journal article·2023-03-10Open access

Photocatalytic Self-Cleaning PVDF Membrane Blended with MWCNT-ZnO Nanocomposites for RhB Removal

Dana Toloman, Maria Stefan, Sergiu Macavei, Lucian Barbu-Tudoran, Adriana Popa

Coatings· Volume 13· Issue 3

Abstract

Polyvinylidene fluoride (PVDF) membranes blended with various amounts of MWCNT-ZnO (0.1%–3%) nanocomposites were prepared by the phase inversion method. The effect of nanocomposites blending on the membrane structural and morphological properties was investigated by XRD, FT-IR and SEM techniques. Contact angle measurement reveals that the hydrophilicity of the membrane increases with the increase of nanocomposite content; a reduction of the contact angle from 103° for PVDF to 49° for hybrid membrane was obtained. An optimum amount of 0.5% of MWCNT-ZnO blended in a PVDF hybrid membrane assured 85% removal rate of RbB under UV light irradiation. It was observed that the pollutant removal occurs through the simultaneous action of two processes: adsorption and photocatalysis. By blending with MWCNT-ZnO nanoparticles, the PVDF membrane acquires photocatalytic properties which assure a self-cleaning property in the membrane, increasing its lifetime.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Membrane Separation Technologies · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute for Research and Development of Isotopic and Molecular Technologies, 67-103 Donat St., 400293 Cluj-Napoca, Romania

Faculty of Biology and Geology, Electron Microscopy Laboratory, Babes-Bolyai University, 5-7 Clinicilor St., 400006 Cluj-Napoca, Romania

References (41)

Show source-provided references
1. Sudarshan, S., Bharti, V.S., Harikrishnan, S., Shukla, S.P., and Bhuvaneswari, G.R. (2022). Eco-toxicological effect of a commercial dye Rhodamine B on freshwater microalgae Chlorella vulgaris. Arch. Microbiol., 204.10.1007/s00203-022-03254-5 ↗
2. Rhodamine B in spices determined by a sensitive UPLC-MS/MS method10.1080/19393210.2018.1548504 ↗
3. Bhattarai, N., Chen, M., Pérez, R., Ravula, S., Strongin, R., McDonough, K., and Warner, I. (2020). Comparison of chemotherapeutic activities of rhodamine-based GUMBOS and NanoGUMBOS. Molecules, 25.10.3390/molecules25143272 ↗
4. Lignin modified PVDF membrane with antifouling properties for oil filtration10.1016/j.jwpe.2021.102248 ↗
5. Polymeric nanocomposite membranes for water treatment: A review10.1007/s10311-019-00895-9 ↗
6. A review of water treatment membrane nanotechnologies10.1039/c0ee00541j ↗
7. Hudaib, B., Abu-Zurayk, R., Waleed, H., and Ibrahim, A.A. (2022). Fabrication of a Novel (PVDF/MWCNT/Polypyrrole) Antifouling High Flux Ultrafiltration Membrane for Crude Oil Wastewater Treatment. Membranes, 12.10.3390/membranes12080751 ↗
8. Fabrication of polyvinylidene fluoride blending membrane coupling with microemulsion polymerization and their anti-fouling performance10.1016/j.polymer.2020.122767 ↗
9. PVDF membrane biofunctionalization by chemical grafting10.1016/j.memsci.2014.12.004 ↗
10. Hybrid PVDF-P(L-DOPA)-ZnO membranes for dyes and antibiotics removal through simultaneous action of adsorption and photocatalysis processes10.1016/j.jece.2021.106812 ↗
11. Tailoring the RhB removal rate by modifying the PVDF membrane surface through ZnO particles deposition10.1007/s10904-020-01795-0 ↗
12. Wang, W., and Sun, H. (2020). Effect of different forms of nano-ZnO on the properties of PVDF/ZnO hybrid membranes. J Appl. Polym. Sci., 137.10.1002/app.49070 ↗
13. Preparation and characterization of PVDF/TiO2 mixed matrix membrane via in situ colloidal precipitation method10.1016/j.desal.2012.03.019 ↗
14. ZnO Nanorod Array Modified PVDF Membrane with Superhydrophobic Surface for Vacuum Membrane Distillation Application10.1021/acsami.8b00271 ↗
15. Impact of a new functionalization of multiwalled carbon nanotubes on antifouling and permeability of PVDF nanocomposite membranes for dye wastewater treatment10.1016/j.chemosphere.2022.133699 ↗
16. Preparation of a Novel Polyvinylidene Fluoride (PVDF) Ultrafiltration Membrane Modified with Reduced Graphene Oxide/Titanium Dioxide (TiO2) Nanocomposite with Enhanced Hydrophilicity and Antifouling Properties10.1021/ie502407g ↗
17. Electroactive phases of poly(vinylidene fluoride): Determination, processing and applications10.1016/j.progpolymsci.2013.07.006 ↗
18. Modification of PVDF membranes using BiOBr precursor in-situ deposition and tannic acid self-assembly for effectively removing organic pollutants10.1016/j.apsusc.2022.153888 ↗
19. Hudandini, M., Puri, N.R., Winardi, S., Widiyastuti, W., Shimada, M., and Kusdianto, K. (2022). Photocatalytic Activity of ZnO/Ag Nanoparticles Fabricated by a Spray Pyrolysis Method with Different O2:N2 Carrier Gas Ratios and Ag Contents. Catalysts, 12.10.3390/catal12111374 ↗
20. A facile synthesis of ZnO/CNT hierarchical microsphere composites with enhanced photocatalytic degradation of methylene blue10.1039/C5RA11873E ↗
21. Achieving Enhanced Photocatalytic Activity of ZnO Supported on MWCNTs towards Degradation of Pollutants Under Visible Light. Mater
22. Preparation of a MWCNT/ZnO nanocomposite and its photocatalytic activity for the removal of cyanide from water using a laser10.1088/0957-4484/21/49/495705 ↗
23. Barrier performance and biodegradability of antibacterial poly(butylene adipate-coterephthalate) nanocomposites reinforced with a new MWCNT-ZnO nanomaterial10.1088/1361-6528/ac1b52 ↗
24. Visible-light responsive PVDF/carbon sphere@TiO2 membrane for dye scavenging and bacteria inactivation10.1016/j.apsusc.2022.154755 ↗
25. A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR10.1039/C7RA01267E ↗
26. ZnO Nanowires@PVDF nanofiber membrane with superhydrophobicity for enhanced anti-wetting and anti-scaling properties in membrane distillation10.1016/j.memsci.2020.118877 ↗
27. Nanoparticle size and surface chemistry effects on mechanical and physical properties of nano-reinforced polymers: The case of PVDF-Fe3O4 nano-composites10.1016/j.polymertesting.2022.107851 ↗
28. Barabaszov, K.C., Holesova, S., Plesník, L., Kolska, Z., Joszko, K., and Gzik-Zrosk, B. (2022). Hybrid Nanofillers Creating the Stable PVDF Nanocomposite Films and Their Effect on the Friction and Mechanical Properties. Polymers, 14.10.3390/polym14183831 ↗
29. Apostolescu, N., Tataru Farmus, R.E., Harja, M., Aurelia Vizitiu, M., Cernatescu, C., Cobzaru, C., and Apostolescu, G.A. (2023). Photocatalytic Removal of Antibiotics from Wastewater Using the CeO2/ZnO Heterojunction. Materials, 16.10.3390/ma16020850 ↗
30. Viana da Silva, A.F., Cesca, K., Ambrosi, A., Zin, G., Di Luccio, M., and Oliveira, J.V. (2022). An expedite facile method for modification of PVDF membranes with polydopamine and TiO2 to improve water permeation. Mater. Lett., 324.10.1016/j.matlet.2022.132611 ↗
31. Structural, optical, morphological and electrochemical properties of ZnO and graphene oxide blended ZnO nanocomposites10.1016/j.ceramint.2022.10.192 ↗
32. Synthesis and characterization of ZnO NRs with spray coated GO for enhanced photocatalytic activity10.1016/j.ceramint.2022.03.082 ↗
33. Investigation of TSDC and dielectric modulus of PVDF–BaZrO3 nanocomposites thin film10.1016/j.vacuum.2018.07.037 ↗
34. Shen, L., Huang, Z., Liu, Y., Li, R., Xu, Y., Jakaj, G., and Lin, H. (2020). Polymeric Membranes Incorporated With ZnO Nanoparticles for Membrane Fouling Mitigation: A Brief Review. Front. Chem., 8.10.3389/fchem.2020.00224 ↗
35. Multi-walled carbon nanotube/PVDF blended membranes with sponge- and finger-like pores for direct contact membrane distillation10.1016/j.desal.2014.11.025 ↗
36. Precisely-controlled modification of PVDF membranes with 3D TiO2/ZnO nanolayer: Enhanced anti-fouling performance by changing hydrophilicity and photocatalysis under visible light irradiation10.1016/j.memsci.2017.01.048 ↗
37. The photodegradation of methylene blue in water with PVDF/GO/ZnO composite membrane10.1016/j.msec.2018.11.049 ↗
38. Hayashi, T., Nakamura, K., Suzuki, T., Saito, N., and Murakami, Y. (2020). OH radical formation by the photocatalytic reduction reactions of H2O2 on the surface of plasmonic excited Au-TiO2 photocatalysts. Chem. Phys. Lett., 739.10.1016/j.cplett.2019.136958 ↗
39. Growing Co-doped TiO2 nanosheets on reduced graphene oxide for efficient photocatalytic removal of tetracycline antibiotic from aqueous solution and modeling the process by artificial neural network10.1016/j.jallcom.2019.05.175 ↗
40. Stefan, M., Leostean, C., Popa, A., Toloman, D., Perhaita, I., Cadis, A., Macavei, S., and Pana, O. (2022). Highly stable MWCNT-CoFe2O4 photocatalyst. EGA-FTIR coupling as efficient tool to illustrate the formation mechanism. J. Alloy. Compd., 928.10.1016/j.jallcom.2022.167188 ↗
41. Photocorrosion suppression of ZnO nanoparticles via hybridization with graphite-like carbon and enhanced photocatalytic activity10.1021/jp807778r ↗