journal article·2020-04-01Open access

Environmentally Friendly Water-Based Self-Crosslinking Acrylate Dispersion Containing Magnesium Nanoparticles and Their Films Exhibiting Antimicrobial Properties

Denisa Steinerová, Andréa Kalendová, Jana Machotová, Marcela Pejchalová

Coatings· Volume 10· Issue 4

Abstract

A water-based polymeric acrylate dispersion (latex) containing MgO nanoparticles, which had been added at a concentration of 1.5% (with respect to the monomers) during the preparation procedure, was investigated as an environmentally friendly binder for sanitary interior paints. The properties of this new latex were compared to those of a reference system free of the magnesium nanoparticles, synthesized by the same route, i.e., by semi-continuous emulsion polymerization. Tests were made in order to ascertain the mechanical and chemical properties, flash corrosion resistance and antimicrobial effect of the latex films. The results revealed that the new latex containing magnesium nanoparticles provided solvent-resistant coating films having pronounced antimicrobial activity against all the tested bacterial and fungal strains. The desirable antimicrobial properties can be ascribed to the sharp-edged character of magnesium nanoparticles, the peroxidation of lipids and the formation of reactive oxygen species. Moreover, no flash corrosion was formed beneath coating films containing magnesium nanoparticles, which can be attributed to the alkaline action due to the dissolution of a fraction of MgO in latex medium. The results of all of the tests provided evidence of the superiority of the polymeric dispersion with the magnesium nanoparticles to the reference system containing no nanoparticles.
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Research context

OpenAlex topics: Magnesium Oxide Properties and Applications · Building materials and conservation · Concrete and Cement Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Chemistry and Technology of Macromolecular Materials, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10 Pardubice, Czech Republic

Department of Biological and Biochemical Sciences, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10 Pardubice, Czech Republic

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