journal article·2019-04-25Open access

A Zinc-Rich Coating Fabricated on a Magnesium Alloy by Oxide Reduction

Dongzhu Lu, Yanliang Huang, Jizhou Duan, Baorong Hou

Coatings· Volume 9· Issue 4

Abstract

The corrosion resistance of magnesium alloys could be enhanced by covering metallic coatings on the surface. The zinc-rich coating is one of these metallic coatings. To fabricate a zinc-rich coating on magnesium alloys, the substrate should be pretreated carefully, and a protective atmosphere is usually required. In this research, a zinc-rich coating was successfully fabricated on the AZ91D magnesium alloy in air by a diffusion alloying method, with zinc oxide as the zinc source. At the same time, the pretreatment of the magnesium alloy matrix was greatly simplified. The as-diffusion-alloyed zinc-rich intermetallic layer was investigated, utilizing SEM, EDS, and XRD, respectively. It is inferred that zinc oxide was reduced into Zn atoms by the active Mg atoms, and the Mg atoms were coming from the magnesium alloy matrix. Then the Zn atoms passed through the oxide film and formed an intermetallic layer on the magnesium alloy surface. Thus, taking advantage of the activity of Mg atoms, magnesium alloys could be surface alloyed with oxides.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China

Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266237, China

Center for Ocean Mega-Science, Chinese Academy of Sciences, Qingdao 266071, China

Funding

the Key Research & Development Program of Shandong Province · the Applied Research Program of Qingdao

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