Highly Conductive Co-Doped Ga2O3:Si-In Grown by MOCVD
Source abstract
Abstract
We report a highly conductive gallium oxide doped with both silicon and indium grown on c-plane sapphire substrate by MOCVD. From a superlattice structure of indium oxide and gallium oxide doped with silicon, we obtained a highly conductive material with an electron hall mobility up to 150 cm2/V·s with the carrier concentration near 2 × 1017 cm−3. However, if not doped with silicon, both Ga2O3:In and Ga2O3 are highly resistive. Optical and structural characterization techniques such as X-ray, transmission electron microscope, and photoluminescence, reveal no significant incorporation of indium into the superlattice materials, which suggests the indium plays a role of a surfactant passivating electron trapping defect levels.
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Research context
OpenAlex topics: Ga2O3 and related materials · ZnO doping and properties · Advanced Photocatalysis Techniques
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Affiliations
Center for Quantum Devices, Department of Electrical and Computer Engineering, Northwestern University, Evanston, IL 60208, USA
Funding
U.S. Air Force
References (27)
Show source-provided references
1. Polymorphism of Ga2O3 and the system Ga2O3—H2O10.1021/ja01123a039 ↗
2. A Review of the growth, doping, and applications of β-Ga2O3 thin films
3. MOCVD Epitaxy of ultrawide bandgap β-(AlxGa1−x)2O3 with high-Al composition on (100) β-Ga2O3 substrates10.1021/acs.cgd.0c00864 ↗
4. Tuning the responsivity of monoclinic solar-blind photodetectors grown by metal organic chemical vapor deposition10.1088/1361-6463/aba313 ↗
5. Stabilization and enhanced energy gap by Mg doping in ε-phase Ga2O3 thin films10.1063/1.5022600 ↗
6. Investigations on the substrate dependence of the properties in nominally-undoped beta-Ga2O3 thin films grown by PLD10.1117/12.2262757 ↗
7. Heteroepitaxy of corundum-structured α-Ga2O3 thin films on α-Al2O3 substrates by ultrasonic mist chemical vapor deposition10.1143/JJAP.47.7311 ↗
8. Successful growth of conductive highly crystalline Sn-doped α-Ga2O3 thin films by fine-channel mist chemical vapor deposition10.1143/JJAP.51.040207 ↗
9. HCl flow-induced phase change of α-, β-, and ε-Ga2O3 films grown by MOCVD10.1021/acs.cgd.7b01791 ↗
10. Hetero-epitaxy of ε-Ga2O3 layers by MOCVD and ALD10.1016/j.jcrysgro.2016.03.013 ↗
11. Growth and characterization of α-, β-, and ϵ-phases of Ga2O3 using MOCVD and HVPE techniques10.1080/21663831.2018.1443978 ↗
12. Ga2O3 metal-oxide-semiconductor field effect transistors on sapphire substrate by MOCVD10.1088/1361-6641/ab2c17 ↗
13. Solar-blind photodetectors based on Ga2O3 and III-nitrides
14. First-principle calculations of electronic structures and polar properties of (κ, ε)-Ga2O310.7567/APEX.11.061101 ↗
15. Strain-induced metastable phase stabilization in Ga2O3 thin films10.1021/acsami.8b17731 ↗
16. Lee, J., Kim, H., Gautam, L., He, K., Hu, X., Dravid, V.P., and Razeghi, M. (2021). Study of phase transition in MOCVD grown Ga2O3 from κ to β phase by ex situ and in situ annealing. Photonics, 8.10.3390/photonics8010017 ↗
17. Anomalous Fe diffusion in Si-ion-implanted β–Ga2O3 and its suppression in Ga2O3 transistor structures through highly resistive buffer layers10.1063/1.4906375 ↗
18. Effect of buffer iron doping on delta-doped β-Ga2O3 metal semiconductor field effect transistors10.1063/1.5039502 ↗
19. Si and Sn doping of ε-Ga2O3 layers10.1063/1.5050982 ↗
20. Ge-doped β-Ga2O3 MOSFETs10.1109/LED.2017.2697359 ↗
21. MOCVD grown epitaxial β-Ga2O3 thin film with an electron mobility of 176 cm2/V s at room temperature10.1063/1.5058059 ↗
22. High quantum efficiency AlGaN solar-blind p-i-n photodiodes10.1063/1.1650550 ↗
23. Review of III-nitride optoelectronic materials for light emission and detection10.1002/pssc.200405133 ↗
24. Indium-surfactant-assisted growth of high-mobility AlN/GaN multilayer structures by metalorganic chemical vapor deposition10.1063/1.1420573 ↗
25. Increased p-type conductivity through use of an indium surfactant in the growth of Mg-doped GaN10.1063/1.4922216 ↗
26. Improvement of surface morphology of nitrogen-polar GaN by introducing indium surfactant during MOVPE growth10.7567/JJAP.53.085501 ↗
27. High hole concentration in p-type AlGaN by indium-surfactant-assisted Mg-delta doping10.1063/1.4919005 ↗