Surface Modification and Functional Structure Space Design to Improve the Cycle Stability of Silicon Based Materials as Anode of Lithium Ion Batteries

Silicon anode is considered as one of the candidates for graphite replacement due to its highest known theoretical capacity and abundant reserve on earth. However, poor cycling stability resulted from the “volume effect” in the continuous charge-discharge processes become the biggest barrier limiting silicon anodes development. To avoid the resultant damage to the silicon structure, some achievements have been made through constructing the structured space and pore design, and the cycling stability of the silicon anode has been improved. Here, progresses on designing nanostructured materials, constructing buffered spaces, and modifying surfaces/interfaces are mainly discussed and commented from spatial structure and pore generation for volumetric stress alleviation, ions transport, and electrons transfer improvement to screen out the most effective optimization strategies for development of silicon based anode materials with good property.