Synthesis and Characterization of Metal Complexes Based on Aniline Derivative Schiff Base for Antimicrobial Applications and UV Protection of a Modified Cotton Fabric
Source abstract
Abstract
Antimicrobial textiles have played an increasingly important protection role in the medical field. With this aim, Schiff bases and nanometal complexes on the cotton fabric were in situ synthesized for achieving the conventional cotton fabric’s highly efficient and durable UV protection and antibacterial properties. Herein, a new Schiff base derived from the condensation reaction of 2,4-dihyroxybenzaldehyde with p-amino aniline was synthesized. Co, Ni, Cu, and Zn complexes of the Schiff base were also prepared and characterized by UV-Vis, Fourier-transform infrared spectroscopy, 1HNMR, 13CNMR, elemental analysis, and thermal analysis. The modified cotton fabric was also characterized via X-ray diffraction, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), transition electron microscope (TEM), and Energy Dispersive X-Ray Analysis (EDX). Moreover, the microbial, UV protection, and tensile strength of the samples were investigated. The antimicrobial was studied against Gram-positive bacteria, Gram-negative bacteria, and fungal strains. Modified cotton fabric exhibited highly antibacterial activity in contrast with fungal activity. These results depended on the Schiff base and the type of metal complex. The results also show that the cotton fabric modified by in situ nanometal complexes provides excellent UV protection.
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Research context
OpenAlex topics: Dyeing and Modifying Textile Fibers · Nanoparticles: synthesis and applications · Synthesis of Tetrazole Derivatives
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, College of Science, Qassim University, Buraidah 51452, Saudi Arabia
Department of Chemistry, College of Science, Ibb University, Ibb P.O. Box 70270, Yemen
Department of Physics, College of Science and Arts in Al-Asyah, Qassim University, Buraidah 51452, Saudi Arabia
National Research Centre, Institute of Textile Research and Technology, 33 El Bohouth Street, Dokki, Cairo P.O. Box 12622, Egypt
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