journal article·2023-05-09Open access

Tribological Behavior of Doped DLC Coatings in the Presence of Ionic Liquid Additive under Different Lubrication Regimes

Mohammadamin Sadeghi, Takeru Omiya, Filipe Fernandes, Luís Vilhena, Amilcar Ramalho, Fábio Ferreira

Coatings· Volume 13· Issue 5

Abstract

Diamond-like carbon (DLC) coatings are widely used in industries that require high durability and wear resistance, and low friction. The unique characteristics of DLC coatings allow for the possibility of creating adsorption sites for lubricant additives through the doping process. In this study, the combined use of europium-doped diamond-like carbon (Eu-DLC), gadolinium-doped diamond-like carbon (Gd-DLC), and pure DLC coatings and an ionic liquid (IL) additive, namely, trihexyltetradecylphosphonium bis (2-ethylhexyl) phosphate [P66614] [DEHP], with a 1 wt.% concentration in polyalphaolefin (PAO) 8 as a base lubricant was investigated. Higher hardness, higher thin-film adhesion, a higher ratio of hardness to elastic modulus, and a higher plastic deformation resistance factor were achieved with the Gd-DLC coating. The CoF of the Gd-DLC coating paired with the IL was superior compared to the other pairs in all lubrication regimes, and the pure DLC coating had a better performance than the Eu-DLC coating. The wear could not be quantified due to the low wear on the surface of the DLC coatings. The friction reduction demonstrates that tribological systems combining Gd-DLC thin films with an IL can be a potential candidate for future research and development efforts to reduce friction and increase the efficiency of moving parts in internal combustion engines, for instance.
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Research context

OpenAlex topics: Lubricants and Their Additives · Diamond and Carbon-based Materials Research · Tribology and Wear Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical Engineering, CEMMPRE, ARISE, University of Coimbra, Rua Luís Reis Santos, 3030-788 Coimbra, Portugal

Laboratory for Wear, Testing & Materials, Instituto Pedro Nunes, Rua Pedro Nunes, 3030-199 Coimbra, Portugal

ISEP, Polytechnic of Porto, Rua Dr. António Bernardino de Almeida, 4249-015 Porto, Portugal

Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX 78712, USA

Funding

COMPETE–Programa Operacional Factores de Competitividade · FCT–Fundação para a Ciência e a Tecnologia · LubEnergy · SmartHyLub · Taiho Kogyo Tribology Research Foundation

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