journal article·2022-01-04Open access

Electrodeposition of Thick and Crack-Free Fe-Cr-Ni Coatings from a Cr (III) Electrolyte

Vanessa Meinhold, Dominik Höhlich, Thomas Mehner, Thomas Lampke

Coatings· Volume 12· Issue 1

Abstract

The electrodeposition of iron-nickel-chromium coatings is a more environmentally friendly and economical alternative to hard-chrome coatings made from chromium (VI) electrolytes and stainless-steel bulk materials. The aim of the study was to develop a suitable deposition method for thick and low-crack Fe-Cr-Ni coatings. Iron-nickel-chromium coatings were electrodeposited using a more ecological chromium (III) electrolyte with direct current (DC), stepped direct current, and pulse current (PC). The influence of the deposition method on the electrolyte aging, the alloy composition of the coating, and their microstructure was investigated. Corrosion studies of the Fe-Cr-Ni coatings in 3.5% NaCl solution were performed using polarization tests. Furthermore, hardness measurements and scratch tests were carried out to determine the adhesion strength. Phase analyses were performed by X-ray diffraction, and the chemical composition and microstructure were characterized by scanning electron microscopy. Using the stepped DC and PC method, crack-free Fe-Cr-Ni coatings were successfully deposited.
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Research context

OpenAlex topics: Electrodeposition and Electroless Coatings · Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials and Surface Engineering Group, Institute of Materials Science and Engineering, Faculty of Mechanical Engineering, Chemnitz University of Technology, D-09107 Chemnitz, Germany

References (28)

Show source-provided references
1. (2021, November 04). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 Concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), Establishing a European Chemicals Agency, Amending Directive 1999/4. 2017, 10, 1–21. Available online: http://data.europa.eu/eli/reg/2006/1907/2021-10-01.
2. Hard chromium plating of EDT mill work rolls
3. Crack density and tribological performance of hard-chrome coatings10.1016/j.triboint.2018.01.055 ↗
4. Residual stresses and strength of hard chromium coatings10.4028/www.scientific.net/MSF.681.133 ↗
5. “Green” Cr(III)-glycine electrolyte for the production of FeCrNi coatings: Electrodeposition mechanisms and role of by-products in terms of coating composition and microstructure10.1039/C9RA04262H ↗
6. Stainless steel-like FeCrNi nanostructures via electrodeposition into AAO templates using a mixed-solvent Cr(III)-based electrolyte10.1016/j.matdes.2020.108559 ↗
7. The electrodeposition of FeCrNi stainless steel: Microstructural changes induced by anode reactions10.1039/C4CP03744H ↗
8. Electroplating of stainless steel10.1021/cm703591n ↗
9. Electrodeposition and characterization of amorphous Fe-Ni-Cr-based alloys10.1007/BF00249658 ↗
10. Properties of Fe-Ni-Cr alloy coatings by using direct and pulse current electrodeposition10.1016/j.jallcom.2008.09.108 ↗
11. Electrodeposition of FeCrNi and FeCr alloys and influence of heat treatment on microstructure and composition10.1088/1757-899X/1147/1/012003 ↗
12. A Preliminary Investigation of the formation of cracks in hard chromium electrodeposits and the evolution of hydrogen during deposition10.1080/00202967.1955.11869702 ↗
13. Microcracks in chromium electrodeposits10.1023/A:1018639800595 ↗
14. On the mechanism of microcrack formation in nanocrystalline Fe-Ni electrodeposits10.1023/A:1018693005002 ↗
15. Electrodeposition of nanocrystalline chromium coatings from cr(iii)-based electrolyte using pulsed current10.1134/S2070205111050066 ↗
16. Electrodeposition of thick chromium coatings from an environmentally acceptable chromium (III)-glycine complex10.1080/00202967.1999.11871269 ↗
17. Effects of CeO2 on friction and wear characteristics of Fe-Ni-Cr alloy coatings10.1016/j.triboint.2005.08.003 ↗
18. Electroplating of Ni-Cr on steel with pulse plating10.1007/BF02652390 ↗
19. The role of hydrogen in metal electrodeposition processes10.1023/A:1018497401365 ↗
20. Electrochemical characterization of chromium deposition from trivalent solutions for decorative applications by EQCM and near-surface pH measurements10.1016/j.electacta.2018.03.011 ↗
21. What is behind the inverse Hall-Petch effect in nanocrystalline materials?10.1016/j.actamat.2007.02.021 ↗
22. Electrodeposition and characterization of nanocrystalline Fe−Ni−Cr alloy coatings synthesized via pulse current method10.1016/S1003-6326(19)65166-6 ↗
23. The behavior of electroplated hard-chromium on Cr-Mo steel subject to long-term annealing at 250 °C10.1016/j.msea.2005.05.007 ↗
24. Deviations from hall-petch behaviour in as-prepared nanocrystalline nickel10.1016/0956-716X(92)90596-7 ↗
25. Akram, W., Mateen, A., Qazi, I., and Hussain, A. (2019, January 8–12). Development and characterization of cost effective wear and corrosion resistant HVOF sprayed chromite coatings and hard chrome plating. Proceedings of the 2019 16th International Bhurban Conference on Applied Sciences and Technology (IBCAST), Islamabad, Pakistan.10.1109/IBCAST.2019.8667168 ↗
26. Electrodeposition of amorphous Fe-Cr-Ni stainless steel alloy with high corrosion resistance, low cytotoxicity and soft magnetic properties10.1016/j.surfcoat.2018.06.003 ↗
27. Effect of Cr(III) solution chemistry on electrodeposition of chromium10.1007/s10800-005-9105-8 ↗
28. A combined surface analytical and electrochemical study of the formation of passive layers on Fe Cr alloys in 0.5 M H2SO410.1016/0010-938X(94)00104-E ↗