Improvement of Wear, Pitting Corrosion Resistance and Repassivation Ability of Mg-Based Alloys Using High Pressure Cold Sprayed (HPCS) Commercially Pure-Titanium Coatings
Source abstract
Abstract
In this study, a compact cold sprayed (CS) Ti coating was deposited on Mg alloy using a high pressure cold spray (HPCS) system. The wear and corrosion behavior of the CS Ti coating was compared with that of CS Al coating and bare Mg alloy. The Ti coating yielded lower wear rate compared to Al coating and Mg alloy. Electrochemical impedance spectroscopy (EIS) and cyclic potentiodynamic polarization (CPP) tests revealed that CS Ti coating can substantially reduce corrosion rate of AZ31B in chloride containing solutions compared to CS Al coating. Interestingly, Ti-coated Mg alloy demonstrated negative hysteresis loop, depicting repassivation of pits, in contrast to AZ31B and Al-coated AZ31B with positive hysteresis loops where corrosion potential (Ecorr) > repassivation potential (Erp); indicating irreversible growth of pits. AZ31B and Al-coated AZ31B were most susceptible to pitting corrosion, while Ti-coated Mg alloy indicated noticeable resistance to pitting in 3.5 wt % NaCl solution. In comparison to Al coating, Ti coating considerably separated the AZ31BMg alloy surface from the corrosive electrolyte during long term immersion test for 11 days.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Magnesium Alloys: Properties and Applications · High-Temperature Coating Behaviors · Corrosion Behavior and Inhibition
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical and Materials Engineering, University of Nevada, Reno, NV 89501, USA
Department of Mechanical Engineering, University of Nevada, Reno, NV 89501, USA
Department of Materials Science and Engineering, College of Engineering, North Carolina State University, 911 Partners Way, Raleigh, NC 27695, USA
ASB Industries Inc., Barberton, OH 44203, USA
References (66)
Show source-provided references
1. Preparation and characterization of colored Ti/Zr conversion coating on AZ91D magnesium alloy10.1016/j.surfcoat.2015.06.069 ↗
2. Microstructural characterization and corrosion resistance evaluation of nanostructured Al and Al/AlCr coated Mg–Zn–Ce–La alloy10.1016/j.jallcom.2014.06.077 ↗
3. Exploring environment friendly nickel electrodeposition on AZ91 magnesium alloy: Effect of prior surface treatments and temperature of the bath on corrosion behavior10.1016/j.corsci.2019.02.004 ↗
4. Fabrication and properties of triplex NiCrAlY/nano Al2O3· 13% TiO2/nano TiO2 coatings on a magnesium alloy by atmospheric plasma spraying method10.1016/j.jallcom.2015.05.106 ↗
5. Corrosion behaviour of thermally sprayed Al and Al/SiCp composite coatings on ZE41 magnesium alloy in chloride medium10.1016/j.corsci.2009.10.040 ↗
6. Corrosion resistance investigation of nanostructured Si-and Si/TiO2-coated Mg alloy in 3.5% NaCl solution10.1016/j.vacuum.2014.05.020 ↗
7. Fabrication and characterization of hydrophobic micro arc oxidation/poly-lactic acid duplex coating on biodegradable Mg–Ca alloy for corrosion protection10.1016/j.vacuum.2015.12.022 ↗
8. Fabrication and Corrosion Resistance Evaluation of Novel Epoxy/Oxide Layer (MgO) Coating on Mg Alloy10.1134/S2070205120050093 ↗
9. Improvement of corrosion resistance of binary Mg-Ca alloys using duplex alu-minum-chromium coatings10.1007/s11665-015-1543-9 ↗
10. Investigation of Corrosion Protection Performance of Multiphase PEO (Mg2SiO4, MgO, MgAl2O4) Coatings on Mg Alloy Formed in Aluminate-Silicate- based Mixture Electrolyte10.1134/S2070205118030231 ↗
11. Understanding Cold Spray for Enhanced Manufacturing Sustainability10.4028/www.scientific.net/MSF.941.1867 ↗
12. Supersonic particle deposition as an additive technology: Methods, challenges, and applications10.1007/s00170-019-04682-2 ↗
13. Kay, C.M., and Karthikeyan, J. (2016). High Pressure Cold Spray: Principles and Applications, ASM Thermal Spray Society.10.31399/asm.tb.hpcspa.9781627082853 ↗
14. Micro-structural evaluation and thermal oxidation behaviors of YSZ/NiCoCrAlYTa coatings deposited by different thermal techniques10.1016/j.ceramint.2020.06.001 ↗
15. Effects of Al2O3 diffusion barrier layer (including Y-containing small oxide precipitates) and nanostructured YSZ top coat on the oxidation behavior of HVOF NiCoCrAl-TaY/APS YSZ coatings at 1100 °C10.1016/j.corsci.2018.07.013 ↗
16. High velocity impact induced microstructure evolution during deposition of cold spray coatings10.1016/j.surfcoat.2014.06.006 ↗
17. Cold spraying: A materials perspective10.1016/j.actamat.2016.06.034 ↗
18. Microstructural characterisation of air plasma sprayed nanostructure ceramic coatings on Mg–1% Ca alloys (bonded by NiCoCrAlYTa)10.1016/j.ceramint.2015.08.118 ↗
19. Evaluation of Normal and Nanolayer Composite Thermal Barrier Coatings in Fused Vanadate-Sulfate Salts at 1000 °C10.1155/2013/790318 ↗
20. Introducing a composite coating containing CNTs with good corrosion properties: Characterization and simulation10.1039/C6RA24222G ↗
21. Surface protection of Mg alloys in automotive applications: A review
22. Microstructure and corrosion performance of a cold sprayed aluminium coating on AZ91D magnesium alloy10.1016/j.corsci.2010.05.023 ↗
23. Cold spray Al–5% Mg coatings for the corrosion protection of magnesium alloys10.1007/s11666-011-9675-4 ↗
24. The effect of pure aluminum cold spray coating on corrosion and corrosion fatigue of magnesium (3% Al–1% Zn) extrusion10.1016/j.surfcoat.2016.11.014 ↗
25. Saltwater corrosion behavior of cold sprayed AA7075 aluminum alloy coatings10.1016/j.corsci.2017.10.033 ↗
26. Corrosion resistant nickel coating with strong adhesion on AZ31B magnesium alloy prepared by an in-situ shot-peening-assisted cold spray10.1016/j.corsci.2018.04.018 ↗
27. Mechanical and corrosion properties in 3.5% NaCl solution of cold sprayed Al-based coatings10.1016/j.surfcoat.2020.125372 ↗
28. Corrosion of titanium. Part 1: Aggressive environments and main forms of degradation
29. Innovative fabrication of porous titanium coating on titanium by cold spraying and vacuum sintering10.1016/j.matlet.2008.04.011 ↗
30. Solid-state cold spraying of Ti and its alloys: A literature review10.1016/j.pmatsci.2019.100633 ↗
31. Microstructure and corrosion resistance of warm sprayed titanium coatings with polymer sealing for corrosion protection of AZ91E magnesium alloy10.1016/j.surfcoat.2019.02.023 ↗
32. A comparative study on the corrosion behavior of Al, Ti, Zr and Hf metallic coatings deposited on AZ91D magnesium10.1016/j.surfcoat.2016.03.079 ↗
33. (2014). ASTM E2109-01 Standard Test Methods for Determining Area Percentage Porosity in Thermal Sprayed Coatings, ASTM.
34. (2005). ASTM G133-05 Standard Test Method for Linearly Reciprocating Ball-on-Flat Sliding Wear, ASTM.
35. Menezes, P.L., Nosonovsky, M., Ingole, S.P., Kailas, S.V., and Lovell, M.R. (2013). Tribology for Scientists and Engineers, Springer.10.1007/978-1-4614-1945-7 ↗
36. Mechanical and tribological properties of cold sprayed Ti coatings on Ti-6Al-4V substrates10.1007/s11666-016-0396-6 ↗
37. Enhanced Electrochemical and Tribo-logical Properties of AZ91D Mg Alloy via Cold Spraying of Al Alloy10.1007/s11666-019-00915-8 ↗
38. (2014). ASTM Standard G61-86 Standard Test Method for Conducting Cyclic Potentiodynamic Polarization (CPP) Measurements for Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys, ASTM.
39. Influence of plasma and cold spray deposited titanium Layers on high-cycle fatigue properties of Ti6Al4V substrates10.1016/j.surfcoat.2012.11.067 ↗
40. Adhesion, tribological and corrosion properties of cold-sprayed CoCrMo and Ti6Al4V coatings on 6061-T651 Al alloy10.1016/j.surfcoat.2017.07.062 ↗
41. Effect of substrate surface condition on fatigue behavior of cold sprayed Ti6Al4V coatings10.1016/j.surfcoat.2016.11.093 ↗
42. Astarita, A., Rubino, F., Carlone, P., Ruggiero, A., Leone, C., Genna, S., Merola, M., and Squillace, A. (2016). On the Improvement of AA2024 Wear Properties through the Deposition of a Cold-Sprayed Titanium Coating. Metals, 6.10.3390/met6080185 ↗
43. Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation10.1016/j.corsci.2009.10.016 ↗
44. Electronic structure and pitting behavior of 3003 aluminum alloy passivated under various conditions10.1016/j.electacta.2009.02.058 ↗
45. Influence of annealing on mechanical and electrochemical properties of cold sprayed niobium coatings10.1016/j.surfcoat.2016.04.027 ↗
46. The influence of current density on the morphology and corrosion properties of MAO coatings on AZ31B magnesium alloy10.1016/j.surfcoat.2016.01.040 ↗
47. SVET, SKP and EIS study of the corrosion behavior of high strength Al and Al–Li alloys used in aircraft fabrication10.1016/j.corsci.2014.03.001 ↗
48. AC electrochemical impedance of a model pit
49. Enhancing anti-wear and anti-corrosion performance of cold spraying aluminum coating by high current pulsed electron beam irradiation10.1016/j.vacuum.2020.109772 ↗
50. Corrosion characteristics of cold gas spray coatings of reinforced aluminum deposited onto carbon steel10.1016/j.corsci.2016.10.019 ↗
51. Corrosion, wear and tribo-corrosion performance of a thermally sprayed aluminum coating modified by plasma electrolytic oxidation technique for offshore submerged components protection10.1016/j.corsci.2018.08.001 ↗
52. Enhanced corrosion resistance of cold-sprayed and shot-peened aluminum coatings on LA43M magnesium alloy10.1016/j.surfcoat.2020.125865 ↗
53. Electrochemical potential noise of 321 stainless steel stressed under constant strain rate testing conditions10.1016/j.electacta.2006.08.029 ↗
54. Effect of ultrasonic cold forging technology as the pretreatment on the corrosion resistance of MAO Ca/P coating on AZ31B Mg alloy10.1016/j.jallcom.2015.02.086 ↗
55. Water and corrosion resistance of epoxy–acrylic–amine waterborne coatings: Effects of resin molecular weight, polar group and hydrophobic segment10.1016/j.corsci.2013.05.020 ↗
56. Preparation and corrosion resistance of a nanocomposite plasma electrolytic oxidation coating on Mg–1%Ca alloy formed in aluminate electrolyte containing titania nano-additives10.1016/j.jallcom.2016.07.081 ↗
57. Deposition of duplex MAO layer/nanostructured titanium dioxide composite coatings on Mg–1% Ca alloy using a combined technique of air plasma spraying and micro arc oxidation10.1016/j.jallcom.2015.07.200 ↗
58. Improved corrosion performance of biodegradable magnesium in simulated inflammatory condition via drug-loaded plasma electrolytic oxidation coatings10.1016/j.matchemphys.2019.122003 ↗
59. Composite anticorrosion coatings for AZ91D magnesium alloy with molybdate conversion coating and silicon sol–gel coatings10.1016/j.porgcoat.2009.07.003 ↗
60. Sowa, M., and Simka, W. (2018). Electrochemical Impedance and Polarization Corrosion Studies of Tantalum Surface Modified by DC Plasma Electrolytic Oxidation. Materials, 11.10.3390/ma11040545 ↗
61. Fabrication and characterization of silk fibroin coating on APTES pretreated Mg-Zn-Ca alloy10.1016/j.msec.2020.110742 ↗
62. Corrosion and surface study of sputtered Al–W coatings with a range of tungsten contents10.1016/j.corsci.2013.01.002 ↗
63. Modification of surface hardness, wear re-sistance and corrosion resistance of cold spray Al coated AZ31B Mg alloy using cold spray double layered Ta/Ti coating in 3.5wt % NaCl solution10.1016/j.corsci.2020.109029 ↗
64. Fabrication corrosion resistance of a hydrophobic micro- arc oxidation coating on AZ31 Mg alloy10.1016/j.corsci.2014.10.041 ↗
65. Evaluating the performance of zinc and aluminum sacrificial anodes in artificial seawater10.1016/j.electacta.2019.05.067 ↗
66. Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ3110.1016/j.corsci.2017.01.025 ↗