journal article·2020-08-31Open access

Corrosion Behavior of a Ni–Cr–Mo Alloy Coating Fabricated by Laser Cladding in a Simulated Sulfuric Acid Dew Point Corrosion Environment

Chao Zheng, Zongde Liu, Shanshan Chen, Congcong Liu

Coatings· Volume 10· Issue 9

Abstract

For this study, aimed at proposing a potential direction to prevent sulfuric acid dew point corrosion, a Ni–Cr–Mo alloy Hastelloy C22 coating was fabricated by coaxial laser cladding technology. The phase composition, microstructure, and corrosion behavior in a simulated sulfuric acid dew point corrosion environment were investigated and compared with a Hastelloy C22 alloy, a titanium alloy TC4, and 09CrCuSb steel (ND). The results showed that the phase composition of the C22 coating is essentially similar to that of the C22 alloy, consisting of a γ-Ni solid solution and Ni6Mo6C1.06. The finer microstructure of the C22 coating mainly contains eutectic and dentrite, presenting a typical solidification feature of laser cladding. The corrosion resistance of the C22 coating is very close to that of the C22 alloy, and outclasses that of TC4 and ND. The corrosion behavior of the C22 coating is intergranular corrosion resulting from the segregation of molybdenum, chromium containing corrosion products, and smaller anode micro-batteries.
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Research context

OpenAlex topics: Metal and Thin Film Mechanics · High Entropy Alloys Studies · Titanium Alloys Microstructure and Properties

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Affiliations

Key Laboratory of Energy Transfer and System of Power Station of Ministry of Education, North China Electric Power University, Beijing 102206, China

Funding

Equipment Pre-research Fund · Fundamental Research Funds for the Central Universities

References (72)

Show source-provided references
1. Determining corrosivity of flue gas condensate
2. Holmes, D.R. (1985). Dewpoint Corrosion, Ellis Horwood.
3. Latest advances in the understanding of acid dewpoint corrosion: Corrosion and stress corrosion cracking in combustion gas condensates10.1108/00035590410533129 ↗
4. Problems existing in operation of wet limestone/gypsum desulfuration system in luohuang power plant and analysis
5. Analysis of low temperature corrosion in coal-fired boiler
6. The corrosion of a steel surface by condensed films of sulphuric acid10.1002/jctb.5010010904 ↗
7. Evaluation of Methods for Measurement of SO3/H2SO4 in Flue Gas10.1080/00022470.1979.10470750 ↗
8. The kinetics of SO3 formation in oil-fired boilers
9. Estimation of combustion flue gas acid dew point during heat recovery and efficiency gain10.1016/j.applthermaleng.2011.01.020 ↗
10. Experimental study and mechanism analysis on low temperature corrosion of coal fired boiler heating surface10.1016/j.applthermaleng.2015.02.003 ↗
11. Berger, D.M., Kieffer, J.K., Trewella, R.J., Wummer, C.J., and Mathay, W.L. (1984). Flue Gas Condensate Sampling and Analysis Study, NACE.
12. Corrosion in flue gas desulfurization plants and other low temperature equipment10.1002/maco.19920430610 ↗
13. MOHURD (2013). GB 50051-2013: Code for Design of Chimneys.
14. Energy, exergy and economic analysis of industrial boilers10.1016/j.enpol.2009.11.087 ↗
15. Technical aspects of lime/limestone scrubbers for coal-fired power plants: Part II: Instrumentation and technology10.1080/00022470.1980.10465116 ↗
16. Flue gas desulfurization: The state of the art10.1080/10473289.2001.10464387 ↗
17. Analysis of degradation of a super-austenitic stainless steel for flue gas desulfurization system after a fire accident10.1016/j.engfailanal.2007.04.006 ↗
18. Environmental influence and countermeasures for high humidity flue gas discharging from power plants10.1016/j.rser.2017.01.143 ↗
19. Anticipate corrosion problems
20. Anti-corrosion protection of chimneys and flue gas ducts10.1108/00035599810236243 ↗
21. Experimental study on corrosion of steels for flue gas reheaters in a coal-fired power plant10.1016/j.applthermaleng.2016.12.066 ↗
22. Deposition and corrosion characteristics of liquid-solid droplets on tubular corrosion probes in desulfurized flue gas10.1016/j.engfailanal.2018.03.020 ↗
23. Corrosion evaluation of one wet desulfurization equipment—Flue gas desulfurization unit10.1016/j.fuproc.2018.10.005 ↗
24. Radway, J.E., and Exley, L.M. (December, January 30). A practical review of the cause and control of cold end corrosion and acidic stack emissions in oil-fired boilers. Proceedings of the Winter Meeting of the ASME, Houston, TX, USA.
25. Cold end corrosion: Causes and cures
26. Solve waste-fuel boiler corrosion problems in procurement
27. Corrosion resistance of FGD ductwork materials
28. Agrawal, A.K., Koch, G.H., and Ross, R.W. (1994). Corrosion performance of duplex and austenitic stainless steels in simulated fgd environments. International Corrosion Conference Series, v 1996-March, NACE.
29. Application and performance of titanium linings in FGD ductwork and stacks10.1002/maco.19920430608 ↗
30. Evaluation of mercaptoazoles as corrosion inhibitors in simulated sulphur dioxide scrubber environments10.1108/eb007360 ↗
31. CICIND (2002). Model Code for Steel Chimneys, Revision 1—1990, Amendment A—2002, CICIND (International Committee on Industrial Construction).
32. Cramer, S.D., and Covino, B.S. (2006). ASM Handbook Vol. 13c: Corrosion: Environments and Industries, ASM International.10.31399/asm.hb.v13c.9781627081849 ↗
33. Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates10.1016/j.corsci.2017.01.016 ↗
34. High performance alloys for solving severe corrosion problems in flue gas desulfurization systems10.1002/maco.19890400702 ↗
35. Corrosion-resistant Ni-Cr-Mo alloys in hot concentrated sulphuric acid with active carbon10.1016/0921-5093(95)80069-7 ↗
36. Durability evaluation of Ni-Cr-Mo super alloys in a simulated scrubbed flue gas environment10.1108/00035599910252703 ↗
37. Corrosion-resistant alloys for flue gas desulfurization installations10.1007/BF01148693 ↗
38. Corrosion resistance of alloys in sulfuric acid at various concentrations and temperatures10.1007/BF01150286 ↗
39. Behaviour of Hastelloy C22 steel in sulphate solutions at pH 3 and low temperatures10.1007/BF00356632 ↗
40. Evaluation of high Ni-Cr-Mo alloys for the construction of sulfur dioxide scrubber plants10.1007/BF02647268 ↗
41. Laser Cladding of Stainless Steel with Hastelloy10.1002/1527-2648(200104)3:4<242::AID-ADEM242>3.0.CO;2-D ↗
42. High power diode laser cladding10.1016/S0924-0136(03)00109-2 ↗
43. Characteristics of cobalt-based alloy coating on tool steel prepared by powder feeding laser cladding10.1016/j.optlastec.2006.12.005 ↗
44. Characterization of dilution action in laser-induction hybrid cladding10.1016/j.optlastec.2010.12.005 ↗
45. Microstructural and mechanical characteristics of laser coatings10.1016/S0257-8972(99)00394-1 ↗
46. Nd: YAG laser cladding of marine propeller with hastelloy C-2210.1007/s00339-004-2854-0 ↗
47. Microstructures, mechanical properties and corrosion resistance of Hastelloy C22 coating produced by laser cladding10.1016/j.jallcom.2012.10.193 ↗
48. Corrosion behavior of Hastelloy C22 coating produced by laser cladding in static and cavitation acid solution10.1016/S1003-6326(14)63232-5 ↗
49. Effect of mechanical polishing on corrosion behavior of Hastelloy C22 coating prepared by high power diode laser cladding10.1016/j.apsusc.2014.02.172 ↗
50. Improvement of Ni-Cr-Mo coating performance by laser cladding combined re-melting10.1016/j.apsusc.2014.04.156 ↗
51. The anti-corrosion behavior under multi-factor impingement of Hastelloy C22 coating prepared by multilayer laser cladding10.1016/j.apsusc.2017.12.108 ↗
52. Erosion-corrosion behavior and electrochemical performance of Hastelloy C22 coatings under impingement10.1016/j.apsusc.2018.06.209 ↗
53. Liu, Z.D., Li, C.C., Gao, Y., and Zheng, C. (2020). High temperature corrosion behaviors of 20G steel, Hastelloy C22 alloy and C22 laser coating under reducing atmosphere with H2S. Coatings, 10.10.3390/coatings10070617 ↗
54. Mclean, M.A., Shannon, G.J., and Steen, W.M. (August, January 30). Laser generating metallic components. Proceedings of the SPIE—The International Society for Optical Engineering, San Diego, CA, USA.
55. Closed loop direct metal deposition: Art to Part10.1016/S0143-8166(00)00072-5 ↗
56. Analysis of coaxial laser cladding processing conditions10.1016/j.surfcoat.2004.06.029 ↗
57. Comparison of coaxial and off-axis nozzle configurations in one step process laser cladding on aluminum substrate10.1016/j.jmatprotec.2012.06.011 ↗
58. Effect of yttrium on the corrosion behaviour of 09CrCuSb alloy in concentrated sulphuric acid10.1016/j.corsci.2013.01.005 ↗
59. Mechanism research on coupling effect between dew point corrosion and ash deposition10.1016/j.applthermaleng.2012.12.013 ↗
60. ASTM International (2017). Designation: G1-03 (Reapproved 2017), Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens, ASTM International.
61. ASTM International (2012). Designation: G31-12a, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM International.
62. Low-Temperature Boiler Corrosion and Deposits—A Literature Review10.1021/ie50598a041 ↗
63. Predicting the corrosivity of an operating FGD system
64. A new steel with good low-temperature sulfuric acid dew point corrosion resistance10.1002/maco.201006046 ↗
65. Investigations on the behavior of laser cladding Ni-Cr-Mo alloy coating on TP347H stainless steel tube in HCl rich environment10.1016/j.surfcoat.2013.06.048 ↗
66. A comparative study on the high temperature corrosion of TP347H stainless steel, C22 alloy and laser-cladding C22 coating in molten chloride salts10.1016/j.corsci.2014.03.012 ↗
67. Effects of powder concentration distribution on fabrication of thin-wall parts in coaxial laser cladding10.1016/j.optlastec.2004.04.009 ↗
68. Morphologies, microstructures and properties of TiC particle reinforced Inconel 625 coatings obtained by laser cladding with wire10.1016/j.jallcom.2017.12.298 ↗
69. Enhanced corrosion and wear resistance properties of carbon fiber reinforced Ni-based composite coating by laser cladding10.1016/j.surfcoat.2017.11.051 ↗
70. Performance of corrosion-resistant alloys in concentrated acids10.1007/s40195-017-0538-y ↗
71. Electrochemical methods to detect susceptibility of Ni-Cr-Mo-W alloy 22 to intergranular corrosion10.1007/s11661-005-0208-y ↗
72. Corrosion behaviour of vacuum induction-melted Ni-based alloy in sulphuric acid10.1016/j.corsci.2010.03.026 ↗