journal article·2019-07-31Open access

Fire Protection Performance and Thermal Behavior of Thin Film Intumescent Coating

Jing Han Beh, Ming Chian Yew, Ming Kun Yew, Lip Huat Saw

Coatings· Volume 9· Issue 8

Abstract

This paper presents the heat release characteristics, char formation and fire protection performance of thin-film intumescent coatings that integrate eggshell (ES) as an innovative and renewable flame-retardant bio-filler. A cone calorimeter was used to determine the thermal behavior of the samples in the condensed phase in line with the ISO 5660-1 standard. The fire resistance of the coatings was evaluated using a Bunsen burner test to examine the equilibrium temperature and formation of the char layer. The fire propagation test was also conducted according to BS 476: Part 6. On exposure, the samples X, Y, and Z were qualified to be Class 0 materials due to the indexes of fire propagation being below 12. Samples Y and Z reinforced with 3.50 wt.% and 2.50 wt.% of ES bio-filler, respectively, showed a significant improvement in reducing the heat release rate, providing a more uniform and thicker char layer. As a result, the addition of bio-filler content has proven to be efficient in stopping the fire propagation as well as reducing the total heat released and equilibrium temperature of the intumescent coatings.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Flame retardant materials and properties · Fire dynamics and safety research · Thermal and Kinetic Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Architecture and Sustainable Design, Lee Kong Chian Faculty of Engineering Science, University of Tunku Abdul Rahman, Cheras, 43000 Kajang, Malaysia

Department of Mechanical and Material Engineering, Lee Kong Chian Faculty of Engineering and Science, University of Tunku Abdul Rahman, Cheras, 43000 Kajang, Malaysia

Department of Civil Engineering, Lee Kong Chian Faculty of Engineering and Science, University of Tunku Abdul Rahman, Cheras, 43000 Kajang, Malaysia

Funding

University of Tunku Abdul Rahman Research Funding (UTARRF)

References (40)

Show source-provided references
1. Performance-based fire safety evacuation of an auditorium facility using a theoretical calculation method10.1108/IJBPA-11-2016-0027 ↗
2. Thermal decomposition of brominated flame retardants (BFRs): Products and mechanisms10.1016/j.pecs.2018.10.004 ↗
3. Prabir, B. (2018). Biomass Gasification, Pyrolysis and Torrefaction: Practical Design and Theory, Academic Press. [3rd ed.].
4. Playing with fire: Chemical safety expertise required10.1021/acs.jchemed.8b00152 ↗
5. Nuclear flash burns: A review and consideration10.1016/j.burnso.2017.10.002 ↗
6. Thermoplastic resins for thin film intumescent coatings-towards a better understanding of their effect on intumescent efficiency10.1016/j.polymdegradstab.2004.01.026 ↗
7. Surface-coating engineering for flame retardant flexible polyurethane foams: A critical review10.1016/j.compositesb.2019.107185 ↗
8. Fire propagation performance of intumescent fire protective coatings using eggshells as a novel biofiller10.1155/2014/805094 ↗
9. Effects from nano-titanium oxide on the thermal resistance of an intumescent fire retardant coating for structural applications10.1016/j.porgcoat.2016.09.017 ↗
10. Sorption on eggshell waste—A review on ultrastructure, biomineralization and other applications10.1016/j.cis.2013.12.013 ↗
11. The physicochemical characteristic of biodegradable methylcellulose film reinforced with chicken eggshells10.1016/j.matpr.2018.04.015 ↗
12. The formulation and study of the thermal stability and mechanical properties of an acrylic coating using chicken eggshell as a novel bio-filler10.1016/j.porgcoat.2013.06.011 ↗
13. Effects of eggshell on the microstructures and properties of Al–Cu–Mg/eggshell particulate composites
14. Collagen of the chicken eggshell membranes10.3109/03008209109152162 ↗
15. Investigation on effect of egg shell powder on mechanical properties of GFRP composites10.1016/j.matpr.2018.01.101 ↗
16. Effect of modified eggshell powder on physical properties of poly(lactic acid) and natural rubber composites10.1016/j.matpr.2017.06.160 ↗
17. Chemical composition of chicken eggshell and shell membranes10.1093/ps/82.3.510 ↗
18. Shah, A., Zhang, Y., Xu, X., Dayo, A., Li, X., Wang, S., and Liu, W. (2018). Reinforcement of stearic acid treated egg shell particles in epoxy thermosets: structural, thermal, and mechanical characterization. Materials, 11.10.3390/ma11101872 ↗
19. Preparation and characterization of composite anthill-chicken eggshell adsorbent: Optimization study on heavy metals adsorption using response surface methodology10.3923/jest.2017.120.130 ↗
20. Tensile and thermal properties of poly(lactic acid)/eggshell powder composite films10.1080/1023666X.2014.879633 ↗
21. Eggshell: A new bio-filler for polypropylene composites10.1016/j.matlet.2007.01.102 ↗
22. Removal of selenium and arsenic by animal biopolymers10.1385/BTER:102:1-3:113 ↗
23. Biomimetic synthesis of BaSO4 nanotubes using eggshell membrane as template10.1557/JMR.2004.0395 ↗
24. Controlled synthesis of different morphologies of BaWO4 crystals through biomembrane/organic-addition supramolecule Templates10.1021/cg0498002 ↗
25. Characterization and adsorption properties of eggshells and eggshell membrane10.1016/j.biortech.2005.02.050 ↗
26. Aspartame optical biosensor with bienzyme-immobilized eggshell membrane and oxygen-sensitive optode membrane10.1021/ac001097a ↗
27. Soluble eggshell membrane protein: Preparation, characterization and biocompatibility10.1016/j.biomaterials.2003.11.052 ↗
28. Fire-resistive performance of intumescent flame-retardant coatigs for steel10.1016/j.matdes.2011.05.032 ↗
29. Effect of epoxy binder on fire protection and bonding strength of intumescent fire protective coatings for steel10.4028/www.scientific.net/AMR.168-170.1228 ↗
30. Integration of thermal insulation coating and moving-air-cavity in a cool roof system for attic temperature reduction10.1016/j.enconman.2013.06.024 ↗
31. Influence of nano bio-filler on the fire-resistive and mechanical properties of water-based intumescent coatings10.1016/j.porgcoat.2018.07.022 ↗
32. (1989). BS 476 Part 6: 1989+A1: 2009 Fire Tests on Building Materials and Structures. Method of test for fire propagation for products, British Standards Institution.
33. (2002). ISO 5660-1 Reaction-to-Fire Tests-Heat Release, Smoke Production and Mass Loss Rate-Part 1: Heat Release Rate (Cone Calorimeter Method), International Standard Organization.
34. Study on preparation and fire-retardant mechanism analysis of intumescent flame-retardant coatings10.1016/j.surfcoat.2007.03.020 ↗
35. Synergistic effect of metal oxides on the flame retardancy and thermal degradation of novel intumescent flame-retardant thermoplastic polyurethanes10.1002/app.33759 ↗
36. A new kind of halogen-free fire retardant coatings made from expandable graphite
37. Influence of expandable graphiteon fire resistance and water resistance of flame retardant coatings10.1016/j.corsci.2006.10.024 ↗
38. Decay and termite resistance of medium density fiberboard (MDF) made from different wood species10.1016/S0964-8305(02)00072-0 ↗
39. Standard transition aluminas. Electron microscopy studies10.1590/S1516-14392000000400003 ↗
40. A study of the mechanism of flame retardance and smoke suppression in polymers filled with magnesium hydroxide10.1016/0141-3910(90)90118-Q ↗