journal article·2018-01-15Open access

Corrosion Inhibition Properties of Waterborne Polyurethane/Cerium Nitrate Coatings on Mild Steel

Mohammad Rahman, Md. Zahir, Md. Haq, Dhafer Shehri, A. Kumar

Coatings· Volume 8· Issue 1

Abstract

Waterborne polyurethane (WBPU)/cerium nitrate (Ce(NO3)3) dispersions were synthesized with different defined Ce(NO3)3 content. All pristine dispersions were stable with different poly(tetramethylene oxide) glycol (PTMG) number average molecular weights (Mn) of 650, 1000, and 2000. The interaction between the carboxyl acid salt group and Ce(NO3)3 was analyzed by Fourier-transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) techniques. Coating hydrophilicity, water swelling (%), water contact angle, leaching, and corrosion protection efficiency were all affected when using different Ce(NO3)3 content and PTMG molecular weights. The maximal corrosion protection of the WBPU coating was recorded using a higher molecular weight of PTMG with 0.016 mole Ce(NO3)3 content.
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Research context

OpenAlex topics: Polymer composites and self-healing · Silicone and Siloxane Chemistry · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Center of Research Excellence in Corrosion, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Center of Research Excellence in Renewable Energy, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Department of Petroleum Engineering, College of Petroleum and Geosciences, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

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