journal article·2018-05-07Open access

Effect of Graphene Oxide/ZSM-5 Hybrid on Corrosion Resistance of Waterborne Epoxy Coating

Na Wang, Huiying Gao, Jing Zhang, Ping Kang

Coatings· Volume 8· Issue 5

Abstract

In this study, the preparation of modified graphene oxide (GO) synergistic structure (ZSM-5-NH-GO) and the effect of this structure on the corrosion performance of epoxy coatings were investigated. The structural and morphological properties of ZSM-5-NH-GO were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The corrosion performances were studied by electrochemical impedance spectroscopy (EIS) and salt spray tests. The EIS results showed that the corrosion resistance of steel substrate was considerably improved by ZSM-5-NH-GO. The salt spray tests demonstrated that the ZSM-5-NH-GO coating provided strong corrosion performance for steel substrate. The mechanical properties of the epoxy-composite coatings containing ZSM-5-NH-GO were studied by adhesion tests. The above results indicated that the composite coating containing 0.7 wt % ZSM-5-NH-GO composite possessed most excellent anti-corrosion performance compared with other epoxy coatings.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Conducting polymers and applications · High voltage insulation and dielectric phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Sino-Spanish Advanced Materials Institute, Shenyang University of Chemical Technology, Shenyang 110142, China

Advanced Manufacturing Institute of Polymer Industry (AMIPI), Shenyang University of Chemical Technology, Shenyang 110142, China

Funding

the financial support of the Finance Refers to Top Talents of Liaoning Province · the BaiQianWan Talents Program of Liaoning Province · Innovative Talents Program of Universities in Liaoning Province · Science and Technology Program of Shenyang · Shenyang Scientific and Technological Innovation Talents Program for Youngs and Middles

References (32)

Show source-provided references
1. The structural stability of graphene anticorrosion coating materials is compromised at low potentials10.1002/chem.201406238 ↗
2. Atmospheric corrosion resistance of MnCuP weathering steel in simulated environments10.1016/j.corsci.2011.08.028 ↗
3. Corrosion protection of stainless steel by separate polypyrrole electrode in acid solutions10.1002/maco.200905344 ↗
4. Composition and expansion coefficient of rust based on X-ray diffraction and thermal analysis10.1016/j.corsci.2011.01.007 ↗
5. Study of dextrin-derived curing agent for waterborne epoxy adhesive10.1016/j.carbpol.2010.09.019 ↗
6. Recent developments in the utilization of green solvents in polymer chemistry10.1039/b909964f ↗
7. Application of magnetite nano-hybrid epoxy as protective marine coatings for steel10.1039/C5RA20730D ↗
8. Graphene: Corrosion-inhibiting coating10.1021/nn203507y ↗
9. Thermomechanical and corrosion inhibition properties of graphene/epoxy ester–siloxane–urea hybrid polymer nanocomposites10.1016/j.porgcoat.2015.07.005 ↗
10. A facile electrochemical approach for development of highly corrosion protective coatings using graphene nanosheets10.1016/j.elecom.2013.03.032 ↗
11. Effect of aminopropylisobutyl polyhedral oligomeric silsesquioxane functionalized graphene on the thermal conductivity and electrical insulation properties of epoxy composites10.1039/C5RA24885J ↗
12. Preparation of polyaniline/graphene composites with excellent anti-corrosion properties and their application in waterborne polyurethane anticorrosive coatings10.1039/C6RA19618G ↗
13. Graphene based anticorrosive coatings for Cr (VI) replacement10.1039/C5NR04702A ↗
14. Silanized graphene oxide reinforced organofunctional silane composite coatings for corrosion protection10.1016/j.porgcoat.2016.07.008 ↗
15. Effect of nano-sized mesoporous silica MCM-41 and MMT on corrosion properties of epoxy coating10.1016/j.porgcoat.2012.07.009 ↗
16. Improvement of anti-corrosive properties of epoxy-coated AA 2024-T3 with TiO2 nanocontainers loaded with 8-hydroxyquinoline10.1016/j.porgcoat.2012.01.005 ↗
17. Designing of corrosion resistant epoxy coatings embedded with polypyrrole/SiO2 composite10.1016/j.porgcoat.2014.04.013 ↗
18. Effect of nano-ZnO particles on the corrosion resistance of polyurethane-based waterborne coatings immersed in sodium chloride solution via EIS technique10.1016/j.porgcoat.2013.04.013 ↗
19. Corrosion performance of waterborne epoxy coatings containing polyethylenimine treated mesoporous-TiO2 nanoparticles on mild steel10.1016/j.porgcoat.2015.07.009 ↗
20. Investigation on anticorrosion performance of polyaniline-mesoporous MCM-41 composites in new water-based epoxy coating10.1002/maco.201307458 ↗
21. Metronidazole: A corrosion Inhibitor for mild dteel in squeous rnvironment10.4152/pea.201206395 ↗
22. (2002). ASTM D4541-02 Standard Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers, ASTM International.
23. Sadeghimeresht, E., Markocsan, N., and Nylen, P. (2016). A comparative study of corrosion resistance for HVAF-sprayed Fe- and Co-based coatings. Coatings, 6.10.3390/coatings6020016 ↗
24. (2003). ASTM B117 Standard Practice for Operating Salt Spray (Fog) Apparatus, ASTM International.
25. ZSM-5 monolith of uniform mesoporous channels10.1021/ja0299405 ↗
26. Covalent assembly of MCM-41 nanospheres on graphene oxide for improving fire retardancy and mechanical property of epoxy resin10.1016/j.compositesb.2017.11.001 ↗
27. Corrosion performance of a hot-dip galvanized steel treated by different kinds of conversion coatings10.1016/j.surfcoat.2010.08.028 ↗
28. Multilayer organic-inorganic coating incorporating TiO2 nanocontainers loaded with inhibitors for corrosion protection of AA2024-T310.1016/j.porgcoat.2011.10.005 ↗
29. Khalajabadi, S.Z., Abu, A.H., Ahmad, N., Kadir, M.R.A., Ismail, A.F., Nasiri, R., Haider, W., and Redzuan, N.B.H. (2017). Biodegradable Mg/HA/TiO2 nanocomposites coated with MgO and Si/MgO for orthopedic applications: A study on the corrosion, surface characterization, and biocompatability. Coatings, 7.10.3390/coatings7100154 ↗
30. Identification and localization of organic coating degradation onset by impedance imaging10.1016/j.polymdegradstab.2010.03.016 ↗
31. Covalently-grafted graphene oxide nanosheets to improve barrier and corrosion protection properties of polyurethane coatings10.1016/j.carbon.2015.05.094 ↗
32. Novel hybrid epoxy silicone materials as efficient anticorrosive coatings for mild steel10.1039/C5RA04500B ↗