journal article·2019-02-03Open access

Effect of Graphene on Flame Retardancy of Graphite Doped Intumescent Flame Retardant (IFR) Coatings: Synergy or Antagonism

Yachao Wang, Jiangping Zhao

Coatings· Volume 9· Issue 2

Abstract

A comparative study between graphene and modified graphene oxide (mGO) on the flame retardancy of graphite doped intumescent flame retardant (IFR) coatings is preliminarily investigated by cone calorimeter (CC), XRD, and SEM, with the final aim of clarifying the interactions between different graphenes and graphite doped coatings (polyester resin-ammonium polyphosphate-urea-pentaerythritol). The CC results determine that graphene exerts an obviously antagonistic effect on flame resistance, evidenced by the increased peak heat release rate (p-HRR) of 56.9 kW·m−2 for SD8+graphene (sample coating contains graphite with a particle size of 8 μm and 0.5 wt.% graphene as dopant), which increased by 80.6% compared with SD8 (coating contains graphite with a particle size of 8 μm); substitution with graphene or mGO imparts an acceleration of fire growth, because graphene inertness improves the viscosity of melting system, evidenced by the cracked appearance and porous structure of SD8+graphene. However, the higher reactivity of mGO favors the combustion; the barrier effect inhibits the transfer of mass and heat simultaneously, leading to a slight influence on flame retarding efficiency.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Flame retardant materials and properties · Graphene research and applications · Toxic Organic Pollutants Impact

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Safety Engineering, College of Resource Engineering, Xi’an University of Architecture & Technology, Xi’an 710055, China

Funding

China Scholarship Council

References (44)

Show source-provided references
1. Bio-based flame retardants: When nature meets fire protection10.1016/j.mser.2017.04.001 ↗
2. Novel organo-modifier for thermally-stable polymer-layered silicate nanocomposites10.1016/j.polymdegradstab.2015.09.005 ↗
3. Fire-protective and flame-retardant coatings—A state-of-the-art review10.1177/0734904110395469 ↗
4. Recent developments in the chemistry of halogen-free flame retardant polymers10.1016/S0079-6700(02)00018-7 ↗
5. Influence of dielectric nanoparticles addition on electroconductivity and other properties of carbon nanotubes-based acrylic coatings10.1016/j.porgcoat.2015.12.006 ↗
6. Biobased polyelectrolyte multilayer-coated hollow mesoporous silica as a green flame retardant for epoxy resin10.1016/j.jhazmat.2017.09.001 ↗
7. Thermal and pyrolysis analysis of minerals reinforced intumescent fire retardant coating10.1016/j.porgcoat.2016.10.014 ↗
8. Tensile and combustion properties of PP/IFR/POE/nano-CaCO3, composites10.1007/s10924-016-0770-y ↗
9. Recent developments in flame retardant polymeric coatings10.1016/j.porgcoat.2013.07.014 ↗
10. The synthesis of a novel graphene-based inorganic–organic hybrid flame retardant and its application in epoxy resin10.1016/j.compositesb.2013.12.033 ↗
11. Synergistically building flame retarding thermosetting composites with high toughness and thermal stability through unique phosphorus and silicone hybridized graphene oxide10.1016/j.compositesa.2017.03.025 ↗
12. Mechanical properties of graphene and graphene-based nanocomposites10.1016/j.pmatsci.2017.07.004 ↗
13. Carbon-family materials for flame retardant polymeric materials10.1016/j.progpolymsci.2017.02.001 ↗
14. Combination effect of carbon nanotubes with graphene on intumescent flame-retardant polypropylene nanocomposites10.1016/j.compositesa.2013.12.010 ↗
15. Graphene/layered double hydroxides nanocomposites: A review of recent progress in synthesis and applications10.1016/j.carbon.2016.03.057 ↗
16. Graphene/layered double hydroxide nanocomposite: Properties, synthesis, and applications10.1016/j.cej.2016.01.114 ↗
17. Interfacial structure and tribological behaviours of epoxy resin coating reinforced with graphene and graphene oxide10.1002/sia.6062 ↗
18. Transparent epoxy coatings with improved electrical, barrier and thermal features made of mechanically dispersed carbon nanotubes10.1016/j.porgcoat.2017.05.017 ↗
19. Combination effects of graphene and layered double hydroxides on intumescent flame-retardant poly(methyl methacrylate) nanocomposites10.1016/j.clay.2013.11.002 ↗
20. Superhydrophobic mgo/pdms hybrid coating on polyester fabric for oil/water separation10.1016/j.porgcoat.2017.12.001 ↗
21. Development of a porous 3D graphene-PDMS scaffold for improved osseointegration10.1016/j.colsurfb.2017.07.087 ↗
22. Evaluation of scratch resistance of functionalized graphene oxide/polysiloxane nanocomposite coatings10.1016/j.porgcoat.2018.01.002 ↗
23. A novel intumescent flame retardant-functionalized graphene: Nanocomposite synthesis, characterization, and flammability properties10.1016/j.matchemphys.2012.05.082 ↗
24. A novel strategy to simultaneously electrochemically prepare and functionalize graphene with a multifunctional flame retardant10.1016/j.cej.2017.01.017 ↗
25. Monolayer polymerization of polyhedral oligomeric silsesquioxane on graphene oxide for highly efficient adsorption of β-lactoglobulin10.1016/j.carbon.2017.06.051 ↗
26. Structural characterization of polyurethane ureas and waterborne polyurethane urea dispersions made with mixtures of polyester polyol and polycarbonate diol10.1016/j.porgcoat.2017.07.009 ↗
27. Benign design and the evaluation of pyrolysis kinetics of polyester resin based intumescent system comprising of alkali-activated silica fume10.1016/j.porgcoat.2018.05.009 ↗
28. Influence of multiwall carbon nanotube (MWCNT) dispersion on ignition of poly(dimethylsiloxane)–MWCNT composites10.1002/pat.3454 ↗
29. Starch-graft copolymers of N-vinylformamide and acrylamide modified with montmorillonite manufactured by reactive extrusion10.1002/app.37630 ↗
30. Influence of heat-stable filler on the thermal shielding performance of water-based intumescent fire-resistive coating for structural steel applications10.1007/s11998-016-9850-0 ↗
31. Recent advances and future trends in new materials for sample preparation10.1016/j.trac.2015.04.011 ↗
32. Graphitic carbon nitride/phosphorus-rich aluminum phosphinates hybrids as smoke suppressants and flame retardants for polystyrene10.1016/j.jhazmat.2017.03.006 ↗
33. The effects of graphene on the flammability and fire behavior of intumescent flame retardant polypropylene composites at different flame scenarios10.1016/j.polymdegradstab.2017.06.015 ↗
34. Graphene-based flame retardants: A review10.1007/s10853-016-0124-0 ↗
35. Synergistic effect of intumescent flame retardant and expandable graphite on mechanical and flame-retardant properties of wood flour-polypropylene composites10.1016/j.conbuildmat.2013.09.028 ↗
36. Scalable chemical-vapour-deposition growth of three-dimensional graphene materials towards energy-related applications10.1039/C7CS00852J ↗
37. Recent progress on graphene-based photocatalysts: Current status and future perspectives10.1039/c2nr31480k ↗
38. Graphene synthesis10.1016/j.diamond.2014.04.006 ↗
39. An overview of the engineered graphene nanostructures and nanocomposites10.1039/c3ra44621b ↗
40. Graphene-based polymer nanocomposites10.1016/j.polymer.2010.11.042 ↗
41. Graphene platforms for smart energy generation and storage10.1016/j.joule.2017.11.011 ↗
42. Graphene-polymer nanocomposites for structural and functional applications10.1016/j.progpolymsci.2014.03.001 ↗
43. Dual modification of graphene by polymeric flame retardant and Ni(OH)2, nanosheets for improving flame retardancy of polypropylene10.1016/j.compositesa.2017.04.012 ↗
44. Is MWCNT a good synergistic candidate in APP–PER–MEL intumescent coating for steel structure?10.1016/j.porgcoat.2015.10.023 ↗