journal article·2023-04-30Open access

Convolvulus microphyllus Extract as a Green, Effective, and Affordable Corrosion Inhibitor: Theoretical Calculations and Experimental Studies

Rajesh Haldhar, Ramkumar Vanaraj, Omar Dagdag, Avni Berisha, Seong-Cheol Kim

Coatings· Volume 13· Issue 5

Abstract

This study demonstrates the ability of Convolvulus microphyllus extract to prevent low-carbon steel corrosion (LCS) by varying inhibitor concentration. The effectiveness of the corrosion reaction was examined using gravimetric techniques and electrochemical procedures in a corrosive 0.5 M sulfuric acid medium. The results of polarization show a mixed adsorption nature on the LCS surface. C. microphyllus-derived film (extract) had an inhibition efficiency (IE) of 92.47% at an inhibitor concentration of 600 mg/L and a temperature 298 K. To examine the morphology, a scanning electron microscope (SEM) and atomic force microscope (AFM) were used to analyze the external films that protect LCS from sulfuric acid. A thin protective coat of inhibitor outside the LCS substrate follows the Langmuir adsorption isotherm. Additionally, computational exploration provided vital insights. The results of these experimental inhibitory outcomes are consistent with those of molecular dynamic simulations.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Electrochemical Analysis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea

Centre for Materials Science, College of Science, Engineering and Technology, University of South Africa, Johannesburg 1710, South Africa

Department of Chemistry, Faculty of Natural and Mathematics Science, University of Prishtina, 10020 Prishtina, Kosovo

Funding

NRF (National Research Foundation) of Korea · Ministry of SMEs and Startups (MSS, Korea)

References (86)

Show source-provided references
1. N–hydroxybenzothioamide derivatives as green and efficient corrosion inhibitors for mild steel: Experimental, DFT and MC simulation approach10.1016/j.molstruc.2021.130648 ↗
2. A combined experimental and theoretical study of green corrosion inhibition of mild steel in HCl solution by aqueous Citrullus lanatus fruit (CLF) extract10.1016/j.molliq.2019.02.010 ↗
3. Green method of carbon steel effective corrosion mitigation in 1 M HCl medium protected by Primula vulgaris flower aqueous extract via experimental, atomic-level MC/MD simulation and electronic-level DFT theoretical elucidation10.1016/j.molliq.2019.04.037 ↗
4. Application of green molecules from Chicory aqueous extract for steel corrosion mitigation against chloride ions attack; the experimental examinations and electronic/atomic level computational studies10.1016/j.molliq.2019.111176 ↗
5. A green complex film based on the extract of Persian Echium amoenum and zinc nitrate for mild steel protection in saline solution; Electrochemical and surface explorations besides dynamic simulation10.1016/j.molliq.2019.111281 ↗
6. Green Eucalyptus leaf extract: A potent source of bio-active corrosion inhibitors for mild steel10.1016/j.bioelechem.2019.107339 ↗
7. Aloysia citrodora leaves extract corrosion retardation effect on mild-steel in acidic solution: Molecular/atomic scales and electrochemical explorations10.1016/j.molliq.2020.113221 ↗
8. Green synthesis of reduced graphene oxide nanosheets decorated with zinc-centered metal-organic film for epoxy-ester composite coating reinforcement: DFT-D modeling and experimental explorations10.1016/j.jtice.2020.09.003 ↗
9. Steel corrosion lowering in front of the saline solution by a nitrogen-rich source of green inhibitors: Detailed surface, electrochemical and computational studies10.1016/j.conbuildmat.2020.119266 ↗
10. Corrosion prevention of AISI 304 stainless steel in hydrochloric acid medium using garlic extract as a green corrosion inhibitor: Electrochemical and theoretical studies10.1016/j.molliq.2020.113679 ↗
11. Synthesis of a multi-functional zinc-centered nitrogen-rich graphene-like thin film from natural sources on the steel surface for achieving superior anti-corrosion properties10.1016/j.corsci.2020.109077 ↗
12. Anti-corrosion performance of the mild steel substrate treated by a novel nanostructure europium oxide-based conversion coating: Electrochemical and surface studies10.1016/j.colsurfa.2020.125689 ↗
13. Detailed theoretical DFT computation/molecular simulation and electrochemical explorations of Thymus vulgaris leave extract for effective mild-steel corrosion retardation in HCl solution10.1016/j.molliq.2021.115897 ↗
14. Valeriana wallichii root extract as a green & sustainable corrosion inhibitor for mild steel in acidic environments: Experimental and theoretical study10.1039/C8QM00120K ↗
15. Superior inhibition action of the Mish Gush (MG) leaves extract toward mild steel corrosion in HCl solution: Theoretical and electrochemical studies10.1016/j.molliq.2021.115876 ↗
16. Theoretical design coupled with experimental study of the effectiveness of the inhibitive molecules based on Cynara scolymus L extract toward chloride-induced corrosion of steel10.1016/j.molliq.2021.115742 ↗
17. A comprehensive electronic-scale DFT modeling, atomic-level MC/MD simulation, and electrochemical/surface exploration of active nature-inspired phytochemicals based on Heracleum persicum seeds phytoextract for effective retardation of the acidic-induced c10.1016/j.molliq.2021.115764 ↗
18. Theoretical and experimental assessment of a green corrosion inhibitor extracted from Malva sylvestris10.1016/j.jece.2021.105256 ↗
19. Combined electrochemical/surface investigations and computer modeling of the aquatic Artichoke extract molecules corrosion inhibition properties on the mild steel surface immersed in the acidic medium10.1016/j.molliq.2020.114856 ↗
20. Synthesis of graphene oxide nanosheets decorated by nanoporous zeolite-imidazole (ZIF-67) based metal-organic framework with controlled-release corrosion inhibitor performance: Experimental and detailed DFT-D theoretical explorations10.1016/j.jhazmat.2020.124068 ↗
21. Struktur der microphyllinsäure aus dem harz von Convolvulus microphyllus10.1016/S0031-9422(00)89238-9 ↗
22. Koch, G., Varney, J., Thompson, N., Moghissi, O., Gould, M., and Payer, J. (2016). International Measures of Prevention, Application, and Economics of Corrosion Technologies Study, NACE International. [1st ed.].
23. Construction of a high-potency anti-corrosive metal-organic film based on europium (III)-benzimidazole: Theoretical and electrochemical investigations10.1016/j.conbuildmat.2020.121271 ↗
24. Nano-scale P, Zn-codoped reduced-graphene oxide incorporated epoxy composite; synthesis, electronic-level DFT-D modeling, and anti-corrosion properties10.1016/j.porgcoat.2021.106416 ↗
25. Polyurethane Based Triblock Copolymers as Corrosion Inhibitors for Mild Steel in 0.5 M H2SO410.1021/acs.iecr.6b03928 ↗
26. Piperine derivatives as green corrosion inhibitors on iron surface; DFT, Monte Carlo dynamics study and complexation modes10.1016/j.molliq.2018.03.127 ↗
27. Inhibition performance of Glycine max, Cuscuta reflexa and Spirogyra extracts for mild steel dissolution in acidic medium: Density functional theory and experimental studies10.1016/j.rinp.2018.06.003 ↗
28. Anti-corrosion performance of eco-friendly inhibitor (2-aminobenzyl) triphenylphosphonium bromide ionic liquid on mild steel in 0.5M sulfuric acid10.1016/j.molliq.2018.04.043 ↗
29. An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media10.1016/j.molliq.2018.06.110 ↗
30. Interfacial adsorption behavior of quaternary phosphonium based ionic liquids on metal-electrolyte interface: Electrochemical, surface characterization and computational approaches10.1016/j.molliq.2019.111995 ↗
31. Isopentyltriphenylphosphonium bromideionic liquid as a newly effective corrosion inhibitor on metal-electrolyte interface in acidic medium: Experimental, surface morphological (SEM-EDX & AFM) and computational analysis10.1016/j.molliq.2020.113838 ↗
32. Towards a theoretical understanding of alkaloid-extract Cytisine derivatives of Retama monosperma (L.) Boiss. Seeds, as eco-friendly inhibitor for carbon steel corrosion in acidic 1M HCl solution10.1142/S0219633620500133 ↗
33. Acid corrosion inhibition of ferrous and non-ferrous metal by nature friendly Ethoxycarbonylmethyltriphenylphosphonium Bromide (ECMTPB): Experimental and MD simulation evaluation10.1016/j.molliq.2020.113705 ↗
34. Study of adsorption mechanism of chalcone derivatives on mild steel-sulfuric acid interface10.1016/j.molliq.2020.113890 ↗
35. Daoudi, W., El Aatiaoui, A., Dagdag, O., Zaidi, K., Haldhar, R., Kim, S.C., Oussaid, A., Aouinti, A., Berisha, A., and Benhiba, F. (2023). Anti-corrosion coating formation by a biopolymeric extract of Artemisia herba-alba plant: Experimental and theoretical investigations. Coatings, 13.10.3390/coatings13030611 ↗
36. Electrochemical studies and molecular simulations on the use of molybdic acid for stabilization of AISI 304 stainless steel passive film in sulfuric acid medium10.1016/j.molliq.2021.117733 ↗
37. Experimental and computational studies on hydroxamic acids as environmental friendly chelating corrosion inhibitors for mild steel in aqueous acidic medium10.1016/j.molliq.2020.113651 ↗
38. Improving the localized corrosion resistance of 304 stainless steel in HCl solution by adsorption of molybdate ions: Interaction mechanisms at the interface using molecular dynamics simulation and electrochemical noise analysis10.1016/j.colsurfa.2022.129085 ↗
39. Computational Modeling: Theoretical Predictive Tools for Designing of Potential Organic Corrosion Inhibitors10.1016/j.molstruc.2021.130294 ↗
40. Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study10.1016/j.molliq.2018.01.144 ↗
41. A new trend in corrosion protection of copper in acidic medium by using Jujube shell extract as an effective green and environmentally safe corrosion inhibitor: Experimental, quantum chemistry approach and Monte Carlo simulation study10.1016/j.molliq.2020.114509 ↗
42. Inhibitive effect of Clopidogrel as a green corrosion inhibitor for mild steel; statistical modeling and quantum Monte Carlo simulation studies10.1016/j.molliq.2018.08.050 ↗
43. Evaluation of Lavandula mairei extract as green inhibitor for mild steel corrosion in 1 M HCl solution. Experimental and theoretical approach10.1016/j.molliq.2020.113493 ↗
44. Research of Lilium brownii leaves extract as a commendable and green inhibitor for X70 steel corrosion in hydrochloric acid10.1016/j.molliq.2020.114914 ↗
45. Natural nutmeg oil as a green corrosion inhibitor for carbon steel in 1.0 M HCl solution: Chemical, electrochemical, and computational methods10.1016/j.molliq.2020.115036 ↗
46. Theoritical evaluation of Citrus Aurantium Leaf Extract as green inhibitor for chemical and biological corrosion of mild steel in acidic solution: Statistical, molecular dynamics, Docking, and quantum mechanics study10.1016/j.molliq.2021.116978 ↗
47. Comparative study of some epoxy polymers based on bisphenolic and aromatic diamines: Synthesis, viscosity, thermal properties computational and statistical approaches10.1007/s10965-021-02530-0 ↗
48. Dendrimeric Epoxy Resins Based on Hexachlorocyclotriphosphazene as a Reactive Flame Retardant Polymeric Materials: A Review10.1007/s10904-021-01900-x ↗
49. Performance of two new epoxy resins as potential corrosion inhibitors for carbon steel in 1MHCl medium: Combining experimental and computational approaches10.1016/j.colsurfa.2021.127066 ↗
50. Epoxy resin and TiO2 composite as anticorrosive material for carbon steel in 3% NaCl medium: Experimental and computational studies10.1016/j.molliq.2020.114249 ↗
51. Trifunctional epoxy resin as anticorrosive material for carbon steel in 1 M HCl: Experimental and computational studies10.1016/j.surfin.2020.100707 ↗
52. Investigation of Corrosion Inhibition Effect and Adsorption Activities of Achyranthes aspera Extract for Mild Steel in 0.5 M H2SO410.1007/s11668-018-0491-8 ↗
53. Investigation of plant waste as a renewable biomass source to develop efficient, economical and eco-friendly corrosion inhibitor10.1016/j.molliq.2021.116184 ↗
54. Use of Syzygium aromaticum extract as green corrosion inhibitor for mild steel in 0.5M H2SO410.1142/S0218625X18502001 ↗
55. Zavidovskiy, I.A., Streletskiy, O.A., Nuriahmetov, I.F., Nishchak, O.Y., Savchenko, N.F., Tatarintsev, A.A., and Pavlikov, A.V. (2023). Highly selective polyene-polyyne resistive gas sensors: Response tuning by low-energy ion irradiation. J. Compos. Sci., 7.10.3390/jcs7040156 ↗
56. FTIR spectroscopy for carbon family study10.1080/10408347.2016.1157013 ↗
57. Use of Sida cordifolia extract as green corrosion inhibitor for mild steel in 0.5 M H2SO410.1016/j.jece.2017.12.064 ↗
58. Investigation of corrosion inhibition effect and adsorption activities of Cuscuta reflexa extract for mild steel in 0.5 M H2SO410.1016/j.bioelechem.2018.07.006 ↗
59. Use of Saraca ashoka extract as green corrosion inhibitor for mild steel in 0.5 M H2SO410.1016/j.molliq.2018.02.104 ↗
60. Papaver somniferum as an efficient corrosion inhibitor for iron alloy in acidic condition: DFT, MC simulation, LCMS and electrochemical studies10.1016/j.molstruc.2021.130822 ↗
61. Myristica fragrans extract as an eco-friendly corrosion inhibitor for mild steel in 0.5 M H2SO4 solution10.1016/j.jece.2018.03.023 ↗
62. Experimental and theoretical studies of Ficus religiosa as green corrosion inhibitor for mild steel in 0.5 M H2SO4 solution10.1016/j.scp.2018.07.002 ↗
63. Extraction and experimental studies of Citrus aurantifolia as an economical and green corrosion inhibitor for mild steel in acidic media10.1080/01694243.2019.1585030 ↗
64. Armoracia rusticana as sustainable and eco-friendly corrosion inhibitor for mild steel in 0.5M sulphuric acid: Experimental and theoretical investigations10.1016/j.jece.2018.08.025 ↗
65. Surface Adsorption and Corrosion Resistance Performance of Acacia concinna Pod Extract: An Efficient Inhibitor for Mild Steel in Acidic Environment10.1007/s13369-019-04270-2 ↗
66. Corrosion resistance of mild steel in 0.5 M H2SO4 solution by plant extract of Alkana tinctoria: Experimental and theoretical studies10.1140/epjp/i2018-12165-0 ↗
67. Evaluation of Gloriosa superba seeds extract as corrosion inhibition for low carbon steel in sulfuric acidic medium: A combined experimental and computational studies10.1016/j.molliq.2020.114958 ↗
68. Anticorrosive properties of a green and sustainable inhibitor from leaves extract of Cannabis sativa plant: Experimental and theoretical approach10.1016/j.colsurfa.2021.126211 ↗
69. Experimental and Theoretical Evaluation of Acacia catechu Extract as a Natural, Economical and Effective Corrosion Inhibitor for Mild Steel in an Acidic Environment10.1007/s40735-020-00368-5 ↗
70. Corrosion inhibition, surface adsorption and computational studies of Momordica charantia extract: A sustainable and green approach10.1007/s42452-020-04079-x ↗
71. Corrosion Resistance and Surface Protective Performance of Waste Material of Eucalyptus globulus for Low Carbon Steel10.1007/s40735-020-00340-3 ↗
72. Withania somnifera extract as green inhibitor for mild steel in 8 % H2SO410.14233/ajchem.2016.20020 ↗
73. Performance of Pfaffia paniculata extract towards corrosion mitigation of low-carbon steel in an acidic environment10.1007/s40090-020-00222-0 ↗
74. Corrosion inhibition, surface adsorption and computational studies of Swertia chirata extract: A sustainable and green approach10.1016/j.matchemphys.2021.124613 ↗
75. DFT/electronic scale, MD simulation and evaluation of 6-methyl-2-(p-tolyl)-1,4-dihydroquinoxaline as a potential corrosion inhibition10.1016/j.molliq.2021.116539 ↗
76. Highly functionalized epoxy macromolecule as an anti-corrosive material for carbon steel: Computational (DFT, MDS), surface (SEM-EDS) and electrochemical (OCP, PDP, EIS) studies10.1016/j.molliq.2020.112535 ↗
77. Chromeno naphthyridines based heterocyclic compounds as novel acidizing corrosion inhibitors: Experimental, surface and computational study10.1016/j.molliq.2020.114825 ↗
78. Highly efficient and eco-friendly acid corrosion inhibitor for mild steel: Experimental and theoretical study10.1016/j.molliq.2021.116220 ↗
79. Adsorption and inhibition mechanism of efficient and environment friendly corrosion inhibitor for mild steel: Experimental and theoretical study10.1016/j.molliq.2021.116634 ↗
80. Cyclohexylamine an effective corrosion inhibitor for mild steel in 0.1 N H2SO4: Experimental and theoretical (molecular dynamics simulation and FMO) study10.1016/j.molliq.2020.114847 ↗
81. Correlation between corrosion inhibition efficiency in sulfuric acid medium and the molecular structures of two newly eco-friendly pyrazole derivatives on iron oxide surface10.1016/j.molliq.2021.115656 ↗
82. Ambient-stable polyethyleneimine functionalized Ti3C2Tx nanohybrid corrosion inhibitor for copper in alkaline electrolyte10.1016/j.matlet.2023.133979 ↗
83. Dong, P., Zhang, Y., Zhu, S., Nie, Z., Ma, H., Liu, Q., and Li, J. (2022). First-Principles Study on the Adsorption Characteristics of Corrosive Species on Passive Film TiO2 in a NaCl Solution Containing H2S and CO2. Metals, 12.10.3390/met12071160 ↗
84. Benzothiazole derivatives-based supramolecular assemblies as efficient corrosion inhibitors for copper in artificial seawater: Formation, interfacial release and protective mechanisms10.1016/j.corsci.2022.110957 ↗
85. Study of the Aegle marmelos as a Green Corrosion Inhibitor for Mild Steel in Acidic Medium: Experimental and Theoretical Approach10.1007/s40735-018-0178-4 ↗
86. Use of Asparagus racemosus extract as green corrosion inhibitor for mild steel in 0.5 M H2SO410.1007/s10853-018-2123-9 ↗