Mechanism of Polyurethane Binder Curing Reaction and Evaluation of Polyurethane Mixture Properties

This study focuses on analyzing the curing reaction mechanism of polyurethane (PU) binders and comprehensively evaluating the PU mixture’s properties. The former was investigated by conducting a Fourier transform infrared spectroscopy (FTIR) test on PU binders with different curing times. The volume change characteristics, construction operation time, and strength formation law were clarified through the splitting tensile test of PU mixtures under different environmental conditions. The optimal PU mixture stacking time and curing time under different environmental conditions were determined. The properties of the PU mixture and asphalt mixture were evaluated and compared through a rutting test, low-temperature bending test, freeze–thaw splitting test, and four-point bending fatigue test. The results show that the physical and chemical curing of the PU binder occurred within the first 24 h of curing, and the reaction speed gradually accelerated to form a polyurea structure 24 h later. It is recommended to stack the PU mixture for 4 h before compaction and to cure it for 2 days before opening under the conditions of 50% humidity and 15–40 °C surrounding temperature. The PU mixture shows better temperature stability and fatigue resistance than the asphalt mixture, and the splitting tensile strength of the PU mixture before and after the freeze–thaw splitting test is also higher. It is clear that the PU mixture is a green road building material with good performance.