Corrosion Behaviors of Tetrasodium Iminodisuccinate (IDS) as an Environmentally Friendly Inhibitor: Experimental and Theoretical Studies
Source abstract
Abstract
An environmentally friendly chelating agent, tetrasodium iminodisuccinate (IDS), was investigated as an inhibitor in the simulated concrete pore solution on Q235 carbon steel by using Tafel polarization (TF), electrochemical impedance spectroscopy (EIS) and surface morphology tests. The EIS and TF results indicate that the IDS is a mixed type of inhibitor and exhibits excellent protection efficiency (97.54%) at 200 mg/L. Furthermore, based on the Langmuir adsorption isotherm, IDS protects carbon steel through physical and chemical adsorption. Besides, density functional theory (DFT) and molecular dynamics (MD) simulations are applied to explore the inhibition mechanism to support the experimental data, indicating that IDS can be used as a new green corrosion inhibitor.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
School of Civil Engineering, Lanzhou Institute of Technology, Lanzhou 730050, China
School of Electronics Science & Engineering, Faculty of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China
Funding
Innovation and Entrepreneurship Training Program
References (54)
Show source-provided references
1. Corrosion behavior of steel in simulated concrete pore solutions treated with calcium silicate hydrates10.1016/j.conbuildmat.2011.11.033 ↗
2. Effect of Phosphate-based inhibitor on prestressing tendons corrosion in simulated concrete pore solution contaminated by chloride ions10.1016/j.conbuildmat.2018.03.118 ↗
3. Investigation of African mangosteen leaves extract as an environment-friendly inhibitor for low carbon steel in 0.5 M H2SO410.1016/j.inoche.2022.109488 ↗
4. Ketosulfone Drug as a Green Corrosion Inhibitor for Mild Steel in Acidic Medium10.1021/ie500232g ↗
5. Electrochemical and Adsorption Studies of 4-Chloro, 8-(Trifluoromethyl) Quinoline (CTQ) for Mild Steel in Acidic Medium10.1007/s11668-020-00944-4 ↗
6. Ingested nitrate and nitrite and stomach cancer risk: An updated review10.1016/j.fct.2012.07.062 ↗
7. Praveen, B.M., Alhadhrami, A., Prasanna, B.M., Hebbar, N., and Prabhu, R. (2021). Anti-Corrosion Behavior of Olmesartan for Soft-Cast Steel in 1 mol dm−3 HCl. Coatings, 11.10.3390/coatings11080965 ↗
8. Corrosion inhibition of carboxylate inhibitors with different alkylene chain lengths on carbon steel in an alkaline solution10.1039/C8RA10083G ↗
9. Carboxylic acids as efficient corrosion inhibitors of aluminium alloys in alkaline media10.1016/j.electacta.2018.08.070 ↗
10. Investigation of anticorrosive behaviour of novel tert-butyl 4-[(4-methyl phenyl) carbonyl] piperazine-1-carboxylate for carbon steel in 1M HCl10.1016/j.heliyon.2021.e06090 ↗
11. General properties and comparison of the corrosion inhibition efficiencies of the triazole derivatives for mild steel10.1515/corrrev-2018-0006 ↗
12. Marzorati, S., Verotta, L., and Trasatti, S.P. (2018). Green Corrosion Inhibitors from Natural Sources and Biomass Wastes. Molecules, 24.10.3390/molecules24010048 ↗
13. Mechanistic study of polyepoxy succinic acid (PESA) as green corrosion inhibitor on carbon steel in aerated NaCl Solution10.1016/j.mtcomm.2021.102848 ↗
14. Interfacial Interaction Study of EDTA with the Defect Structure of Fe 3-δ O 4 Passive Film in an Aggressive Alkaline Medium Based on the Lattice Theory of Point Defects10.1039/D1RA07171H ↗
15. A comprehensive study on the inhibition behaviour of four carboxylate-based corrosion inhibitors focusing on efficiency drop after the optimum concentration for carbon steel in the simulated concrete pore solution10.1016/j.conbuildmat.2021.123702 ↗
16. Detailed theoretical DFT computation/molecular simulation and electrochemical explorations of Thymus vulgaris leave extract for effective mild-steel corrosion retardation in HCl solution10.1016/j.molliq.2021.115897 ↗
17. The inhibition mechanism of maize gluten meal extract as green inhibitor for steel in concrete via experimental and theoretical elucidation10.1016/j.conbuildmat.2018.11.216 ↗
18. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Petersson, G.A., and Nakatsuji, H. (Gaussian 16, 2016). Gaussian 16, Revision C.01.
19. In-Depth Insight into the Inhibition Mechanism of the Modified and Combined Amino Acids Corrosion Inhibitors: “Intramolecular Synergism” vs. “Intermolecular Synergism”10.1016/j.cej.2022.135439 ↗
20. Self-assembly of hierarchical N-heterocycles-inorganic materials into three-dimensional structure for superior corrosion protection
21. Quantum chemical and experimental evaluation of the inhibitory action of two imidazole derivatives on mild steel corrosion in sulphuric acid medium10.1016/j.heliyon.2019.e02759 ↗
22. The use of global and local molecular parameters for the analysis of the gas-phase basicity of amines10.1021/ja00279a008 ↗
23. Review on epoxy polymers and its composites as a potential anticorrosive coatings for carbon steel in 3.5% NaCl solution: Computational approaches10.1016/j.molliq.2021.116307 ↗
24. Insight into the Corrosion Inhibition of Novel Macromolecular Epoxy Resin as Highly Efficient Inhibitor for Carbon Steel in Acidic Mediums: Synthesis, Characterization, Electrochemical Techniques, AFM/UV–Visible and Computational Investigations10.1016/j.molliq.2021.116492 ↗
25. Investigating the anti-corrosion behaviors of the waterborne epoxy composite coatings with barrier and inhibition roles on mild steel10.1016/j.porgcoat.2019.04.028 ↗
26. Epoxy-polyamide nanocomposite coating with graphene oxide as cerium nanocontainer generating effective dual active/barrier corrosion protection10.1016/j.compositesb.2019.05.055 ↗
27. The Reaction of Aliphatic Nitro Compounds with Nitrite Esters1,210.1021/ja01588a060 ↗
28. An imide-based organic polymer as an inhibitor for HRB400 steel in simulated concrete pore solution: Experimental and theoretical calculations10.1016/j.molstruc.2022.133426 ↗
29. Synergistic Effect of Polypyrrole-Intercalated Graphene for Enhanced Corrosion Protection of Aqueous Coating in 3.5% NaCl Solution10.1021/acsami.7b08325 ↗
30. Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors. Part 1: An overview10.1016/j.corsci.2015.01.037 ↗
31. Adsorption and Corrosion Inhibition Studies of Some Selected Dyes as Corrosion Inhibitors for Mild Steel in Acidic Medium: Gravimetric, Electrochemical, Quantum Chemical Studies and Synergistic Effect with Iodide Ions10.3390/molecules200916004 ↗
32. Synthesis and characterisation of composite nanoparticles of mesoporous silica loaded with inhibitor for corrosion protection of Cu-Zn alloy10.1016/j.corsci.2017.02.004 ↗
33. Corrosion inhibition of N80 steel in 15% HCl by pyrazolone derivatives: Electrochemical, surface and quantum chemical studies10.1039/C5RA25441H ↗
34. Natural Products for Material Protection: Inhibition of Mild Steel Corrosion by Date Palm Seed Extracts in Acidic Media10.1021/ie401737u ↗
35. Application of Anise Extract for Corrosion Inhibition of Carbon Steel in CO2 Saturated 3.0% NaCl Solution10.1134/S2070205118010240 ↗
36. Synthesis and investigation of pyran derivatives as acidizing corrosion inhibitors for N80 steel in hydrochloric acid: Theoretical and experimental approaches10.1016/j.jallcom.2018.05.236 ↗
37. N-acetyl cysteine based corrosion inhibitor formulations for steel protection in 15% HCl solution10.1016/j.molliq.2017.09.040 ↗
38. Chemically modified expired Dapsone drug as environmentally benign corrosion inhibitor for mild steel in sulphuric acid useful for industrial pickling process10.1016/j.molliq.2019.110903 ↗
39. Experimental and Theoretical Study of New Schiff Bases Based on Imidazo (1, 2-a) Pyridine as Corrosion Inhibitor of Mild Steel in 1M HCl10.1016/j.molstruc.2020.129372 ↗
40. Characterization of ceramic sol–gel coatings as an alternative chemical conversion treatment on commercial carbon steel10.1016/j.electacta.2008.11.023 ↗
41. Development of electroplated magnetic materials for MEMS10.1016/S0304-8853(03)00264-6 ↗
42. Sustainable corrosion inhibitor for steel in simulated concrete pore solution by maize gluten meal extract: Electrochemical and adsorption behavior studies10.1016/j.conbuildmat.2019.117080 ↗
43. Green synthesis of 1-benzyl-4-phenyl-1H-1,2,3-triazole, its application as corrosion inhibitor for mild steel in acidic medium and new approach of classical electrochemical analyses10.1016/j.corsci.2019.01.019 ↗
44. Computational, Monte Carlo simulation and experimental studies of some arylazotriazoles (AATR) and their copper complexes in corrosion inhibition process10.1016/j.molliq.2018.01.055 ↗
45. A new corrosion inhibitor for steel rebar in concrete: Synthesis, electrochemical and theoretical studies10.1016/j.molstruc.2020.129257 ↗
46. Effect of fluid velocity and temperature on the corrosion mechanism of low carbon steel in industrial water in the absence and presence of 2-hydrazino benzothiazole10.1007/s11814-008-0212-1 ↗
47. Ionic liquids based gemini cationic surfactants as corrosion inhibitors for carbon steel in hydrochloric acid solution10.1016/j.molliq.2016.01.066 ↗
48. Green Eucalyptus leaf extract: A potent source of bio-active corrosion inhibitors for mild steel10.1016/j.bioelechem.2019.107339 ↗
49. Computational simulation and statistical analysis on the relationship between corrosion inhibition efficiency and molecular structure of some hydrazine derivatives in phosphoric acid on mild steel surface10.1016/j.apsusc.2019.04.125 ↗
50. Quantum chemical calculations, molecular dynamic (MD) simulations and experimental studies of using some azo dyes as corrosion inhibitors for iron. Part 2: Bis–azo dye derivatives10.1016/j.molstruc.2018.03.013 ↗
51. Corrosion Inhibitors—Correlation between Electronic Structure and Efficiency10.5006/1.3290328 ↗
52. Is the analysis of molecular electronic structure of corrosion inhibitors sufficient to predict the trend of their inhibition performance10.1016/j.electacta.2010.09.065 ↗
53. Experimental and theoretical studies for mild steel corrosion inhibition in 1M HCl by two new benzothiazine derivatives10.1016/j.corsci.2013.06.052 ↗
54. Understanding the inhibition performance of novel dibenzimidazole derivatives on Fe (110) surface: DFT and MD simulation insights10.1016/j.jmrt.2021.12.140 ↗