journal article·2023-04-06Open access

Gradient Coating of Laser Cladding TiB2/Ti-Based Alloy on Titanium Alloy Surface

Yinghua Lin, Haibo Wang, Mingxing Zhang, Hui Lin, Dengqiang Yan, Qinghua Lin, Xin Kang, Xinlin Wang

Coatings· Volume 13· Issue 4

Abstract

The technology of the TiB2/TiB cladding layer addresses the issue of the insufficient wear resistance of cup-shaped parts composed of titanium alloy materials. In order to eliminate the cracking problem of laser cladding TiB2/Ti-based alloy, 30%TiB2/Ti-based alloy gradient coating was prepared on the surface of titanium alloy by laser cladding in this study. The results revealed that the microstructure of the matrix and the cladding layer is metallurgically bonded. The microstructures of the cladding layer appear as rod-like and coarse-grained features on the surface, and fine needle-like and small-grained morphologies inside. The fine needle-like TiB precipitated in situ from the melt has a flat interface with Ti and exhibits a low degree of interfacial mismatch, while the interface between small particle-like TiB and Ti is wavy and has a high degree of interfacial mismatch. The gradual increase in the amount of TiB is present from the surface to the bottom of the cladding layer, while the amount of unmelted TiB2 particles decreases. The chemical structure of the cladding layer is mainly presented as TiB2, TiB and α-Ti phases. The maximum hardness of the cladding layer is 725 HV0.2, where it is more than twice the hardness of the substrate. The fretting wear resistance of the cladding layer is better than that of the titanium alloy substrate under low loads (50 N–100 N), while a high load (more than 150 N) triggers a reverse outcome.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: High Entropy Alloys Studies · Titanium Alloys Microstructure and Properties · Additive Manufacturing Materials and Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Hunan Province Key Laboratory for Ultra-Fast Micro/Nano Technology and Advanced Laser Manufacture, School of Mechanical Engineering, University of South China, Hengyang 421001, China

School of Mechanical and Electrical Engineering, Putian University, Putian 351100, China

Hunan Special Equipment Inspection and Testing Institute, Hengyang Branch, Hengyang 421007, China

Funding

Hunan Natural Science Foundation—Provincial and Municipal Joint Fund · Hengyang Guiding Plan Project · University of South School Talent Introduction Project

References (28)

Show source-provided references
1. Review of micro-arc oxidation of titanium alloys: Mechanism, properties and applications10.1016/j.jallcom.2023.169773 ↗
2. Shu, L.S., Li, J.H., Wu, H., and Heng, Z. (2022). Optimization of Multi-Track Laser-Cladding Process of Titanium Alloy Based on RSM and NSGA-II Algorithm. Coatings, 12.10.3390/coatings12091301 ↗
3. A review on superplastic forming of Ti-6Al-4V and other titanium alloys10.1016/j.mtcomm.2023.105343 ↗
4. Yue, Y., Liu, S.G., Qiu, W.W., Wang, F., Xue, Y.J., Xia, C.Q., and Du, S.M. (2023). Comparative Study on Wear Behaviors of Monolayer and Heterogeneous Multilayer Ta Coatings in Atmospheric and SBF Environments. Coatings, 13.10.3390/coatings13010120 ↗
5. Fretting wear behavior of nano ZrO2 doped plasma electrolytic oxidation composite coatings on TC21 titanium alloy10.1016/j.surfcoat.2021.127429 ↗
6. Wang, K.M., Liu, W., Hong, Y.X., Shakhawat Sohan, H.M., Tong, Y.G., Hu, Y.L., Zhang, M.J., Zhang, J., Xiang, D.D., and Fu, H.G. (2023). An Overview of Technological Parameter Optimization in the Case of Laser Cladding. Coatings, 13.10.3390/coatings13030496 ↗
7. Study on dual rotary fretting wear behavior of Ti6Al4V titanium alloy10.1016/j.wear.2016.10.027 ↗
8. In-situ observation of microcrack initiation and damage nucleation modes on the HAZ of laser-welded DP1180 joint10.1016/j.jmst.2023.01.001 ↗
9. A study on the additive manufacturing of a high chromium nickel-based superalloy by extreme high-speed laser metal deposition10.1016/j.optlastec.2020.106504 ↗
10. Effects of TiB2 content on the processability and mechanical performance of Hastelloy-X based composites fabricated by selective laser melting10.1016/j.optlastec.2022.108441 ↗
11. Solidification orientation relationships between Al3Ti and TiB210.1016/j.actamat.2019.12.013 ↗
12. The nucleation sequence of α-Al on TiB2 particles in Al-Cu alloys10.1016/j.actamat.2021.116652 ↗
13. Mechanical properties of casting titanium alloy matrix composites reinforced by WC and TiB2 ceramic particulates10.1016/j.matpr.2022.01.385 ↗
14. In situ formed TiB2/TiC complex structure in laser-alloyed coatings with improved wear property10.1016/j.ceramint.2021.11.263 ↗
15. Wang, Z., Lan, N., Zhang, Y., and Deng, W.R. (2022). Microstructure and Properties of MAO-Cu/Cu-(HEA)N Composite Coatings on Titanium Alloy. Coatings, 12.10.3390/coatings12121877 ↗
16. CALPHAD-guided alloy design and processing for improved strength and toughness in Titanium Boride (TiB) ceramic alloy containing a ductile phase10.1016/j.actamat.2019.03.040 ↗
17. Experiment and modeling of TiB2/TiB boride layer of Ti−6Al−2Zr−1Mo−1V alloy10.1016/S1003-6326(21)65761-8 ↗
18. Laser in-situ synthesis of high aspect ratio TiB fiber bundle reinforced titanium matrix composite coating10.1016/j.optlastec.2019.02.047 ↗
19. Laser in-situ synthesis of titanium matrix composite coating with TiB−Ti network-like structure reinforcement10.1016/S1003-6326(19)65073-9 ↗
20. Laplace pressure evolution and four instabilities in evaporating two-grain liquid bridges10.1016/j.powtec.2015.05.024 ↗
21. The effect of capillary force on airborne nanoparticle filtration10.1016/j.jaerosci.2015.02.001 ↗
22. Preparation of soft-agglomerated nano-sized ceramic powders by sol–gel combustion process10.1016/j.mseb.2009.02.007 ↗
23. Atomic insights into heterogeneous nucleation and growth kinetics of Al on TiB2 particles in undercooled Al-5Ti-1B melt10.1016/j.jmst.2023.01.027 ↗
24. Mechanical properties of Ti-6Al-4V/TiB composites with randomly oriented and aligned TiB reinforcements10.1016/S1359-6454(02)00510-4 ↗
25. A study of TiB2/TiB gradient coating by laser cladding on titanium alloy10.1016/j.optlaseng.2016.01.016 ↗
26. TiB whisker induced variant selection in titanium matrix composites10.1016/j.scriptamat.2022.114772 ↗
27. Effect of scanning speed on microstructure and properties of TiC/Ni60 composite coatings on Ti6Al4V alloy by laser cladding10.1016/j.optlastec.2022.108309 ↗
28. Interfacial energy between Al melt and TiB2 particles and efficiency of TiB2 particles to nucleate α-Al10.1016/j.scriptamat.2018.09.042 ↗