journal article·2022-11-19Open access

High Temperature Low Friction Behavior of h-BN Coatings against ZrO2

Qunfeng Zeng

Coatings· Volume 12· Issue 11

Abstract

This paper presents high temperature low friction behaviors of the h-BN coatings, which were deposited on high-speed tool steel by radio frequency magnetron sputtering. A tribometer was used to investigate high temperature tribological properties of h-BN coatings against ZrO2 from 500 °C to 800 °C. The surface morphology, mechanical properties and chemical states of the worn surface of the friction pair were characterized and investigated systemically. The experimental results show that h-BN coatings are of significant importance to improve high temperature tribological properties of steel. Moreover, it is found that high temperature super low friction of the friction pairs is successfully achieved due to tribochemistry, which plays a key role in forming the in-situ generated Fe2O3/h-BN composites on the worn surface of h-BN coatings. CoFs of the friction pair are as super low as about 0.02 at 800 °C and around 0.03 at 600 °C at the stable stage. The high temperature super low friction mechanism of the friction pair is discussed in detail. The present study opens a new strategy to achieve high temperature super low friction of the friction system during sliding.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research · Lubricants and Their Additives

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Education Ministry for Modern Design and Rotor-Bearing System, Xi’an Jiaotong University, Xi’an 710049, China

Funding

National Natural Science Foundation of China · National Science and Technology Major Project · Natural Science Foundation of Chongqing, China · Natural Science Basic Research Plan in Shaanxi Province of China

References (47)

Show source-provided references
1. Trzepiecinski, T., and Lemu, H. (2019). Recent developments and trends in the friction testing for conventional sheet metal forming and incremental sheet forming. Metals, 10.10.3390/met10010047 ↗
2. Nanocomposite and nanostructured tribological materials for space applications
3. Transformation-induced high temperature low friction behaviors of ZrO2-steel system at temperatures up to 900 °C10.1088/2053-1591/ab26fd ↗
4. The effect of counterface on the tribological performance of a high temperature solid lubricant composite from 25 to 650 °C10.1016/S0257-8972(96)02959-3 ↗
5. Zeng, Q. (2021). High-temperature superlubricity behaviors of γ-Fe2O3@SiO2 nanocomposite coatings. Composite Materials, Elsevier.10.1016/B978-0-12-820512-9.00009-5 ↗
6. Nowak, P., Kucharska, K., and Kamiński, M. (2019). Ecological and health effects of lubricant oils emitted into the environment. Int. J. Environ. Res. Public Health, 16.10.3390/ijerph16163002 ↗
7. Experimental analysis of tribological properties of lubricating oils with nanoparticle additives10.1016/j.wear.2006.08.021 ↗
8. Towards the use of diamond-like carbon solid lubricant coatings in vacuum and space environments10.1243/13506501JET323 ↗
9. Zeng, Q., Erdemir, A., and Eryilmaz, O. (2017). Ultralow friction of ZrO2 ball sliding against DLC films under various environments. Appl. Sci., 7.10.3390/app7090938 ↗
10. Probing superlubricity stability of hydrogenated diamond-like carbon film by varying sliding velocity10.1016/j.apsusc.2018.01.048 ↗
11. Vazirisereshk, M., Martini, A., Strubbe, D., and Baykara, M.Z. (2019). Solid lubrication with MoS2: A review. Lubricants, 7.10.3390/lubricants7070057 ↗
12. Manu, B., Gupta, A., and Jayatissa, A. (2021). Tribological properties of 2D materials and composites—A review of recent advances. Materials, 14.10.3390/ma14071630 ↗
13. Microstructure and tribological properties of WS2/MoS2 multilayer films10.1016/j.apsusc.2011.06.148 ↗
14. Uzoma, P.C., Hu, H., Khadem, M., and Penkov, O.V. (2020). Tribology of 2D nanomaterials: A review. Coatings, 10.10.20944/preprints202008.0683.v1 ↗
15. Elevated-temperature super-lubrication performance analysis of dispersion-strengthened WSN coatings: Experimental research and first-principles calculation10.1016/j.surfcoat.2020.126651 ↗
16. Superlubricity behaviors of Si3N4/DLC Films under PAO oil with nano boron nitride additive lubrication10.1002/sia.5269 ↗
17. Tribological behaviour and lubrication performance of hexagonal boron nitride (h-BN) as a replacement for graphite in aluminium forming10.1016/j.triboint.2014.09.011 ↗
18. Friction and anti-galling properties of hexagonal boron nitride (h-BN) in aluminium forming10.1016/j.wear.2017.04.026 ↗
19. Novel chemical process for preparing h-BN solid lubricant coatings on titanium-based substrates for high temperature tribological applications10.1016/j.surfcoat.2015.03.040 ↗
20. Advancements in superlubricity10.1007/s11431-013-5387-y ↗
21. Effect of h-BN addition on friction and wear properties of C/C-SiC composites fabricated by LSI10.1111/ijac.13838 ↗
22. Tribological properties of h-BN matrix solid-lubricating composites under elevated temperatures10.1016/j.triboint.2020.106333 ↗
23. High-temperature tribological behaviors of ZrO2/h-BN/SiC composite under air and vacuum environments10.1016/j.triboint.2020.106748 ↗
24. High-temperature friction and wear of Ag/h-BN-containing Ni-based composites against steel10.1007/s11249-010-9655-8 ↗
25. Microstructure and tribological performance of laser-cladded Ni60/h-BN coatings on Ti-6Al-4V alloy at high temperature10.1080/10402004.2019.1617916 ↗
26. Investigation of hBN powder lubricating characteristics of die steel H13-ceramic Si3N4tribopairat 800 °C10.1177/1350650119873252 ↗
27. Compatibility of graphite, hBN and graphene with self-lubricating coatings and tool steel for high temperature aluminium forming10.1016/j.wear.2021.204187 ↗
28. Effects of multiple post weld heat treatments on microstructure and precipitate of fine grained heat affected zone of P91 weld10.1002/srin.201800607 ↗
29. Micro structural characterization of BN thin films using RF magnetron sputtering method10.1016/j.matpr.2020.02.493 ↗
30. Tran, T., and Chung, K. (2020). Tribological characteristics of single-layer h-BN measured by colloidal probe atomic force microscopy. Coatings, 10.10.3390/coatings10060530 ↗
31. Effects of initial texture on rolling texture and property of electrodeposited nickel plate10.1166/jctn.2015.4156 ↗
32. Study on the friction and wear performance of lightly loaded reciprocating carbon/aramid-based composites10.1155/2021/9924690 ↗
33. High photo degradation and antibacterial activity of BN-Ag/TiO2 composite nanofibers under visible light10.1039/C7NJ03183A ↗
34. Magnetic and electrical properties of poly pyrrole-coated γ-Fe2O3 nanocomposite particles10.1088/0957-4484/14/6/311 ↗
35. Theoretical and experimental investigation of the electronic, optical, electric, and elastic properties of Zn-doped anatase TiO2 for photocatalytic applications10.1007/s00339-021-04721-4 ↗
36. Conducting polythiophene/α-Fe2O3 nanocomposite for efficient methanol electrochemical sensor10.1016/j.apsusc.2019.145226 ↗
37. Aging study on carboxymethyl cellulose-coated zero-valent iron nanoparticles in water: Chemical transformation and structural evolution10.1016/j.jhazmat.2016.03.069 ↗
38. Enhanced photoelectrochemical water splitting efficiency of hematite (α-Fe2O3)-Based photoelectrode by the introduction of maghemite (γ-Fe2O3) nanoparticles10.1016/j.jphotochem.2021.113179 ↗
39. Resonance Raman studies of nitric oxide binding to ferric and ferrous hemoproteins: Detection of Fe (III)-NO stretching, Fe (III)-N-O bending, and Fe (II)-N-O bending vibrations10.1073/pnas.80.22.7042 ↗
40. Micro-Raman investigation of terra sigillata slips: A comparative study of central Italian and southern Gaul productions10.1002/jrs.2678 ↗
41. A novel sonogel based on h-BN nanosheets for the tribological application under extreme conditions10.1016/j.triboint.2019.05.045 ↗
42. High-temperature oxidation of boron nitride10.1016/S0272-8842(86)80006-2 ↗
43. High temperature anti-friction behaviors of a-Si: H films and counterface material selection10.3390/coatings9070450 ↗
44. Superlow friction and oxidation analysis of hydrogenated amorphous silicon films under high temperature10.1016/j.jnoncrysol.2018.04.041 ↗
45. Superlubricity of the DLC films-related friction system at elevated temperature10.1039/C5RA16084G ↗
46. Dwindling the re-stacking by simultaneous exfoliation of boron nitride and decoration of α-Fe2O3 nanoparticles using a solvo thermal route10.1039/C7NJ04325B ↗
47. Phase transition of electro oxidized Fe3O4 to γ and α-Fe2O3 nano particles using sintering treatment10.12693/APhysPolA.125.1210 ↗