Three-Dimensional Carbon-Coated LiFePO4 Cathode with Improved Li-Ion Battery Performance

LiFePO4 (LFPO)has great potential as the cathode material for lithium-ion batteries; it has a high theoretical capacity (170 m·A·h·g−1), high safety, low toxicity and good economic benefits. However, low conductivity and a low diffusion rate inhibit its future development. To overcome these weaknesses, three-dimensional carbon-coated LiFePO4 that incorporates a high capacity, superior conductivity and low volume expansion enables faster electron transport channels. The use of Cetyltrimethyl Ammonium Bromid (CTAB) modification only requires a simple water bath and sintering, without the need to add a carbon source in the LFPO synthesis process. In this way, the electrode shows excellent reversible capacity, as high as 159.8 m·A·h·g−1 at 2 C, superior rate capability with 97.3 m·A·h·g−1 at 5 C and good cycling ability, preserving ~84.2% capacity after 500 cycles. By increasing the ion transport rate and enhancing the structural stability of LFPO nanoparticles, the LFPO-positive electrode achieves excellent initial capacity and cycle life through cost-effective and easy-to-implement carbon coating. This simple three-dimensional carbon-coated LiFePO4 provides a new and simple idea for obtaining comprehensive and high-performance electrode materials in the field of lithium cathode materials.