journal article·2021-08-26Open access

Enhanced the Efficiency of Photocatalytic Degradation of Methylene Blue by Construction of Z-Scheme g-C3N4/BiVO4 Heterojunction

Xiong Zhang, Minjin Li, Cheng Liu, Zhiyong Zhang, Fuchun Zhang, Qiaoping Liu

Coatings· Volume 11· Issue 9

Abstract

Both non-metallic g-C3N4 and BiVO4 are novel photocatalysts responsive to visible light, but their low charge separation efficiency restricts their inconspicuous photocatalytic activity. In this paper, direct Z-type g-C3N4/BiVO4 photocatalyst was constructed by calcination and hydrothermal for the degradation of methylene blue. The existence of g-C3N4/BiVO4 heterojunction was confirmed by the detailed study of its chemical structure and morphology by various characterization methods, such as X-ray diffraction (XRD), Scanning electron microscope (SEM), and X-ray photoelectron spectroscopy (XPS). The evaluation of photocatalytic performance showed that the MB degradation performance of 1.0-CN/BVO was significantly enhanced, which was 4.528 times and 2.387 times higher than pristine BiVO4 and g-C3N4, respectively, which was mainly due to the enhanced light capture ability and effective electron transfer in the photocatalytic reaction. The 1.0-CN/BVO composite exhibited extremely catalytic stability and recyclability.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Gas Sensing Nanomaterials and Sensors · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Information Science & Technology, Northwest University, Xi’an 710127, China

School of Physics and Electronic Information, Yan’an University, Yan’an 716000, China

Shaanxi Key Laboratory of Intelligent Processing for Big Energy Data, Yan’an University, Yan’an 716000, China

Funding

General Special Scientific Research Plan of Education Department of Shaanxi Provincial Government · Shaanxi Key Laboratory of Intelligent Processing for Big Energy Data Foundation Funding project · Shaanxi Provincial Education Department Natural Science Special Fund

References (39)

Show source-provided references
1. Nanomaterials for energy conversion and storage10.1002/cnma.201600177 ↗
2. Facile fabrication of highly efficient g-C3N4/Ag2O heterostructured photocatalysts with enhanced visible-light photocatalytic activity10.1021/am4038307 ↗
3. Photocatalytic CO2 reduction by CdS promoted with a zeolitic imidazolate framework10.1016/j.apcatb.2014.07.026 ↗
4. Progress in bismuth vanadate photoanodes for use in solar water oxidation10.1039/C2CS35260E ↗
5. CTAB-assisted synthesis of monoclinic BiVO4 photocatalyst and its highly efficient degradation of organic dye under visible-light irradiation10.1016/j.jhazmat.2009.08.068 ↗
6. Hydrothermal synthesis and photoelectric properties of BiVO4 with different morphologies: An efficient visible-light photocatalyst10.1016/j.apsusc.2011.04.025 ↗
7. Effects of structure, morphology, and up-conversion on Nd-doped BiVO4 system with high photocatalytic activity10.1016/j.ceramint.2014.11.016 ↗
8. Nanostructured bismuth vanadate-based materials for solar-energy-driven water oxidation: A review on recent progress10.1039/C4NR05245E ↗
9. Synthesis and characterization of a core-shell BiVO4@g-C3N4 photo-catalyst with enhanced photocatalytic activity under visible light irradiation10.1039/C6RA27766G ↗
10. Difference in valence band top of BiVO4 with different crystal structure10.1016/j.matchemphys.2012.08.023 ↗
11. Monoclinic–tetragonal heterostructured BiVO4 by yttrium doping with improved photocatalytic activity10.1021/jp409170y ↗
12. Effects of pH on the hierarchical structures and photocatalytic performance of BiVO4 powders prepared via the microwave hydrothermal method10.1021/am401019m ↗
13. Factors in the metal doping of BiVO4 for improved photoelectrocatalytic activity as studied by scanning electrochemical microscopy and first-principles density-functional calculation10.1021/jp204492r ↗
14. Facile and sustainable synthesis of carbon-doped ZnO nanostructures towards the superior visible light photocatalytic performance10.1039/C6NJ04070E ↗
15. Efficient visible-light driven photocatalysts: Coupling TiO2(AB) nanotubes with g-C3N4 nanoflakes10.1007/s10854-016-5655-2 ↗
16. Visible-light neural stimulation on graphitic-carbon nitride/graphene photocatalytic fibers10.1021/acsami.7b12733 ↗
17. g-C3N4-based heterostructured photocatalysts10.1002/aenm.201701503 ↗
18. g-C3N4/BiVO4 composites with enhanced and stable visible light photocatalytic activity10.1016/j.jallcom.2013.12.050 ↗
19. Enhanced photoelectrochemical performance of Z-scheme g-C3N4/BiVO4 photocatalyst10.1016/j.apcatb.2018.04.056 ↗
20. Novel rugby-like g-C3N4/BiVO4 core/shell Z-scheme composites prepared via low-temperature hydrothermal method for enhanced photocatalytic performance10.1016/j.seppur.2019.115937 ↗
21. Mediator-free direct Z-scheme photocatalytic system: BiVO4/g-C3N4 organic-inorganic hybrid photocatalyst with highly efficient visible-light-induced photocatalytic activity10.1039/C4DT03905J ↗
22. Highly active metal-free carbon dots/g-C3N4 hollow porous nanospheres for solar-light-driven PPCPs remediation: Mechanism insights, kinetics and effects of natural water matrices10.1016/j.watres.2020.115492 ↗
23. Synthesis of g-C3N4/BiVO4 heterojunction composites for photocatalytic degradation of nonylphenol ethoxylate10.1016/j.seppur.2020.117202 ↗
24. Fabrication of BiVO4@g-C3N4(100) heterojunction with enhanced photocatalytic visible-light-driven activity10.1016/j.jssc.2019.03.022 ↗
25. Doping strategy to promote the charge separation in BiVO4 photoanodes10.1016/j.apcatb.2017.03.078 ↗
26. Enhanced photocatalytic activity of the carbon quantum dot-modified bioi microsphere10.1186/s11671-016-1262-7 ↗
27. Facile synthesis of g-C3N4/BiVO4 heterojunctions with enhanced visible light photocatalytic performance10.1016/j.ceramint.2016.09.156 ↗
28. Direct Z-scheme photocatalyst for efficient water pollutant degradation: A case study of 2D g-C3N4/BiVO410.1016/j.matchemphys.2019.122308 ↗
29. Facile synthesis of Z-scheme BiVO4 /porous graphite carbon nitride heterojunction for enhanced visible-light-driven photocatalyst10.1016/j.apsusc.2017.06.093 ↗
30. Facile fabrication of g-C3N4 QDs/BiVO4 Z-scheme heterojunction towards enhancing photodegradation activity under visible light10.1016/j.jtice.2018.10.011 ↗
31. A sonochemical route to visible-light-driven high-activity BiVO4 photocatalyst10.1016/j.molcata.2006.01.052 ↗
32. Excellent visible-light photocatalysis of fluorinated polymeric carbon nitride solids10.1021/cm1019102 ↗
33. N-doped graphitic carbon-incorporated g-C3N4 for remarkably enhanced photocatalytic H-2 evolution under visible light10.1016/j.carbon.2015.12.008 ↗
34. Eu doped g-C3N4 nanosheet coated on flower-like BiVO4 powders with enhanced visible light photocatalytic for tetracycline degradation10.1016/j.apsusc.2018.05.084 ↗
35. A novel hydrothermal induced BiVO4/g-C3N4 heterojunctions visible-light photocatalyst for effective elimination of aqueous organic pollutants10.1016/j.vacuum.2020.109458 ↗
36. Thiophene-containing pechmann dye derivatives10.1021/ol1019772 ↗
37. Direct Z-scheme photocatalysts: Principles, synthesis, and applications10.1016/j.mattod.2018.04.008 ↗
38. A Hierarchical Z-scheme alpha-Fe2O3/g-C3N4 hybrid for enhanced photocatalytic CO2 reduction10.1002/adma.201706108 ↗
39. Novel ternary heterojunction photcocatalyst of Ag nanoparticles and g-C3N4 nanosheets co-modified BiVO4 for wider spectrum visible-light photocatalytic degradation of refractory pollutant10.1016/j.apcatb.2016.12.017 ↗