Superconducting HfO2-YBa2Cu3O7−δ Nanocomposite Films Deposited Using Ink-Jet Printing of Colloidal Solutions

To reduce the fabrication costs while maximizing the superconducting and pinning properties of YBa2Cu3O7−δ (YBCO) nanocomposite films, the drop-on-demand ink-jet printing technique was used to deposit colloidal YBCO inks onto LaAlO3 substrates. These inks containing preformed HfO2 nanocrystals were carefully adjusted, prior to the jettability, as the droplet formation depends on the rheological properties of the inks themselves. After carefully adjusting printing parameters, 450-nm thick pristine YBCO films with a self-field critical current density (Jc) of 2.7 MA cm−² at 77 K and 500-nm thick HfO2-YBCO nanocomposite films with a self-field Jc of 3.1 MA·cm−² at 77 K were achieved. The final HfO2-YBCO nanocomposite films contained dispersed BaHfO3 particles in a YBCO matrix due to the Ba2+ reactivity with the HfO2 nanocrystals. These nanocomposite films presented a more gradual decrease of Jc with the increased magnetic field. These nanocomposite films also showed higher pinning force densities than the pristine films. This pinning enhancement was related to the favorable size and distribution of the BaHfO3 particles in the YBCO matrix.