journal article·2022-01-30Open access

Multiwalled-Carbon-Nanotubes (MWCNTs)–GPTMS/Tannic-Acid-Nanocomposite-Coated Cotton Fabric for Sustainable Antibacterial Properties and Electrical Conductivity

Marwa M. Abd El-Hady, Asmaa Farouk, Samar Sharaf

Coatings· Volume 12· Issue 2

Abstract

We propose a method of crosslinking multiwalled carbon nanotubes (MWCNTs) with cotton fabric. 3-Glycidoxypropyltrimethoxy silane (GPTMS) polymer was used for the stabilization and modification of the surfaces of MWCNTs. The presence of tannic acid in the finishing formulation adds a sustainable functionality to the treated surface. The formation of the GPTMS–MWCNTs nanocomposite as well as the MWCNTs–GPTMS tannic-epoxy nanocomposite on the fabric surface was confirmed by Fourier-transform infrared spectra (FTIR). The surface morphology and physical properties were investigated. An assessment of antibacterial activity, UV-protective properties, and electrical conductivity was performed. The post-treatment results of the MWCNTs–GPTMS nanocomposite fabric with tannic acid exhibited superior antibacterial character with the highest inhibition zones for Staphylococcus aureus and Escherichia coli (26 mm, 24 mm). On the contrary, the electrical conductivity was negatively impacted. The treatment of cotton fabric with tannic acid showed a great UV-protection-factor estimation of 96.2, which was additionally improved by treatment with MWCNTs 152.1. Cotton fabric treated with cotton/GPTMS/tannic acid/MWCNTs as well as cotton/GPTMS/MWCNTs recorded the highest electrical-conductivity properties. Fabrication of MWCNTs–GPTMS/tannic-acid-nanocomposite-coated cotton fabric for durable antibacterial and UV protection with improved electrical and physical properties was successfully achieved.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Conducting polymers and applications · Nanoparticles: synthesis and applications · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Research Centre, Textile Research and Technology Institute, 33 El-Behoth Street, Dokki, Cairo P.O. Box 12622, Egypt

Department of Physics, College of Science and Arts in Al-Asyah, Qassim University, Buraidah 51452, Saudi Arabia

Department of Chemistry, Faculty of Science, King Khalid University, Abha 62529, Saudi Arabia

References (53)

Show source-provided references
1. Multi-walled carbon nanotube-coated cotton fabric for possible energy storage devices10.1007/s12034-014-0829-0 ↗
2. Hyperbranched polymer–silver nanohybrid induce super antibacterial activity and high performance to cotton fabric10.1007/s10570-019-02319-x ↗
3. Wound dressing properties of cationized cotton fabric treated with carrageenan/cyclodextrin hydrogel loaded with honey bee propolis extract10.1016/j.ijbiomac.2019.04.065 ↗
4. Novel route for antibacterial finishing of cotton fabric based on Ag loaded cyclodextrin—PAN copolymers10.21608/ejchem.2016.1553 ↗
5. Potential Advantages and Risks of Nanotechnology for Textiles
6. Flame retardancy and UV protection of cotton-based fabrics using nano ZnO and polycarboxylic acids10.1016/j.carbpol.2012.08.085 ↗
7. High performance fabrics via innovative reinforcement route using cellulose nanoparticles10.1080/00405000.2017.1335377 ↗
8. Novel conductive textile fabric based on polyaniline and CuO nanoparticles
9. Highly hydrophobic and UV protective properties of cotton fabric using layer by layer self-assembly technique10.1007/s10570-019-02815-0 ↗
10. Photocatalytic activity and antibacterial properties of linen fabric using reduced graphene oxide/silver nanocomposite10.1039/D0RA07544B ↗
11. The antimicrobial activity of cotton fabrics treated with different crosslinking agents and chitosan10.1016/j.carbpol.2005.02.019 ↗
12. Antimicrobial and physical properties of woolen fabrics cured with citric acid and chitosan10.1002/app.21104 ↗
13. New insights into the protogenic and spectroscopic properties of commercial tannic acid: The role of gallic acid impurities10.1039/C7NJ04903J ↗
14. Kaczmarek, B. (2020). Tannic acid with antiviral and antibacterial activity as a promising component of biomaterials—A minireview. Materials, 13.10.3390/ma13143224 ↗
15. Tannic acid functionalized UV-curable carbon nanotube: Effective reinforcement of acrylated epoxidized soybean oil coating10.1016/j.porgcoat.2019.01.035 ↗
16. Stabilized nanosilver loaded nylon knitted fabric using BTCA without yellowing10.1016/j.porgcoat.2012.01.003 ↗
17. A novel method for coating of carbon nanotube on cellulose fiber using 1, 2, 3, 4-butanetetracarboxylic acid as a cross-linking agent10.1016/j.porgcoat.2012.01.012 ↗
18. Functional cellulose fibers via polycarboxylic acid/carbon nanotube composite coating10.1007/s11998-012-9429-3 ↗
19. Smart electronic yarns and wearable fabrics for human biomonitoring made by carbon nanotube coating with polyelectrolytes10.1021/nl801495p ↗
20. Electrically conductive yarns based on PVA/carbon nanotubes10.1016/j.compstruct.2005.10.016 ↗
21. Mechanical strength improvement of polypropylene threads modified by PVA/CNT composite coatings10.1016/j.matlet.2008.07.037 ↗
22. Polyvinylpyrrolidone/carbon nanotube/cotton functional nanocomposite: Preparation and characterization of properties10.1007/s12221-018-8308-7 ↗
23. Conductive superhydrophobic cotton fabrics via layer-by-layer assembly of carbon nanotubes for oil-water separation and human motion detection10.1016/j.matlet.2019.06.078 ↗
24. The production of soft, durable, and electrically conductive polyester multifilament yarns by dye-printing them with carbon nanotubes10.1016/j.carbon.2008.11.013 ↗
25. A facile approach for the fabrication of highly stable superhydrophobic cotton fabric with multi-walled carbon nanotubes−azide polymer composites10.1021/la904337z ↗
26. Multi-wall carbon nanotubes and nano titanium dioxide coated on cotton fabric for superior self-cleaning and UV blocking10.1016/S1872-5805(14)60144-X ↗
27. Comparison of the E Test to agar dilution, broth microdilution, and agar diffusion susceptibility testing techniques by using a special challenge set of bacteria10.1128/jcm.29.3.533-538.1991 ↗
28. Methods for in vitro evaluating antimicrobial activity: A review10.1016/j.jpha.2015.11.005 ↗
29. Electrically conductive textile coating with a PEDOT-PSS dispersion and a polyurethane binder10.1177/0040517512444330 ↗
30. Kasaw, E., Haile, A., and Getnet, M. (2020). Conductive Coatings of Cotton Fabric Consisting of Carbonized Charcoal for E-Textile. Coatings, 10.10.3390/coatings10060579 ↗
31. Palop, J.J., Mucke, L., and Roberson, E.D. (2010). Quantifying biomarkers of cognitive dysfunction and neuronal network hyperexcitability in mouse models of Alzheimer’s disease: Depletion of calcium-dependent proteins and inhibitory hippocampal remodeling. Alzheimer’s Disease and Frontotemporal Dementia, Springer.10.1007/978-1-60761-744-0_17 ↗
32. Structural and morphological characterizations of MWCNTs hybrid coating onto cotton fabric as potential humidity and temperature wearable sensor10.1016/j.snb.2017.05.175 ↗
33. Adsorption of phenolic compounds by carbon nanotubes: Role of aromaticity and substitution of hydroxyl groups10.1021/es801297u ↗
34. Water dispersed multi-walled carbon nanotubes modified by tannin acid10.1016/j.matlet.2014.02.075 ↗
35. Samanta, K.K., Basak, S., and Chattopadhyay, S. (2017). Sustainable dyeing and finishing of textiles using natural ingredients and water-free technologies. Textiles and Clothing Sustainability, Springer.10.1007/978-981-10-2185-5_4 ↗
36. Temperature induced color changing cotton fabricated via grafting epoxy modified thermochromic capsules10.1007/s10570-019-02438-5 ↗
37. Effect of lanthanum 4-hydroxy cinnamate on the polymerisation, condensation and thermal stability of hybrid sol–gel formulations10.1007/s10971-020-05315-x ↗
38. Synthesis of silver nanoparticles decorated on core-shell structured tannic acid-coated iron oxide nanospheres for excellent electrochemical detection and efficient catalytic reduction of hazardous 4-nitrophenol10.1016/j.compositesb.2018.10.084 ↗
39. Superhydrophobic cotton fabric coated with tannic acid/polyhedral oligomeric silsesquioxane for highly effective oil/water separation10.1016/j.porgcoat.2021.106191 ↗
40. Characterization of nanocomposite coatings on textiles: A brief review on microscopic technology
41. Strong adhesion of Saos-2 cells to multi-walled carbon nanotubes10.1016/j.mseb.2009.12.044 ↗
42. Application of carbon nanotube technology for removal of contaminants in drinking water: A review10.1016/j.scitotenv.2009.09.027 ↗
43. Evaluation of the antimicrobial efficacy of green tea extract (egcg) against streptococcus pyogenes in vitro-biomed 2011
44. Antibacterial and antifungal activity of silver nanospheres synthesized by tri-sodium citrate assisted chemical approach10.1016/j.vacuum.2017.10.003 ↗
45. Comparative study of antifungal activity of silver and gold nanoparticles synthesized by facile chemical approach10.1016/j.jece.2018.08.009 ↗
46. Tannins protect against skin tumor promotion induced by ultraviolet-B radiation in hairless mice10.1207/S15327914NC3701_9 ↗
47. Yin, Y., Huang, Z., Wang, P., Zhu, Z., Xu, J., Chen, S., and Wang, H. (2020). The Use of Copper Ions and Tannic Acid to Enhance the UV Protection of Cotton Fabrics. J. Nat. Fibers, 1–10.10.1080/15440478.2020.1848708 ↗
48. Functionalization of cotton with carbon nanotubes10.1039/b801849a ↗
49. Electrical properties and shape-memory behavior of self-assembled carbon nanofiber nano paper incorporated with shape-memory polymer10.1088/0964-1726/19/7/075021 ↗
50. Carbon nanotubes noncovalently functionalized by an organic−inorganic hybrid: New building blocks for constructing superhydrophobic conductive coatings10.1021/la102350t ↗
51. Functionalization of textiles with multi-walled carbon nanotubes by a novel dyeing-like process10.1007/s10853-012-6412-4 ↗
52. UV radiation induced flame retardant cellulose fiber by using polyvinylphosphonic acid/carbon nanotube composite coating10.1016/j.compositesb.2012.07.052 ↗
53. Antibacterial activity of cotton coated with ZnO and ZnO-CNT composites10.1007/s12010-014-1257-8 ↗