journal article·2023-10-04Open access

Enhanced Corrosion Resistance and Surface Wettability of PVDF/ZnO and PVDF/TiO2 Composite Coatings: A Comparative Study

Adel Mohamed, Abdulrahman Alateyah, Hosam Hasan, Penchal Matli, Mohamed El-Sayed Seleman, Essam Ahmed, Waleed El-Garaihy, Teresa Golden

Coatings· Volume 13· Issue 10

Abstract

This study aims to enhance the practical performance of PVDF/ZnO and PVDF/TiO2 composite coatings known for their distinctive properties. The coatings, applied through spray coating with PVDF and ZnO or TiO2 nanoparticles on glass, steel, and aluminum substrates, underwent a comprehensive evaluation. Surface wetting properties and morphology were respectively evaluated using a technique involving liquid droplets and an imaging method using high-energy electrons. Potentiodynamic polarization was used to compare corrosion resistance between coated and bare substrates. Nanoindentation was used to assess coating hardness, and bonding strength was subsequently quantified. The results revealed that PVDF/ZnO composite coatings had higher water contact angles (161 ± 5° to 138 ± 2°) and lower contact angle hysteresis (7 ± 2° to 2 ± 1°) compared to PVDF/TiO2 and PVDF coatings. Moreover, corrosion tests demonstrated superior protection for steel and aluminum surfaces coated with superhydrophobic PVDF/ZnO. Nanoindentation indicated enhanced mechanical properties with TiO2 nanoparticles, with adhesion results favoring TiO2 over ZnO nanoparticles.
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Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Surface Modification and Superhydrophobicity · Polymer Nanocomposite Synthesis and Irradiation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Metallurgical and Materials Engineering, Faculty of Petroleum and Mining Engineering, Suez University, Suez 43512, Egypt

Department of Mechanical Engineering, College of Engineering, Qassim University, Unaizah 56452, Saudi Arabia

Department of Physics, Sri Krishnadevaraya University, Anantapur 515003, India

Mechanical Engineering Department, Faculty of Engineering, Suez Canal University, Ismailia 41522, Egypt

Department of Chemistry, University of North Texas, 1155 Union Circle #305070, Denton, TX 76203, USA

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