Preparation of Gallic Acid Intercalated Layered Double Hydroxide for Enhanced Corrosion Protection of Epoxy Coatings
Source abstract
Abstract
In the field of corrosion protection coatings, layered double hydroxide (LDH) has gained wide attention as a novel controlled-release nanocontainer. In this paper, by using a co-precipitation to store corrosion inhibitors in layered double hydroxide with barrier properties, an environmentally friendly gallic acid (GA) intercalated layered double hydroxide corrosion protection filler (GA-LDH) was prepared. The epoxy coating was then modified with GA-LDH to improve its corrosion protection performance. The structure, composition, and release behavior of GA-LDH were investigated by a series of characterizations, such as field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and ultraviolet-visible spectrophotometry (UV-vis). Electrochemical impedance spectroscopy (EIS) and a neutral salt spray test (NSS) were performed to evaluate the effect of EP coating containing GA-LDH on corrosion protection for Q235 steel. The results show that GA-LDH added to an epoxy coating can achieve excellent corrosion protection performance and is expected to be widely used in marine corrosion protection contexts.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Layered Double Hydroxides Synthesis and Applications · Silicone and Siloxane Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Liaoning Provincial Key Laboratory for Synthesis and Preparation of Special Functional Materials, Shenyang University of Chemical Technology, Shenyang 110142, China
State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute (LSMRI), Xiamen 361101, China
Shenyang Research Institute of Industrial Technology for Advanced Coating Materials, Shenyang 110300, China
Liaoning Shunfeng New Material Technology Co., Ltd., Shenyang 110326, China
Funding
“Jie Bang Gua Shuai” of Science and Technology Projects of Liaoning Province · Sino-Spain Joint Laboratory on Material Science · Shenyang Science and Technology Program-Major Key Core Technology Project · Liao Ning Revitalization Talents Program · State Key Laboratory for Marine Corrosion and Protection Foundation
References (55)
Show source-provided references
1. Fabrication of composite coatings with core-shell nanofibers and their mechanical properties, anticorrosive performance, and mechanism in seawater10.1016/j.porgcoat.2020.105893 ↗
2. Functionalized multi-walled carbon nanotube/polyindole incorporated epoxy: An effective anti-corrosion coating material for mild steel10.1016/j.jallcom.2020.158057 ↗
3. New valve-free organosilica nanocontainer for active anticorrosion of polymer coatings10.1016/j.compositesb.2021.109185 ↗
4. Achieving high performance anticorrosive coating via in situ polymerization of polyurethane and poly(propylene oxide) grafted graphene oxide composites10.1016/j.corsci.2020.109055 ↗
5. Anticorrosion performance of electro-deposited epoxy/ amine functionalized graphene oxide nanocomposite coatings10.1016/j.corsci.2020.109143 ↗
6. Corrosion-protective performance of magnetic CoFe2O4/polyaniline nanocomposite within epoxy coatings10.1016/j.jtice.2021.08.008 ↗
7. Fabrication of BTA-MOF-TEOS-GO nanocomposite to endow coating systems with active inhibition and durable anticorrosion performances10.1016/j.porgcoat.2020.105629 ↗
8. Highly orientated graphene/epoxy coating with exceptional anti-corrosion performance for harsh oxygen environments10.1016/j.corsci.2020.109049 ↗
9. Rising of MXenes: Novel 2D-functionalized nanomaterials as a new milestone in corrosion science-a critical review10.1016/j.cis.2022.102730 ↗
10. Metal-organic frameworks template-directed growth of layered double hydroxides: A fantastic conversion of functional materials10.1016/j.ccr.2022.214467 ↗
11. Wang, J., Qi, Y., Zhao, X., and Zhang, Z. (2020). Electrochemical investigation of corrosion behavior of epoxy modified silicate zinc-rich coatings in 3.5% NaCl solution. Coatings, 10.10.3390/coatings10050444 ↗
12. The corrosion inhibitor behavior of iron in saline solution by the action of magnesium carboxyphosphonate10.1515/pac-2018-0513 ↗
13. Polymer/Inorganic nanocomposite coatings with superior corrosion protection performance: A review10.1016/j.jiec.2020.04.029 ↗
14. Active anti-corrosion of epoxy coating by nitrite ions intercalated MgAl LDH10.1016/j.jhazmat.2020.122215 ↗
15. Reviewing the current status of layered double hydroxide-based smart nanocontainers for corrosion inhibiting applications10.1016/j.jmrt.2020.12.025 ↗
16. Controlled release of nitrate and molybdate intercalated in Zn-Al-layered double hydroxide nanocontainers towards marine anticorrosion applications10.1016/j.colcom.2018.03.003 ↗
17. Anticorrosive waterborne epoxy (EP) coatings based on sodium tripolyphosphate-pillared layered double hydroxides (STPP-LDHs)10.1016/j.porgcoat.2019.04.055 ↗
18. Delamination and self-assembly of layered double hydroxides for enhanced loading capacity and corrosion protection performance10.1016/j.apsusc.2018.08.109 ↗
19. Active corrosion protection of Mg-Al-PO43− LDH nanoparticle in silane primer coated with epoxy on mild steel10.1016/j.jtice.2017.03.010 ↗
20. Quantitative determination of major polyphenol constituents in pomegranate products10.1016/j.foodchem.2011.11.106 ↗
21. Antioxidant activity of different white teas: Comparison of hot and cold tea infusions10.1016/j.jfca.2013.09.010 ↗
22. Polyphenolic compounds appear to limit the nutritional benefit of biofortified higher iron black bean (Phaseolus vulgaris L.)10.1186/1475-2891-13-28 ↗
23. Water-based rust converter and its polymer composites for surface anticorrosion10.1016/j.colsurfa.2017.10.041 ↗
24. Water-based & eco-friendly & high-efficiency 3,4,5-Trihydroxybenzoic acid ester as a novel rust conversion agent and its polymer composites for enhanced surface anticorrosion10.1016/j.colsurfa.2021.127065 ↗
25. Ocean acidification effect on the iron-gallic acid redox interaction in seawater. Front
26. Incorporation of layered double hydroxides modified with benzotriazole into an epoxy resin for the corrosion protection of Zn-Mg coated steel10.1016/j.porgcoat.2020.105894 ↗
27. Layered double hydroxide (LDH) for multi-functionalized corrosion protection of metals: A review10.1016/j.jmst.2021.05.078 ↗
28. Studies on the formation of 5-aminosalicylate intercalated Zn–Al layered double hydroxides as a function of Zn/Al molar ratios and synthesis routes10.1016/j.ces.2006.12.041 ↗
29. Facile fabrication of epoxy/polybenzoxazine based superhydrophobic coating with enhanced corrosion resistance and high thermal stability10.1016/j.colsurfa.2018.10.066 ↗
30. Fabrication of azobenzene non-covalent bonding grafting graphene composite and its application in weathering and corrosion resistant polyurethane coating10.1016/j.polymdegradstab.2022.110157 ↗
31. The effect of interlayer spacing on the inhibitor release capability of layered double hydroxide based nanocontainers10.1016/j.jclepro.2019.119676 ↗
32. Zn/Al Layered double hydroxides nanostructure as effective controlled release vehicle of nicotinic acid for topical applications10.1016/j.clay.2021.106304 ↗
33. Deintercalation of carbonate ions from carbonate-type layered double hydroxides (LDHs) using acid–alcohol mixed solutions10.1016/j.clay.2011.07.017 ↗
34. Ferreira MGS. Comparative X-ray diffraction and infrared spectroscopy study of Zn–Al layered double hydroxides: Vanadate vs nitrate10.1016/j.chemphys.2012.01.026 ↗
35. Intercalation of LDH NO3 with short-chain intercalants10.1007/s12034-018-1704-1 ↗
36. A composite corrosion inhibitor of MgAl Layered double hydroxides co-intercalated with hydroxide and organic anions for carbon steel in simulated carbonated concrete pore solutions10.1149/2.0141911jes ↗
37. Designing novel organic inhibitor loaded MgAl-LDHs nanocontainer for enhanced corrosion resistance10.1016/j.cej.2020.127367 ↗
38. Synthesis, characterization, and controlled release anticorrosion behavior of benzoate intercalated Zn–Al layered double hydroxides10.1016/j.materresbull.2011.07.021 ↗
39. Hybrid materials based on a layered zinc hydroxide solid and gallic acid: Structural characterization and evaluation of the controlled release behavior as a function of the gallic acid content10.1016/j.clay.2019.105228 ↗
40. Antioxidant drugs intercalated into layered double hydroxide: Structure and in vitro release10.1016/j.clay.2010.06.017 ↗
41. Synthesis of dual functional gallic-acid-based carbon dots for bioimaging and antitumor therapy10.1039/C9BM00570F ↗
42. Nature of the use of adventitious carbon as a binding energy standard10.1116/1.579868 ↗
43. Facile fabrication of ZnAl layered double hydroxide film co-intercalated with vanadates and laurates by one-step post modification10.1016/j.colcom.2020.100351 ↗
44. Mechanism of in situ surface polymerization of gallic acid in an environmental-inspired preparation of carboxylated core-shell magnetite nanoparticles10.1021/la5038102 ↗
45. Thermogravimetric analysis of selected layered double hydroxides10.1007/s10973-012-2584-z ↗
46. Organo/Zn-Al LDH nanocomposites for cationic dye removal from aqueous media10.1186/s11671-016-1402-0 ↗
47. Epoxy/layered double hydroxide (LDH) nanocomposites: Synthesis, characterization, and Excellent cure feature of nitrate anion intercalated Zn-Al LDH10.1016/j.porgcoat.2019.105218 ↗
48. Tailoring of a potential nanoformulated form of gibberellic acid: Synthesis, characterization, and field applications on vegetation and flowering10.1021/acs.jafc.8b02761 ↗
49. Gallate–Zn–Al-layered double hydroxide as an intercalated compound with new controlled release formulation of anticarcinogenic agent10.1016/j.jpcs.2010.08.003 ↗
50. Tuning F-doped degree of rGO: Restraining corrosion-promotion activity of EP/rGO nanocomposite coating10.1016/j.jmst.2019.09.043 ↗
51. Wang, N., Diao, X., Zhang, J., and Kang, P. (2018). Corrosion Resistance of waterborne epoxy coatings by incorporation of dopamine treated mesoporous-TiO2 particles. Coatings, 8.10.3390/coatings8060209 ↗
52. Organic/inorganic hybrid waterborne polyurethane coatings with self-healing properties for anticorrosion application10.1016/j.porgcoat.2022.107244 ↗
53. Experimental and theoretical studies of four allyl imidazolium-based ionic liquids as green inhibitors for copper corrosion in sulfuric acid10.1016/j.corsci.2017.02.021 ↗
54. Wang, X., Zhu, Q., Liu, X., and Hou, B. (2021). Rust conversion performance of phosphoric acid–gallic acid in vinyl chloride acrylic emulsion. Coatings, 11.10.3390/coatings11020152 ↗
55. Preparation and properties of natural gallic acid based rust conversion emulsion10.1108/PRT-12-2014-0115 ↗