journal article·2021-06-30Open access

A General Strategy towards Superhydrophobic Self-Cleaning and Anti-Corrosion Metallic Surfaces: An Example with Aluminum Alloy

Shunli Zheng, Cheng Li, Yupeng Zhang, Tengfei Xiang, Ying Cao, Quanli Li, Zhong Chen

Coatings· Volume 11· Issue 7

Abstract

Corrosion and contamination of metallic structures can cause loss of their functionality as well as aesthetic values. In this study, we describe a general strategy to prepare superhydrophobic self-cleaning and anti-corrosion surfaces for metallic structures. As a specific example, a superhydrophobic coating (SHC) on aluminum alloy was prepared by a simple etching combined with the decoration of a low-surface-energy material. The optimal SHC has a water contact angle (CA) at ~157.4° and a sliding angle (SA) of ~8.3° due to the synergy of binary hierarchical structures and chemical modification. The SHC showed low adhesion to dry contaminants and a series of liquids, displaying a good self-cleaning effect. The SHC maintained superhydrophobicity after exposure to air and humid condition at 60 °C for 7 days. In addition, the electrochemical measurements reveal that the anti-corrosion performance was enhanced by reducing the corrosion current density (Jcorr) by 1 order of magnitude and increasing the corrosion potential (Ecorr) by 0.527 V as compared to the bare Al alloy substrate after immersion for 168 h.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Advanced Sensor and Energy Harvesting Materials · Aerosol Filtration and Electrostatic Precipitation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Lab. of Oral Diseases Research of Anhui Province, College & Hospital of Stomatology, Anhui Medical University, Hefei 230032, China

College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, 29 Jiangjun Avenue, Nanjing 210016, China

AVIC Taiyuan Aero Instruments Co. Ltd., 137 Bingzhou South Road, Taiyuan 030000, China

School of Architectural and Civil Engineering, Anhui University of Technology, 59 Hudong Road, Huashan District, Ma’anshan 243032, China

Institute of Materials Science and Engineering, Anhui University of Technology, 59 Hudong Road, Huashan District, Ma’anshan 243032, China

School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Funding

Natural Science Foundation of Anhui Province · Improvement Program of Basic and Clinical Cooperative Research of Anhui Medical University · Research Improvement Program in Stomatologic Hospital & College of Anhui Medical University · Grants for Scientific Research of BSKY from Anhui Medical University · the Agency for Science, Technology and Research (A*STAR) of Singapore

References (70)

Show source-provided references
1. Development of a superhydrophobic and bactericide organic topcoat to be applied on thermally sprayed aluminum coatings in offshore submerged components10.1016/j.porgcoat.2019.105376 ↗
2. (2018, April 24). The Annual Loss of Marine Corrosion in China is 700 Billion. (In Chinese).
3. Corrosion resistance mechanism of chromate conversion coated aluminium current collector in lithium-ion batteries10.1016/j.corsci.2019.108100 ↗
4. Performance comparison of steam-based and chromate conversion coatings on AA6060 aluminium alloy10.5006/1624 ↗
5. Storage and release of soluble hexavalent chromium from chromate conversion coatings equilibrium aspects of CrVI concentration10.1149/1.1393568 ↗
6. Fabrication of inherent anticorrosion superhydrophobic surfaces on metals10.1021/acssuschemeng.8b00639 ↗
7. Robust and chemically stable superhydrophobic aluminum-alloy surface with enhanced corrosion-resistance properties10.1007/s40684-019-00031-6 ↗
8. Development of Cu2+- and/or phosphonium-based polymeric biocidal materials and their potential application in antifouling paints10.1016/j.porgcoat.2012.04.019 ↗
9. Corrosion protection of aluminum alloy AA7020 in NaCl solution by hybrid sol–gel coatings10.1134/S2070205120020033 ↗
10. Epoxy-based smart coating with self-repairing polyurea-formaldehyde microcapsules for anticorrosion protection of aluminum alloy AA202410.1007/s11998-020-00334-3 ↗
11. Liu, S., Liu, L., Meng, F., Li, Y., and Wang, F. (2018). Protective performance of polyaniline-sulfosalicylic acid/epoxy coating for 5083 aluminum. Materials, 11.10.3390/ma11020292 ↗
12. Optimizing maleic anhydride microcapsules size for use in self-healing epoxy-based coatings for corrosion protection of aluminum alloy10.1002/maco.201709972 ↗
13. Characterizations of UV aging and atmospheric corrosion on epoxy coated 7A04 aluminum alloy10.4028/www.scientific.net/MSF.686.784 ↗
14. NTP-CERHR expert panel report on the reproductive and developmental toxicity of bisphenol A10.1002/bdrb.20147 ↗
15. Large-scale fabrication of translucent, stretchable and durable superhydrophobic composite films10.1039/C7TA08203G ↗
16. Development of stable superhydrophobic coatings on aluminum surface for corrosion-resistant, self-cleaning, and anti-icing applications10.1016/j.matdes.2015.12.155 ↗
17. Superhydrophobic paper fabricated via nanostructured titanium dioxide-functionalized wood cellulose fibers10.1007/s10853-020-04489-7 ↗
18. Slippery liquid-infused porous surface for corrosion protection with self-healing property10.1016/j.cej.2018.03.137 ↗
19. A mechanically robust transparent coating for anti-icing and self-cleaning applications10.1039/C8TA05692G ↗
20. Rough structure of electrodeposition as a template for an ultrarobust self-cleaning surface10.1021/acsami.6b15745 ↗
21. Hierarchical flower like double-layer superhydrophobic films fabricated on AZ31 for corrosion protection and self-cleaning10.1039/C7NJ02684F ↗
22. Waterborne bio-based epoxy coatings for the corrosion protection of metallic substrates10.1016/j.porgcoat.2019.105265 ↗
23. Fabrication of superhydrophobic green surfaces with good self-cleaning, chemical stability and anti-corrosion properties10.1007/s10853-019-03789-x ↗
24. Facile fabrication of superhydrophobic zinc coatings with corrosion resistance via an electrodeposition process10.1039/D0NJ00561D ↗
25. Stearic acid-coated superhydrophobic Fe2O3/Fe3O4 composite film on N80 steel for corrosion protection10.1016/j.surfcoat.2018.12.040 ↗
26. Formation of superhydrophobic micro-nanostructured iron oxide for corrosion protection of N80 steel10.1016/j.matdes.2018.09.002 ↗
27. Zhang, Z., Shen, Z., Wu, H., Li, L., and Fu, X. (2020). Study on preparation of superhydrophobic Ni-Co coating and corrosion resistance by sandblasting-electrodeposition. Coatings, 10.10.3390/coatings10121164 ↗
28. Self-healing solid slippery surface with porous structure and enhanced corrosion resistance10.1016/j.cej.2020.128083 ↗
29. Durable waterborne hydrophobic bio-epoxy coating with improved anti-icing and self-cleaning performance10.1021/acssuschemeng.8b04203 ↗
30. Icephobic materials: Fundamentals, performance evaluation, and applications10.1016/j.pmatsci.2019.03.004 ↗
31. Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation10.1016/j.cej.2017.10.006 ↗
32. A superhydrophobic monolithic material with tunable wettability for oil and water separation10.1007/s10853-014-8756-4 ↗
33. Scalable superhydrophobic coating with controllable wettability and investigations of its drag reduction10.1016/j.colsurfa.2018.07.011 ↗
34. Super-hydrophobic coatings on cotton fabrics using sol-gel technique by spray10.1007/s10971-020-05307-x ↗
35. Single-step formation of superhydrophobic surfaces using photobase-catalyzed sol-gel process10.1016/j.porgcoat.2019.105293 ↗
36. Patterning a superhydrophobic area on a facile fabricated superhydrophilic layer based on an inkjet-printed water-soluble polymer template10.1021/acs.langmuir.0c01769 ↗
37. Superhydrophobic SiO2 micro/nanofibrous membranes with porous surface prepared by freeze electrospinning for oil adsorption10.1016/j.colsurfa.2019.02.038 ↗
38. Insitu growth of durable superhydrophobic Mg-Al layered double hydroxides nanoplatelets on aluminum alloys for corrosion resistance10.1016/j.jallcom.2018.07.086 ↗
39. Preparation of superhydrophobic laser-induced graphene using taro leaf structure as templates10.1016/j.surfcoat.2020.125744 ↗
40. Omniphobic etched aluminum surfaces with anti-icing ability10.1021/acs.langmuir.0c01324 ↗
41. Fabrication of superhydrophobic surface with improved corrosion inhibition on 6061 aluminum alloy substrate10.1016/j.apsusc.2015.03.040 ↗
42. Fabrication of self-cleaning superhydrophobic surface on aluminum alloys with excellent corrosion resistance10.1016/j.surfcoat.2015.07.002 ↗
43. Rational designed structured superhydrophobic iron oxide surface towards sustainable anti-corrosion and self-cleaning10.1016/j.cej.2020.127768 ↗
44. One-step hydrothermal process to fabricate superhydrophobic surface on magnesium alloy with enhanced corrosion resistance and self-cleaning performance10.1016/j.apsusc.2017.06.066 ↗
45. Low-cost one-step fabrication of superhydrophobic surface on Al alloy10.1016/j.apsusc.2011.03.096 ↗
46. Colorful and superhydrophobic titanium surfaces textured by obliquely incident femtosecond laser induced micro/nano structures10.1016/j.optcom.2020.125687 ↗
47. Extraordinary drag-reducing effect of a superhydrophobic coating on a macroscopic model ship at high speed10.1039/c3ta10225d ↗
48. A facile method to prepare superhydrophobic fluorinated polysiloxane/ZnO nanocomposite coatings with corrosion resistance10.1016/j.apsusc.2014.11.100 ↗
49. Large-scale fabrication of durable and robust super-hydrophobic spray coatings with excellent repairable and anti-corrosion performance10.1016/j.cej.2019.02.093 ↗
50. Fabrication of superhydrophobic aluminium alloy surface with excellent corrosion resistance by a facile and environment-friendly method10.1016/j.apsusc.2013.06.117 ↗
51. Mechanically robust hydrophobic bio-based epoxy coatings for anti-corrosion application10.1016/j.surfcoat.2019.02.020 ↗
52. Electrochemical behaviour and corrosion inhibition of Al, Al-6061 and Al–Cu in neutral aqueous solutions10.1016/S0010-938X(98)00145-0 ↗
53. A study on electrochemical growth behavior of the Co–Ni alloy nanowires in anodic aluminum oxide template10.1016/j.jallcom.2009.02.020 ↗
54. Ellinas, K., Dimitrakellis, P., Sarkiris, P., and Gogolides, E. (2021). A review of fabrication methods, properties and applications of superhydrophobic metals. Processes, 9.10.3390/pr9040666 ↗
55. Atmospheric corrosion protection performance and mechanism of superhydrophobic surface based on coalescence-induced droplet self-jumping behavior10.1021/acsami.0c21802 ↗
56. Dong, X.J., Meng, J.B., Hu, Y.Z., Wei, X.T., Luan, X.S., and Zhou, H.A. (2020). Fabrication of self-cleaning superhydrophobic surfaces with improved corrosion resistance on 6061 aluminum alloys. Micromachines, 11.10.3390/mi11020159 ↗
57. Large spot diameter nanosecond laser treatment of aluminum alloy sheets for high-speed superhydrophobic hierarchical micro- and nanostructured surface preparation10.1016/j.surfcoat.2019.01.020 ↗
58. Electrospinning of a functional perfluorinated block copolymer as a powerful route for imparting superhydrophobicity and corrosion resistance to aluminum substrates10.1021/la102808w ↗
59. Structural comparison of self-assembled monolayers of n-alkanoic acids on the surfaces of silver, copper, and aluminum10.1021/ja00063a062 ↗
60. Structure stability and corrosion inhibition of super-hydrophobic film on aluminum in seawater10.1016/j.apsusc.2008.08.088 ↗
61. A simple approach to fabricate stable superhydrophobic glass surfaces10.1016/j.apsusc.2012.11.103 ↗
62. Resistance of solid surfaces to wetting by water10.1021/ie50320a024 ↗
63. Apparent contact angles on rough surfaces: The Wenzel equation revisited10.1016/S0927-7757(99)00098-9 ↗
64. Contact angle hysteresis. III. Study of an idealized heterogeneous surface10.1021/j100789a012 ↗
65. Fabrication of the superhydrophobic surface on aluminum alloy by anodizing and polymeric coating10.1016/j.apsusc.2012.10.167 ↗
66. Wettability of porous surfaces10.1039/tf9444000546 ↗
67. Rapid fabrication of large-area, corrosion-resistant superhydrophobic Mg alloy surfaces10.1021/am2010527 ↗
68. Superhydrophobic aluminum alloy surface: Fabrication, structure, and corrosion resistance10.1016/j.colsurfa.2013.09.014 ↗
69. Chemical nature of superhydrophobic aluminum alloy surfaces produced via a one-step process using fluoroalkyl-silane in a base medium10.1021/am201277x ↗
70. Corrosion behavior of super-hydrophobic surface on copper in seawater10.1016/j.electacta.2007.06.072 ↗