journal article·2020-09-10Open access

On-Aluminum and Barrier Anodic Oxide: Meeting the Challenges of Chemical Dissolution Rate in Various Acids and Solutions

Alexander Poznyak, Andrei Pligovka, Ulyana Turavets, Małgorzata Norek

Coatings· Volume 10· Issue 9

Abstract

The chemical dissolution—in 0.1 M solutions of phosphoric, malonic, citric, sulfosalicylic, and tartaric acids and 0.6 M solutions of sulfuric, oxalic, malonic, phosphoric, tartaric, and citric acids—of aluminum (Al) and its barrier anodic oxide, with thicknesses of 240 and 350 nm, produced during the anodization of Al deposited on a sitall substrate and Al foil, respectively, in a 1% citric acid aqueous solution, was investigated. Signs of chemical dissolution for 0.1 M phosphoric acid solution and 0.6 M concentrations of all the listed solutions were found. It was shown that the dissolution rate and the nature of its change depend on the acid nature, the state of the sample surface, and the classification of the electrolytes according to their degrees of aggressiveness with respect to aluminum.
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Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Concrete Corrosion and Durability · Smart Materials for Construction

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Electronic Technology and Engineering, Belarusian State University of Informatics and Radioelectronics, 6 Brovki Str., 220013 Minsk, Belarus

Research and Development Laboratory 4.10 “Nanotechnologies”, Belarusian State University of Informatics and Radioelectronics, 6 Brovki Str., 220013 Minsk, Belarus

Institute of Materials Science and Engineering, Faculty of Advanced Technologies and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland

Funding

Belarusian Republican Foundation for Fundamental Research · The state research program of the Republic of Belarus, grant ”Convergence 2020”

References (42)

Show source-provided references
1. Diggle, J. (1973). Oxides and Oxide Films, Marcel Dekker.10.1149/1.2402368 ↗
2. Blesa, M.A., Morando, P.J., and Regazzoni, A.E. (1994). Chemical Dissolution of Metal Oxides, CRC Press.
3. Lemieux, E., Hartt, W.H., and Lucas, K.E. (2001). A Critical Review of Aluminum Anode Activation, Dissolution Mechanisms and Performance. 2001 NACE Conference Papers, Proceedings of the CORROSION 2001, Houston, TX, USA, 11–16 March 2001, NACE International.
4. Chemical dissolution resistance of anodic oxide layers formed on aluminum10.1016/S1003-6326(11)60913-8 ↗
5. The Chemistry of Failure of Aluminum Electrolytic Capacitors10.1109/TPMP.1965.1135396 ↗
6. Buehler, M., Miller, A., and Andryushchenko, T. (2007). Reducing Aluminum Dissolution in High pH Solutions. (2007/0152252 A1), U.S. Patent.
7. Andryushchenko, T., and Miller, A. (2009). Chemical Dissolution of Barrier and Adhesion Layers. (7,560,380 B2), U.S. Patent.
8. The effects of applied potential and pH on the electrochemical dissolution of barrier layer in porous anodic oxide film on pure aluminium10.1016/0010-938X(96)00131-X ↗
9. In situ electrochemical dissolution of the oxide barrier layer of porous anodic alumina fabricated by hard anodization10.1016/j.jelechem.2009.04.008 ↗
10. Kinetics and Modeling of Wet Etching of Aluminum Oxide by Warm Phosphoric Acid10.1149/1.1836489 ↗
11. Dynamics and temperature dependence of etching processes of porous and barrier aluminum oxide layers10.1016/j.electacta.2004.02.003 ↗
12. In Situ Determination of the Pore Opening Point during Wet-Chemical Etching of the Barrier Layer of Porous Anodic Aluminum Oxide: Nonuniform Impurity Distributionin Anodic Oxide10.1021/am400520d ↗
13. Pligovka, A.N., Luferov, A.N., Nosik, R.F., and Mozalev, A.M. (2010). Dielectric characteristics of thin film capacitors based on anodized Al/Ta layers. Proc. Int. Crimean Conf. Microw. Telecommun. Technol. (CriMiCo), 880–881.10.1109/CRMICO.2010.5632734 ↗
14. Columnar Niobium Oxide Nanostructures: Mechanism of Formation, Microstructure, and Electrophysical Properties10.1134/S1063784219110124 ↗
15. Anodic Niobia Column-like 3-D Nanostructures for Semiconductor Devices10.1109/TNANO.2019.2930901 ↗
16. Growth and dissolution of anodic aluminum oxide in oxalic acid solutions
17. Dissolution of aluminum in its anodizing in malonic acid solution
18. The role of electric field in pore formation during aluminum anodization10.1016/j.electacta.2011.02.002 ↗
19. Young, L. (1961). Anodic Oxide Films, Academic Press.
20. Henley, V.F. (1982). Anodic Oxidation of Aluminium and Its Alloys. Pergamon.
21. Study of the initial stage of aluminium anodization in malonic acid solution10.1016/0013-4686(87)90043-0 ↗
22. Anodic oxide cellular structure formation on aluminum films in tartaric acid electrolyte10.1016/0167-577X(93)90069-A ↗
23. Atomic-Emission Plasma Spectrometry Applied to the Initial Stages of Aluminum Anodization in Malonic Acid
24. Aluminum-Dissolution Kinetics during Electrochemical Anodizing in a Tartaric Acid Electrolyte
25. Dissolution of Aluminum during the Initial Stages of Anodization in Phosphoric Acid Electrolyte
26. Dissolution of aluminum in the first stage of anodic oxidation in solution of boric acid
27. Dissolution of the Anodic Oxide at the Initial Stage of Aluminum Anodizing in Aqueous Solutions of Organic Acids
28. Dissolution of anodic aluminum oxide in the initial stage of anodic oxidation in aqueous solutions of tartaric and sulfosalicylic acids
29. Analysis of chemical dissolution of the barrier layer of porous oxide on aluminum thin films using a re-anodizing technique10.1016/j.apsusc.2005.02.024 ↗
30. Dissolution behavior of anodic oxide films formed in sulfanic acid on aluminum10.1007/s00604-006-0609-7 ↗
31. The dissolution of porous oxide films on aluminium10.1016/0013-4686(70)85002-2 ↗
32. In situ spectroscopic ellipsometric study of porous alumina film dissolution10.1016/S0013-4686(02)00015-4 ↗
33. Enhanced Performance of Nanostructured Coatings for Drilling by Droplet Elimination10.1080/10426914.2014.973582 ↗
34. Oxidation of Aluminum and Its Alloys. Aluminum Alloys10.1016/B978-0-12-341831-9.50024-3 ↗
35. Study on Anodic Oxidation and Sealing of Aluminum Alloy10.20964/2018.02.78 ↗
36. Dell’oca, C.J., Pulfrey, D.L., and Young, L. (1971). Anodic Oxide Films. Phys. Thin Film., 1–71.10.1016/B978-0-12-533006-0.50008-6 ↗
37. Scheer, R., and Schock, H.-W. (2011). Thin Film Technology. Chalcogenide Photovolt., 235–275.10.1002/9783527633708.ch5 ↗
38. Photoluminescent properties of barrier anodic oxide films on aluminum10.1016/j.tsf.2011.01.188 ↗
39. Lurie, J. (1975). Handbook of Analytical Chemistry, Mir Publishers.
40. Ugay, Y. (2000). General and Inorganic Chemistry, Higher School. (In Russian).
41. Anodic oxide films on aluminum10.1021/cr60259a005 ↗
42. The Reaction of Aluminum Electrodes with a Glycol Borate Electrolyte10.1149/1.2423354 ↗