journal article·2022-04-22Open access

Influence of Texture and Thickness of Pyrocarbon Coatings as Interphase on the Mechanical Behavior of Specific 2.5D SiC/SiC Composites Reinforced with Hi-Nicalon S Fibers

Emilien Buet, James Braun, Cédric Sauder

Coatings· Volume 12· Issue 5

Abstract

In the framework of SiC/SiC composite development for nuclear applications, the influence of pyrocarbon interphase texture and thickness on the mechanical behavior both on as-processed materials and on irradiated materials is a major concern. Thus, the PyC interphase influence has to be clearly addressed to define its optimal chemical vapor infiltration processing parameters. For this purpose, specific 2.5D SiC/SiC composites reinforced with Hi-Nicalon S fibers and with two kinds of PyC texture and thickness were produced. Transmission electronic microscopy allowed PyC thickness and microstructure/texture characterizations, whereas push-out and tensile tests were employed as experimental mechanical procedures. The original result is that PyC nature directly influences the interfacial shear stress and failure mode of the weakest interface, regardless of the PyC thickness within the studied range. Adhesive failure or cohesive failure are highlighted depending on the PyC CVI deposition mechanisms. Similar post-irradiation characterizations will be required to assess the role of irradiation on the PyC microstructure/texture evolution and mechanical behavior of these materials.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Boron and Carbon Nanomaterials Research · Nuclear Materials and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Université Paris-Saclay, CEA, Service de Recherches Métallurgiques Appliquées, 91191 Gif-Sur-Yvette, France

References (48)

Show source-provided references
1. Spriet, P. (2014). CMC Applications to Gas Turbines. Ceramic Matrix Composites, John Wiley & Sons, Ltd.10.1002/9781118832998.ch21 ↗
2. DiCarlo, J.A. (2014). Advances in SiC/SiC Composites for Aero-Propulsion. Ceramic Matrix Composites, John Wiley & Sons, Ltd.10.1002/9781118832998.ch7 ↗
3. Lewis, D.A., Hogan, M.T., McMahon, J., and Kinney, S. (2008). Application of Uncooled Ceramic Matrix Composite for Turbine Blades for Performance Improvement of Advanced Turboshaft Engines, Annual Forum Proceedings-American Helicopter Society.
4. Radiation Effects in SiC for Nuclear Structural Applications10.1016/j.cossms.2012.03.005 ↗
5. Katoh, Y. (2014). Radiation Effects. Ceramic Matrix Composites, John Wiley & Sons, Ltd.10.1002/9781118832998.ch13 ↗
6. Sauder, C. (2014). Nuclear Applications. Ceramic Matrix Composites, John Wiley & Sons, Ltd.10.1002/9781118832998.ch22 ↗
7. Accident Tolerant Fuel Cladding Development: Promise, Status, and Challenges10.1016/j.jnucmat.2017.12.043 ↗
8. Continuous SiC Fiber, CVI SiC Matrix Composites for Nuclear Applications: Properties and Irradiation Effects10.1016/j.jnucmat.2013.06.040 ↗
9. Design and Strategy for Next-Generation Silicon Carbide Composites for Nuclear Energy10.1016/j.jnucmat.2020.152375 ↗
10. Silicon Carbide and Its Composites for Nuclear Applications—Historical Overview10.1016/j.jnucmat.2019.151849 ↗
11. Mechanical Property Degradation of High Crystalline SiC Fiber–Reinforced SiC Matrix Composite Neutron Irradiated to ~100 Displacements per Atom10.1016/j.jeurceramsoc.2017.12.026 ↗
12. Two Approaches for Interface Design of Continuous Fiber Ceramic Matrix Composites
13. Microcomposite Test Procedure for Evaluating the Interface Properties of Ceramic Matrix Composites10.1111/j.1151-2916.1995.tb08814.x ↗
14. Fibre-Matrix Interphases and Interfaces in Ceramic Matrix Composites Processed by CVI10.1163/156855493X00112 ↗
15. Quantitative Structural and Textural Assessment of Laminar Pyrocarbons through Raman Spectroscopy, Electron Diffraction and Few Other Techniques10.1016/j.carbon.2005.12.029 ↗
16. Microstructure of the Pyrocarbon Matrix in Carbon/Carbon Composites10.1016/S0266-3538(00)00125-1 ↗
17. Impact of Ex-PAN Carbon Fibers Thermal Treatment on the Mechanical Behavior of C/SiC Composites and on the Fiber/Matrix Coupling10.1016/j.cartre.2021.100107 ↗
18. Effect of Pyrolytic Carbon Interphase on Mechanical Properties of Mini T800-C/SiC Composites10.1007/s40145-020-0432-3 ↗
19. Effect of Pyrocarbon Interphase Texture and Thickness on Tensile Damage and Fracture in T-700TM Carbon Fiber–Reinforced Silicon Carbide Minicomposites10.1111/jace.18193 ↗
20. Hi-Nicalon Fiber-Reinforced CVI-SiC Matrix Composites: I Effects of PyC and PyC-SiC Multilayers on the Fracture Behaviors and Flexural Properties10.2320/matertrans.43.2568 ↗
21. Influence of Interface Characteristics on the Mechanical Properties of Hi-Nicalon Type-S or Tyranno-SA3 Fiber-Reinforced SiC/SiC Minicomposites: Influence of Interface Characteristics on the Mechanical Properties10.1111/j.1744-7402.2010.02485.x ↗
22. Micro-Mechanical Evaluation of SiC-SiC Composite Interphase Properties and Debond Mechanisms10.1016/j.compositesb.2017.07.035 ↗
23. Fiber/Matrix Debonding Evaluation of SiCf/SiC Composites Using Micropillar Compression Technique10.1016/j.compositesb.2021.109189 ↗
24. Appropriate Thickness of Pyrolytic Carbon Coating on SiC Fiber Reinforcement to Secure Reasonable Quasi-Ductility on NITE SiC/SiC Composites10.1016/j.ceramint.2018.07.158 ↗
25. Mechanical Behavior of SiC/SiC Composites Reinforced with New Tyranno SA4 Fibers: Effect of Interphase Thickness and Comparison with Tyranno SA3 and Hi-Nicalon S Reinforced Composites10.1016/j.jnucmat.2021.153367 ↗
26. Influence of Surface Fibre Properties and Textural Organization of a Pyrocarbon Interphase on the Interfacial Shear Stress of SiC/SiC Minicomposites Reinforced with Hi-Nicalon S and Tyranno SA3 Fibres10.1016/j.jeurceramsoc.2013.08.027 ↗
27. Swelling of Nuclear Graphite and High Quality Carbon Fiber Composite under Very High Irradiation Temperature10.1016/j.jnucmat.2008.07.033 ↗
28. Characterization of Nearly Stoichiometric SiC Ceramic Fibres10.1023/A:1017988827616 ↗
29. Tensile Creep Behavior of SiC-Based Fibers with a Low Oxygen Content10.1111/j.1551-2916.2007.01535.x ↗
30. Influence of Chemical and Physical Properties of the Last Generation of Silicon Carbide Fibres on the Mechanical Behaviour of SiC/SiC Composite10.1016/j.jeurceramsoc.2011.09.023 ↗
31. Bhatt, R.T., Cosgriff, L.M., and Fox, D.S. (2010). Influence of Fiber Architecture on Impact Resistance of Uncoated SiC/SiC Composites. Design, Development, and Applications of Engineering Ceramics and Composites, John Wiley & Sons, Ltd.10.1002/9780470909836.ch9 ↗
32. The Effects of Neutron Irradiation on Shear Properties of Monolayered PyC and Multilayered PyC/SiC Interfaces of SiC/SiC Composites10.1016/j.jnucmat.2007.03.096 ↗
33. Effect of Neutron Irradiation on Tensile Properties of Unidirectional Silicon Carbide Composites10.1016/j.jnucmat.2007.03.083 ↗
34. High-Dose, Intermediate-Temperature Neutron Irradiation Effects on Silicon Carbide Composites with Varied Fiber/Matrix Interfaces10.1016/j.jeurceramsoc.2019.03.014 ↗
35. Young’s Modulus, Thermal Expansion Coefficient and Fracture Behavior of Selected Si–B–C Based Carbides in the 20–1200 °C Temperature Range as Derived from the Behavior of Carbon Fiber Reinforced Microcomposites10.1016/j.jeurceramsoc.2006.12.006 ↗
36. Influence of an Original Manufacturing Process on the Properties and Microstructure of SiC/SiC Tubular Composites10.1016/j.compositesa.2019.04.031 ↗
37. Direct Observation of the Elasticity-Texture Relationship in Pyrolytic Carbon via in Situ Micropillar Compression and Digital Image Correlation10.1016/j.carbon.2021.06.045 ↗
38. ISO 20323:2018 (2022, March 14). Fine Ceramics (Advanced Ceramics, Advanced Technical Ceramics)—Mechanical Properties of Ceramic Composites at Ambient Temperature in Air Atmospheric Pressure—Determination of Tensile Properties of Tubes: International Organization for Standardization. Available online: https://www.iso.org/standard/67672.html.
39. Development of Damage in a 2D Woven C/SiC Composite under Mechanical Loading: I. Mechanical Characterization10.1016/S0266-3538(96)00094-2 ↗
40. Inelastic Behaviour of Ceramic-Matrix Composites10.1016/S0266-3538(01)00122-1 ↗
41. Relationships between Hysteresis Measurements and the Constituent Properties of Ceramic Matrix Composites: II, Experimental Studies on Unidirectional Materials10.1111/j.1151-2916.1995.tb08047.x ↗
42. Optimizing the Fabrication Process for Superior Mechanical Properties in the FCVI SiC Matrix/Stoichiometric SiC Fiber Composite System10.1016/S0022-3115(02)01060-7 ↗
43. Mechanical Properties of Several Advanced Tyranno-SA Fiber-Reinforced CVI-SiC Matrix Composites10.1016/S0921-5093(02)00468-9 ↗
44. The Physics and Mechanics of Fibre-Reinforced Brittle Matrix Composites10.1007/BF00355946 ↗
45. Damage and Failure in Ceramic Matrix Minicomposites: Experimental Study and Model10.1016/S1359-6454(96)00224-8 ↗
46. Influence of the Carbon Interface on the Mechanical Behavior of SiC/SiC Composites10.1016/j.compositesa.2020.105867 ↗
47. Pyrocarbon Deposits on a Graphite Surface Observed by STM10.1002/1521-3862(200105)7:3<125::AID-CVDE125>3.0.CO;2-B ↗
48. The Effect of Neutron Irradiation on the Fiber/Matrix Interphase of Silicon Carbide Composites10.1016/j.jnucmat.2008.11.015 ↗